• Nuclear Engineering and Technology
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• 제39권1호
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• pp.21-30
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• 2007

Current high-temperature gas-cooled reactors (HTGRs) are based on a closed Brayton cycle with helium gas as the working fluid. Thermodynamic performance of the axial-flow helium gas turbines is of critical concern as it considerably affects the overall cycle efficiency. Helium gas turbines pose some design challenges compared to steam or air turbomachinery because of the physical properties of helium and the uniqueness of the operating conditions at high pressure with low pressure ratio. This report present a review of the helium Brayton cycle experiences in Germany and in Japan. The design and availability of helium gas turbines for HTGR are also presented in this study. We have developed a new throughflow calculation code to calculate the design-point performance of helium gas turbines. Use of the method has been illustrated by applying it to the GTHTR300 reference.

• Bulletin of the Korean Chemical Society
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• 제21권11호
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• pp.1085-1089
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• 2000

The effect of 2-hydroxyacetophenone-aroyl hydrazone derivatives on the inhibition of copper corrosion in 3N nitric acid solution at 303 K was investigated by galvanostatic polarization and thermometric techniques. A significant decrease in the cor rosion rate of copper was observed in the presence of the investigated compounds. The corrosion rate was found to depend on the nature and concentrations of the inhibitors. The degree of surface coverage of the adsorbed inhibitors is determined from polarization measurements, and it was found that the results obey the Frumkin adsorption isotherm. The inhibitors acted as mixed-type inhibitors, but the cathode is more polarized. The relative inhibitive efficiency of these compounds has been explained on the basis of structure dependent electron donor properties of the inhibitors and the nature of the metal-inhibitor interaction at the surface. Also, some thermodynamic data for the adsorption process ( ΔGa* and f ) are calculated and discussed.

• Proceedings of the Safety Management and Science Conference
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• 대한안전경영과학회 2008년도 추계학술대회
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• pp.659-667
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• 2008

The LNG carriers have been propelled by steam turbines and the LNG boil-off(BOG) has been used as fuel or vented. However, as the alternative propulsion systems such as diesel engines are being equipped on the LNG carriers for better fuel efficiency, a need for the LNG BOG re-liquefaction system that liquefies the BOG and sends the liquid BOG back to the LNG cargo has arisen in recent years. This study investigates the design of the BOG re-liquefaction system based on the reverse Brayton refrigeration cycle. The thermodynamic and heat exchanger analysis are carried out and the limitations to the system performance are discussed.

• Bulletin of the Korean Chemical Society
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• 제11권4호
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• pp.333-339
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• 1990

A series of new dimesogenic compounds whose mesogens are of aromatic ester or amide type having a trifluoromethyl $(CF_3)$ substituent at the para-position of each terminal phenolic rings were prepared and their liquid crystalline properties were studied by differential scanning calorimetry (DSC) and on a cross-polarizing microscope. The compounds have two identical mesogenic units bracketing a central decamethylene spacer. Trifluoromethyl group appears to favor the formation of smectic phases when it is attached to a phenoxy or anilide terminal. Its group efficiency for mesophase formation seems to be inferior to other common substituents. A thermodynamic analysis of the phase transitions was made and the results were explained in relation to the structures of the compounds.

• Journal of Electrochemical Science and Technology
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• 제12권3호
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• pp.365-376
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• 2021

Two arylamino substituted mercaptoimidazole derivatives namely 4,5-dimethyl-1-(phenylamino)-1H-imidazole-2(3H)-thione (I1) and 4,5- dimethyl-1-((p-chlorophenyl)amino)- 1H-imidazole-2(3H)-thione (I2) were synthesized and investigated as corrosion inhibitors for carbon steel in 0.5 M HCl solution by means of electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, ATR-FTIR spectroscopy and SEM. The results showed that the investigated mercaptoimidazole derivatives act as mixed type inhibitors and inhibition efficiency follows the I2>I1 order. Adsorption of inhibitors on metal surface was found to obey the Langmuir adsorption isotherm. Thermodynamic parameters revealed that adsorption of the inhibitors has both physisorption and chemisorption adsorption mechanism. Electrochemical test results were supported by quantum chemical parameters obtained from DFT calculations.

