• Title/Summary/Keyword: Thermodynamic factor

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Thermodynamic cheracteristics of micro algae for energy conversion (조류 부산물의 에너지 전환을 위한 열역학 특성 고찰)

  • Lee, See-Hoon;Seo, Myung-Won;Kim, Sang-Don
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.447-450
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    • 2009
  • 2세대 바이오연료 생산에 적용되는 미세 조류의 열화학적 전환 특성을 열천칭 반응기를 이용하여 고찰하였다. 반응 온도 (500 - $800^{\circ}C$)와 수분 함량 (0-60wt.%)을 변수로 하였으며 미세조류로서 가장 널리 이용되는 클로렐라를 이용하였다. 대표적인 열화학적 전환 반응인 열분해, 부분 산화 (5%), 연소 반응을 고찰하였으며 실험 영역에서 반응온도 및 산소의 분압이 증가함에 따라 탄소 전환율이 증가하였으며 Shrinking-core model을 사용하여 반응 차수를 구하였다. 가스화 영역인 부분 산화 (5%) 조건에서의 activation energy와 frequency factor 값은 각각 19.60 kJ/mol, $2.47{\times}10-1\;s^{-1}$ 이었으며 산소 분압에 의한 반응 차수는 0.209 임을 확인하였다. 수분 함량에 따른 클로렐라의 반응 특성을 살펴보면, 수분 함량이 증가함에 따라 탄소 전환율과 반응성이 감소하는 경향이 발견되었다. 열분해의 경우, 건조 시료에 비하여 수분 함량이 늘어남에 따라 탄소 전환율과 반응성이 급격하게 감소하는 경향을 보였다. 반면, 부분 산화(5%) 및 연소의 경우에는 건조 시료, 수분 함량 20, 40% 시료의 탄소 전환율과 반응성은 거의 일정하였다. 그러나 수분 함량이 60%가 되면서 탄소 전환율 및 반응성이 급격히 떨어졌다.

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Propulsion System Modeling and Reduction for Conceptual Truss-Braced Wing Aircraft Design

  • Lee, Kyunghoon;Nam, Taewoo;Kang, Shinseong
    • International Journal of Aeronautical and Space Sciences
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    • v.18 no.4
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    • pp.651-661
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    • 2017
  • A truss-braced wing (TBW) aircraft has recently received increasing attention due to higher aerodynamic efficiency compared to conventional cantilever wing aircraft. For conceptual TBW aircraft design, we developed a propulsion-and-airframe integrated design environment by replacing a semi-empirical turbofan engine model with a thermodynamic cycle-based one built upon the numerical propulsion system simulation (NPSS). The constructed NPSS model benefitted TBW aircraft design study, as it could handle engine installation effects influencing engine fuel efficiency. The NPSS model also contributed to broadening TBW aircraft design space, for it provided turbofan engine design variables involving a technology factor reflecting progress in propulsion technology. To effectively consolidate the NPSS propulsion model with the TBW airframe model, we devised a rapid, approximate substitute of the NPSS model by reduced-order modeling (ROM) to resolve difficulties in model integration. In addition, we formed an artificial neural network (ANN) that associates engine component attributes evaluated by object-oriented weight analysis of turbine engine (WATE++) with engine design variables to determine engine weight and size, both of which bring together the propulsion and airframe system models. Through propulsion-andairframe design space exploration, we optimized TBW aircraft design for fuel saving and revealed that a simple engine model neglecting engine installation effects may overestimate TBW aircraft performance.

A Study on the Entropy Generation of Single Fin-Tube Heat Exchanger (단일 핀-관 열교환기에서 엔트로피 생성에 관한 연구)

  • Pak, Hi-Yong;Lee, Kwan-Soo;Kim, Byoung-Kue
    • Solar Energy
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    • v.10 no.1
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    • pp.14-21
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    • 1990
  • The entropy generation rate in a fin-tube heat exchanger is investigated as a basis for thermodynamic optimization associated with single fin-tube heat exchanger. The entropy generation (irreversibility)analysis is used to find the optimum design factor and investigate total entropy generation, optimum dimensions of fin length, tube inner and outer diameters, and fin spacing on the variation of design factors. The results of this study are as follows: As the outer diameter increases, optimum !in spacing and fin length increase but the entropy generation and optimum inner diameter decrease; As fin thickness increases, the entropy generation of system and optimum fin spacing increase; As fin length increases, entropy generation and optimum outer diameter increase.

