• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
• /
• pp.250-254
• /
• 2002

Intergranular corrosion of austenitic stainless steels is a conventional and momentous problem during welding and high temperature use. One of the major reasons for such intergranular corrosion is so-called sensitization, i.e., chromium depletion due to chromium carbide precipitation at grain boundaries. Conventional methods for preventing sensitization of austenitic stainless steels include reduction of carbon content in the material, stabilization of carbon atoms as non-chromium carbides by the addition of titanium, niobium or zirconium, local solution-heat-treatment by laser beam, etc. These methods, however, are not without drawbacks. Recent grain boundary structure studies have demonstrated that grain boundary phenomena strongly depend on the crystallographic nature and atomic structure of the grain boundary, and that grain boundaries with coincidence site lattices are immune to intergranular corrosion. The concept of "grain boundary design and control", which involves a desirable grain boundary character distribution, has been developed as grain boundary engineering. The feasibility of grain boundary engineering has been demonstrated mainly by thermomechanical treatments. In the present study, a thermomechanical treatment was tried to improve the resistance to the sensitization by grain boundary engineering. A type 304 austenitic stainless steel was pre-strained and heat-treated, and then sensitized, varying the parameters (pre-strain, temperature, time, etc.) during the thermomechanical treatment. The grain boundary character distribution was examined by orientation imaging microscopy. The intergranular corrosion resistance was evaluated by electrochemical potentiokinetic reactivation and ferric sulfate-sulfuric acid tests. The sensitivity to intergranular corrosion was reduced by the thermomechanical treatment and indicated a minimum at a small roll-reduction. The frequency of coincidence-site-lattice boundaries indicated a maximum at a small strain. The ferric sulfate-sulfuric acid test showed much smaller corrosion rate in the thermomechanically-treated specimen than in the base material. An excellent intergranular corrosion resistance was obtained by a small strain annealing at a relatively low temperature for long time. The optimum parameters created a uniform distribution of a high frequency of coincidence site lattice boundaries in the specimen where corrosive random boundaries were isolated. The results suggest that the thermomechanical treatment can introduce low energy segments in the grain boundary network by annealing twins and can arrest the percolation of intergranular corrosion from the surface.

• Fibers and Polymers
• /
• 제5권1호
• /
• pp.19-24
• /
• 2004

PET yarns textured at different texturing conditions were treated with superheated steam or dry heat at different temperatures for different times. The effects of the treatment conditions on the thermomechanical and structural changes of the yarn were examined by shrinkage, X-ray diffraction and birefringence measurements. With increase in superheated steam temperature, the crystalline orientation factor and birefringence decreased, whereas crystal size increased. Dry heat treatment had a smaller effect on shrinkage and structural properties in comparison with superheated steam treatment. The additional shrinkage after texturing process was investigated. The effect of heat-setting in both media was more significant at $200^{\circ}C$. The time dependence of the properties was not linear.

• 한국주조공학회지
• /
• 제1권2호
• /
• pp.10-18
• /
• 1981

In this paper tensile strength and fatigue propagation rate were investigated by aging treatment $(T_6)$ and thermomechanical treatment (TMT) of 7075-Al Alloy specimen. The results of teat showed that TMT improved tensile strength and fatigue crack propagation due to bomogenization of microstructure. In TMT, the results of comparison between T-H' AHA and T-AHA and $T-AH{\cdot}{\cdot}{\cdot}$and $T-HA{\cdot}{\cdot}{\cdot}$were showed that T-AHA and $T-AH{\cdot}{\cdot}{\cdot}$treatments, after solution treatment, which are aging treated before rolling have higher tensile strength. Our investigation on high temperature stability at the Specimen for $T_6$, T-AHA, $T-AH{\cdot}{\cdot}{\cdot}$treatments resulted in rapid reduction of tensile strength over $150^{\circ}C$, but the reduction of tensile strength for specimen of TMT was smoothed than $T_6$.

• 열처리공학회지
• /
• 제12권2호
• /
• pp.145-156
• /
• 1999

The distribution of the second phase, the change of transformation temperature and mechanical properties with thermomechanical treatment conditions were investigated by metallography, calorimetry, EDS, tensile test and fractography in a Cu-Al-Ni-Ti-Mn alloy. The cast structure revealed Ti-rich precipitates($X_L$ phase) between dendrite arms, which have been identified as $(Cu,Ni)_2TiAl$ intermetallic compounds. By homogenizing above $900^{\circ}C$, the $X_L$ phase was melted in the matrix, while the Xs phase was precipitated in matrix and the volume fraction of it was increased. When hot-rolled specimen was betatized below $750^{\circ}C$, recrystallization could not be observed. However, the specimen betatized above $800^{\circ}C$ was recrystallized and the grain size was about $50{\mu}m$, while Xs phase was precipitated in matrix. With raising betatizing temperature, $M_s$ and $A_s$ temperatures were fallen and transformation hysteresis became larger. The strain of the specimen betatized at $800^{\circ}C$ was 8.2% as maximum value. The maximum shape recovery rate could be obtained in the specimen betatized at $800^{\circ}C$ but it was decreased due to the presence of Xs phase with increasing betatizing temperature.

