• 제목/요약/키워드: Thermoelectric materials

검색결과 400건 처리시간 0.023초

고온에서의 La0.75Ba0.25MnO3 세라믹스의 전기전도 및 열전특성 (High-Temperature Electrical Transport and Thermoelectric Properties of La0.75Ba0.25MnO3 Ceramics)

  • 정우환
    • 한국재료학회지
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    • 제18권4호
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    • pp.175-180
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    • 2008
  • In this study, the thermoelectric power and resistivity of the perovskite manganite $La_{0.75}Ba_{0.25}MnO_3$ were investigated in the temperature range 300K-1200K. The electrical resistivity and thermoelectric power indicate a transport mechanism dominated by adiabatic small-polaron hopping. The power factor increases from $2{\times}10^{-6}W/mK^2$ to $1{\times}10^{-5}W/mK^2$ as to the temperature increases from 400K to 1200K, which indicates that the compound is highly feasible as a thermoelectric material at high temperatures.

MPC 공정에 의한 열전반도체 분말의 성형 및 미세조직 (Consolidation of Thermoelectric Semiconductor Powder by MPC and Their Microstructure)

  • 한태봉;홍순직
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 춘계학술대회 논문집
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    • pp.525-527
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    • 2008
  • N-Type $SbI_3$-doped $95%{Bi_2}{Te_3}-5%{Bi_2}{Se_3}$ compounds were prepared by a gas atomization and Magnetic Pulsed Compaction process. The dynamic recrystallization and thermoelectric properties of the MPCed bulks with consolidation temperatures and times were investigated by a combination of microscopy, XRD and thermoelectric property testing. The microstructure of MPCed bulk shows homogeneous and fine distribution through consolidated bulks due to dynamic recrystallization during hot MPC. This research presented the challenges toward the successful consolidation of thermoelectric powder using magnetic pulsed compaction (MPC).

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온수를 이용한 열전발전기에서 유량변화에 따른 발전 특성 (Characteristic of Electric Generation for the Water Flow Rate in Thermoelctric Generator Using Hot Water)

  • 우병철;이희웅;서창민
    • 대한기계학회논문집B
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    • 제26권10호
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    • pp.1333-1340
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    • 2002
  • The objective of this study is to develop a thermoelectric generation system which converts unused energy from close-at-hand sources such as garbage incineration heat and industrial exhaust etc. into electricity. This paper presents applicability of a commercially available thermoelectric generator f3r waster heat recovery. The test facility consists of water heater, pump, thermoelectric module and aluminium tubes and hot and cold water is used as heat source and sink fluids. It is shown that the three components of thermoelectric research exist in manufacturing a thermoelectric generator. The first component is fabrication of thermoelectric materials, the second is manufacturing of thermoelectric generator with 32 thermoelectric modules. The last one is characteristic measuring of thermoelectric generator with 32 thermoelectric modules of two types, cooling and power purpose. It was found that the rate of cold and hot water is 25 and 37 liter per minute and the maximum power of thermoelectric generator is 28Watts and its efficiency is 1.04%.

압전 액츄에이터를 이용한 열전냉각 시스템 성능 향상에 관한 연구 (A Study on Enhancement of Thermoelectric Cooling System Performance by Piezoelectric Actuator)

  • 양호동;윤희성;오율권
    • 한국안전학회지
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    • 제24권6호
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    • pp.13-19
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    • 2009
  • The thermoelectric cooling system consisted of the thermoelectric module, a heat sink and a cooling fan, respectively. Also, the piezoelectric actuator was applied to improve the performance of thermoelectric cooling system and investigate the heat transfer phenomenon. The temperature distribution of test section was measured to investigate cooling characteristics of thermoelectric cooling system. The flow phenomenon of test section was visualized using visualization device. When the piezoelectric actuator was applied to the heat transfer process of thermoelectric cooling system, acoustic streaming was occurred in test section. The acoustic streaming was occurred forced convection flow, and was regularly formed the temperature distribution in test section. The results clearly show that the acoustic streaming is one of the prime effects to enhance the convection heat transfer and can enhance the performance of thermoelectric cooling system.