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A Numerical Study on Acoustic Tuning of Quarter-Wave Resonators in a Model Combustion Chamber (연소실에서 1/4파장 공명기의 주파수 동조에 대한 수치적 연구)

  • Park, Ju-Hyun;Park, I-Sun;Sohn, Chae-Hoon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.281-284
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    • 2009
  • Acoustic tuning frequency of quarter-wave resonators is investigated numerically to suppress combustion instability in a liquid rocket engine. A quarter-wave resonator is adopted, which was designed from the cold acoustic test for optimal damping condition. First, in a model combustion chamber scaled down from a full-scale chamber, reactive flow filed is analyzed numerically and acoustic-pressure responses are examined. Next, thermodynamic properties in the resonators are predicted. Based on the data, frequency tuning method is studied. The optimum tuning length of each resonator is proposed and thereby, sufficient damping is produced.

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Empirical Equations for Thermodynamic Physical Properties of Freon-23 and HFC-227ea (Freon-23과 HFC-227ea의 열역학적 물성에 관한 실험식)

  • 김재덕;이윤우;송명석;노경호
    • Fire Science and Engineering
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    • v.16 no.3
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    • pp.16-25
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    • 2002
  • For Freon-23, a conventional extinguished agent regulated by Montreal Protocol and HFC-227ea, its alternative, the empirical equations were correlated in terms of saturated pressure, density, viscosity, enthalpy and surface tension. They were obtained by regression analysis from the experimental data in the literature. The empirical equations of saturated pressure were expressed as the second and third order function of temperature. The empirical equation of density was expressed as compressibility factor and saturated pressure by a function of temperature. The empirical equation of viscosity was formulated as a power function. Heat capacities as well as enthalpies were well fitted by empirical form of the second-order temperature. Finally, surface tension simply has linear function form in terms of temperature.

Reconstruction of Thermodynamics by the Concept of Available Energy (II) - Thermodynamics of Real World - (가용 에너지에 의한 열역학의 재구성 (II) - 실제세계 열역학 -)

  • Jung, Pyung-Suk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1573-1581
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    • 2004
  • Thermodynamic principles are described with a new point of view. In present study, the interaction between two systems is focused instead of the behavior of a system in conventional thermodynamics. The state change of a system cannot occur by itself but it is the result of the interaction between systems. However, the interaction itself is also the result of another kind of interaction, the interaction between two interactions. To reconstruct thermodynamics with such a point of view, the reversible world is imagined, in which conservations and measurements are discussed. There exists a conserved quantity for each mode of reversible interaction. The conserved transferring quantity in the interaction between interactions is the effective work, which is supposed to be measurable and conserved in reversible world. Effective work is the primary concepts of energy. It is the key factor to explain measurements, energy conservation and energy dissipation. The concepts developed in reversible world are applied to the real world in which irreversible phenomena may occur. Irreversibility is the result of effective energy dissipation, in which effective work irreversibly changes into entropy. A quantitative relation between the disappearing effective work and the generated entropy is dissipation equation which is given by experiments. A special temperature scale to give a very simple type of the dissipation equation is the absolute temperature scale, which gives the conventional conservation of energy.

Measurement of EUV (Extreme Ultraviolet) and electron temperature in a hypocycloidal pinch device for EUV lithography

  • Lee, Sung-Hee;Hong, Young-June;Choi, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.108-108
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    • 2010
  • We have generated Ne-Xe plasma in dense plasma focus device with hypocycloidal pinch for extreme ultraviolet (EUV) lithography and investigated an electron temperature. We have applied an input voltage 4.5 kV to the capacitor bank of 1.53 uF and the diode chamber has been filled with Ne-Xe(30%) gas in accordance with pressure. If we assumed that the focused plasma regions satisfy the local thermodynamic equilibrium (LTE) conditions, the electron temperature of the hypocycloidal pinch plasma focus could be obtained by the optical emission spectroscopy (OES). The electron temperature has been measured by Boltzmann plot. The light intensity is proportion to the Bolzman factor. We have been measured the electron temperature by observation of relative Ne-Xe intensity. The EUV emission signal whose wavelength is about 6~16 nm has been detected by using a photo-detector (AXUV-100 Zr/C, IRD) and the line intensity has been detected by using a HR4000CG Composite-grating Spectrometer.