• 펄프종이기술
• /
• 제47권1호
• /
• pp.35-44
• /
• 2015

Thermomechanical pulping process uses large amounts of energy, mostly electricity to run electrical facilities. Thermomechanical pulp (TMP) made from Pinus densiflora also has a big drawback that refining consumes 90 per cent of the total energy used in TMP process. This study explored to draw up a way to save refining energy through different thermal treatment at the stages of presteaming and refining. Presteaming temperature was $80^{\circ}C$, $100^{\circ}C$, and $120^{\circ}C$. After presteaming at each temperature, refining was carried out at $100^{\circ}C$, $120^{\circ}C$, and $140^{\circ}C$ respectively. In a presteaming stage, steaming temperature over $120^{\circ}C$ greatly contributed to the decrease of refining energy leading to earlier attainment of a target freeness, irrespective of refining temperature. In addition, NaOH treatment with presteaming enhanced better development of fiber properties during refining than presteaming without NaOH. High temperature refining at $140^{\circ}C$ produced a high strength paper, and wood chips treated by alkali responded better to refining than at over $120^{\circ}C$. Improved softening effect on wood chips led to the decrease in shives contents but it gave no effect on pitch contents of TMP.

• 열처리공학회지
• /
• 제11권2호
• /
• pp.75-81
• /
• 1998

The effect of thermomechanical treatment on thermal expantion and melting point of Fe-30%Ni-0.35%C alloy was investigated. The dimention changes of the ausformed martensite and the marformed martensite were decreased with increasing deformation degree in the range of $25{\sim}350^{\circ}C$ prior to reverse transformation but became larger in the range of $500{\sim}800^{\circ}C$ after the reverse transformation. The dimension change and the thermal expansion coefficient were reduced in the order of the deformed austenite, the marformed martensite and the ausformed martensite in the range of $25{\sim}800^{\circ}C$. Therefore, the ausforming treatment is more effective than the marforming treatment in improving the heat-resistance. The melting points of the deformed austenite, the ausformed martensite and the marformed martensite were lowered as either the heating rate or the degree of deformation was increased.

• 열처리공학회지
• /
• 제3권1호
• /
• pp.8-16
• /
• 1990

Effects of thermomechanical treatments(TMT) on the microstructures and mechanical properties in Al-2.27%, Li-1.28%, Cu-0.63%, Mg-0.12%, Zr alloy were investigated. The TMT process improved the tensile strength. Growth of ${\delta}^{\prime}$, S' and $T_1$ phases was restrained by TMT processes while the density of ${\delta}^{\prime}$, S' and $T_1$ phases was increased by TMT processes. The TMT treated specimens tend to fail in inter-subboundary mode. The increases of strength by the T-HA processes were compared to those of the T-AHA processes.

• Progress in Superconductivity
• /
• 제1권1호
• /
• pp.56-60
• /
• 1999

Ultra fine MgO particles added BSCCO tapes were fabricated by tape casting using Doctor Blade Method and enclosed by silver foil for different starting compositions (that is, 2223 major, 2212 major). In order to obtain optimum microstructure, thermomechanical treatment was done. Microstructure and phase were analyzed by XRD, SEM and DTA. The critical current density was measured under magnetic field at 77K. The tapes fabricated from the precursor powder with BSCCO-2223 phase (>90%) result in a microstructure with a larger grain size and higher transport critical current density value under magnetic field at given thermomechanical treatment conditions.

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 1999년도 Proceedings of Pre-symposium of the 10th ISWPC
• /
• pp.84-89
• /
• 1999

Treatment with the enzyme pectinase has been reported to lower the cationic demand of thermomechanical pulp(TMP) bleached with alkaline peroxide in the laboratory. We have extended this discovery to bleached TMP produced industrially, and shown that commercial enzyme preparations can treat pulp within 15 minutes at the at the temperature and pH values prevalent in paper mills. About half of the cationic demand in the bleached pulp can be destroyed by pectinase. Dynamic drainage jar experiments show that the enzyme treatment improves the effectiveness of several cationic polymers to increase retention in the absence of retention aids or with non-ionic polymers, and does not damage the strength properties of the pulp. Pectinase could be easily incorporated into paper machine stock preparation systems to lower the charges of cationic retention aids needed in furnishes containing peroxide-bleached mechanical pulp.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 1994년도 추계 학술발표 강연 및 논문 개요집
• /
• pp.182-182
• /
• 1994