기계적 합금화에 의한 Zn4Sb3 열전소재의 합성 및 열전 특성 (Synthesis and Thermoelectric Properties of Zn4Sb3 by Mechanical Alloying Process)

  • 어순철
    • 한국재료학회지
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    • 제14권8호
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    • pp.535-541
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    • 2004
  • Thermoelectric $Zn_{4}Sb_3$ alloy powders were synthesized from elemental powders by mechanical alloying process and consolidated by hot pressing under controlled atmosphere. Single phase $Zn_{4}Sb_3$ was not obtained using a nominal stoichiometric composition, but near single phase $Zn_{4}Sb_3$ with remnant elemental Zn having a relatively high density was produced using a nominally 11.7 $at.\%$ Zn rich powders. Phase transformations during mechanical alloying were systematically investigated using XRD and SEM. Thermoelectric and transport properties were evaluated for the hot pressed specimens and compared with results of analogous studies.

열간 압축 공정에 의한 Zn4Sb3의 직접 고상 반응 합성 및 열전특성 (Direct Solid State Synthesis of Zn4Sb3 by Hot Pressing and Thermoelectric Properties)

  • 어순철
    • 한국분말재료학회지
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    • 제12권4호
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    • pp.255-260
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    • 2005
  • Direct solid state synthesis by hot pressing has been applied in order to produce high efficiency $Zn_4Sb_3$ bulk specimens. Single phase $Zn_4Sb_3$ with 98.5% of theoretical density was successfully produced by direct hot pressing of elemental powders containing 1.2 at.% excess Zn. Thermoelectric properties as a function of temperature were investigated from room temperature to 600 K and compared with results of other studies. Transport properties at room temperature were also evaluated. Thermoelectric properties of single phase $Zn_4Sb_3$ materials produced by direct synthesis were measured and are comparable to the published data. Direct solid state synthesis by hot pressing provides a promising processing route in this material.

그래핀 산화물 분말 첨가에 의한 비스무스 텔루라이드 기지 복합재료의 열전에너지변환 특성 고찰 (Investigation on the Thermoelectric Properties of Bismuth Telluride Matrix Composites by Addition of Graphene Oxide Powders)

  • 김경태;민태식;김동원
    • 한국분말재료학회지
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    • 제23권4호
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    • pp.263-269
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    • 2016
  • Graphene oxide (GO) powder processed by Hummer's method is mixed with p-type $Bi_2Te_3$ based thermoelectric materials by a high-energy ball milling process. The synthesized GO-dispersed p-type $Bi_2Te_3$ composite powder has a composition of $Bi_{0.5}Sb_{1.5}Te_3$ (BSbT), and the powder is consolidated into composites with different contents of GO powder by using the spark plasma sintering (SPS) process. It is found that the addition of GO powder significantly decreases the thermal conductivity of the pure BSbT material through active phonon scattering at the newly formed interfaces. In addition, the electrical properties of the GO/BSbT composites are degraded by the addition of GO powder except in the case of the 0.1 wt% GO/BSbT composite. It is found that defects on the surface of GO powder hinder the electrical transport properties. As a result, the maximum thermoelectric performance (ZT value of 0.91) is achieved from the 0.1% GO/BSbT composite at 398 K. These results indicate that introducing GO powder into thermoelectric materials is a promising method to achieve enhanced thermoelectric performance due to the reduction in thermal conductivity.

On-Film Formation of Nanowires for High-efficiency Thermoelectric Devices

  • Ham, Jin-Hee;Shim, Woo-Young;Lee, Seung-Hyun;Voorhees, Peter W.;Lee, Woo-Young
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.17-17
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    • 2009
  • We report the invention of a direct growth method termed On-Film Formation of Nanowire (OFF-ON) for making high-quality single-crystal nanowires, i.e. Bi and $Bi_2Te_3$, without the use of conventional templates, catalysts, or starting materials. We have used the OFF-ON technique to grow single crystal semi-metallic Bi and compound semiconductor $Bi_2Te_3$ nanowires from sputtered Bi and BiTe films after thermal annealing, respectively. The mechanism for nanowire growth is stress-induced mass flow along grain boundaries in the polycrystalline films. OFF-ON is a simple but powerful method for growing perfect single-crystal semi-metallic and compound semiconductor nanowires of high aspect ratio with high crystallinity that distinguishes it from other competitive growth approaches that have been developed to date. Our results suggest that Bi and $Bi_2Te_3$ nanowires grown by OFF-ON can be an ideal material system for exploring their unique thermoelectric properties due to their high-quality single crystalline and high conductivity, which have consequence and relevance for high-efficiency thermoelectric devices.

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