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The Investigation of Detonation Characteristics of Ethylene Oxide Mixture by Using Incident Shock Tube Technique (입사 충격파관을 이용한 에틸렌 옥사이드 혼합물의 데토네이션 특성연구)

  • Moon, J.H.;Chung, J.D.;Kang, J.G.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.2 no.5
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    • pp.121-134
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    • 1994
  • Shock tube investigation of ethylene oxide-$0_{2}-N_{2}$ mixture have been performed to reveal detonation characteristics of the mixture in terms of detonation pressure and speed. Theoretical calculation of thermodynamic parameters at the Chapmann-Jouguet detonation of the mixture has been also performed. A comparision of the observed results with the calculated ones can lead us to predict the detonation parameters of ethylene oxide in an artificial air. In addition, we have observed ignition delay times of ethylene oxide mixtures. The best fit of the observed delay times to Arrhenius gas kinetic relation gives : ${\tau}=10^{-144}{e{xp}}(E_a/RT)[C_{2}H_{4}O]^{-4.8}[O_{2}]^{-12.4}[N_{2}]^{-14.1}$ $E_a=3.67kcal/mole$ The observed activation energy is markedly reduced, compared with the case of ethylene oxide diluted in Ar. It could be due to the factor that $N_2$ play a role as detonation promoter yielding very reactive NOx radicals.

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A Numerical Study on the Transmission of Thermo-Acoustic Wave Induced by Step Pulsed Heating in an Enclosure (제한공간내 펄스가열에 기인한 열음향파의 전달특성에 관한 수치적 연구)

  • 황인주;김윤제
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.11
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    • pp.914-922
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    • 2002
  • Thermo-acoustic waves can be thermally generated in a compressible flow field by rapid heating and cooling, and chemical reaction near the boundary walls. This mechanism is very important in the space environment in which natural convection does not exist. Also this may be a significant factor for heat transfer when the fluids are close to the thermodynamic critical point. In this study, the generation and transmission characteristics of thermo-acoustic waves in an air-filled confined domain with two-step pulsed heating are studied numerically. The governing equations are discretized using control volume method, and are solved using PISO algorithm and second-order upwind scheme. For the purpose of stable solution, time step was set to the order of $1\times10_-9s,\;and\;grids\;are\;50\times2000$. Results show that temperature and pressure distributions of fluid near the boundary wall subjected to a rapid heating are increased abruptly, and the induced thermo-acoustic wave propagates through the fluid until it decays due to viscous and heat dissipation. Pressure waves have sharp front shape and decay with a long tail in the case of step heating, but these waves have sharp pin shape in the case of pulsed heating.

Tempereture Dependent Dielectric Relaxation Study of Aniline in Dimethylsulphoxide and Dimethlformamide Using Time Domain Technique (시간분해기법을 이용한 디메틸 술폭사이드와 디메틸 포름아미드-아닐린용액에서 온도의존 유전이완에 관한 연구)

  • Chaudhari, Ajay;Patil, C.S.;Shankarwar, A.G.; Arbad, B.R.;Mehrotra, S.C.
    • Journal of the Korean Chemical Society
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    • v.45 no.3
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    • pp.201-207
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    • 2001
  • The dielectric relaxation study for aniline-dimethylsulphoxide (DMSO) and aniline-dim.ethylformamide(DMF) has been carried out using the Time domain reflectometry (TDR) technique, at different temperature and concentrations, in the frequency range of 10 MHz to 10 GHz. The dielectric parameters viz. static permittivity, relaxation time, the Kirkwood correlation factor, excess permittivity, excess inverse relaxation time and thermodynamic parameters have been obtained. The calibration method based on least squares fit method has been used. The dielectric parameters show systematic change with temperature and concentrations.

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