• International Journal of Computer Science & Network Security
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• 제22권12호
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• pp.178-184
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• 2022

Renewable energy sources based on solar radiation, wind energy, geothermal energy, and biomass energy have now reached the level of industrial application. A new way to generate electricity using low-potential heat is to install a hydro-steam turbine. In hydro-steam turbines, hot water is supplied directly to turbine rotor nozzles without prior separation into steam and water in separators, which significantly increases the efficiency of hot water energy use. Such turbines are suggested to be used as autonomous energy sources in geothermal heating systems, heating water boilers and cooling systems of chemical reactors, metallurgical furnaces, etc. The authors conclude that the installation of hydro-steam turbines in heating plants and process boiler plants can also be effective if the used exhaust steam-water mixture at the turbine outlet is used to heat the network water or as return water.

• Transactions of the Korean Society of Mechanical Engineers B
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• 제36권7호
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• pp.711-719
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• 2012

A thermodynamic analysis and a feasibility study on the organic Rankine cycle (ORC) as a waste heat recovery system for a marine diesel engine were carried out. The ORC and its combined cycle with the engine were simulated, and its performance was estimated theoretically using R245fa. A parametric study on the performance of the ORC system was carried out under different temperature conditions of the heat transfer loop and specification of the heat exchanger. According to the thermodynamic analysis, ~10% of the thermal efficiency of the cycle was able to be realized with the low temperature heat source below $250^{\circ}C$. The electric power output of the ORC was estimated to be about 4% of the mechanical power output of the engine, considering additional pumps for cooling water and circulation of the heat transfer medium. According to the present study, the electric power generated by the ORC is about 59%-69% of the required power, and it is possible to reduce the fuel consumption under normal seagoing conditions.

• Korean Chemical Engineering Research
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• 제55권6호
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• pp.807-815
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• 2017

This study investigated the removal efficiency of residual pentane from paclitaxel according to the drying temperature in the case of rotary evaporation, and performed a kinetic and thermodynamic analysis of the drying process. At all the temperatures (25, 30, 35, 40, and $45^{\circ}C$), a large amount of the residual solvent was initially removed during the drying, and the drying efficiency increased when increasing the drying temperature. Five drying models (Newton, Page, modified Page, Henderson and Pabis, Geometric) were then used for the kinetic analysis, where the Henderson and Pabis model showed the highest coefficient of determination ($r^2$) and lowest root mean square deviation (RMSD), indicating that these models were the most suitable. Furthermore, in the thermodynamic analysis of the rotary evaporation, the activation energy ($E_a$) was 4.9815 kJ/mol and the standard Gibbs free energy change (${\Delta}G^0$) was negative, whereas the standard enthalpy change (${\Delta}H^0$) and standard entropy change (${\Delta}S^0$) were both positive, indicating that the drying process was spontaneous, endothermic, and irreversible.

• Journal of Electrical Engineering and Technology
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• 제9권5호
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• pp.1511-1519
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• 2014

The objective of this paper is to propose a modelling of a small compressed air energy storage system, which drives an induction generator based on a field-oriented control (FOC) principle for a renewable power generation. The proposed system is a hybrid technology of energy storage and electrification, which is developed to use as a small scale of renewable energy power plant. The energy will be transferred from the renewable energy resource to the compressed air energy by reciprocating air compressor to be stored in a pressurized vessel. The energy storage system uses a small compressed air energy storage system, developed as a small unit and installed above ground to avoid site limitation as same as the conventional CAES does. Therefore, it is suitable to be placed at any location. The system is operated in low pressure not more than 15 bar, so, it easy to available component in country and inexpensive. The power generation uses a variable speed induction generator (IG). The relationship of pressure and air flow of the compressed air, which varies continuously during the discharge of compressed air to drive the generator, is considered as a control command. As a result, the generator generates power in wide speed range. Unlike the conventional CAES that used gas turbine, this system does not have any combustion units. Thus, the system does not burn fuel and exhaust pollution. This paper expresses the modelling, thermodynamic analysis simulation and experiment to obtain the characteristic and performance of a new concept of a small compressed air energy storage power plant, which can be helpful in system designing of renewable energy electrification. The system was tested under a range of expansion pressure ratios in order to determine its characteristics and performance. The efficiency of expansion air of 49.34% is calculated, while the efficiency of generator of 60.85% is examined. The overall efficiency of system of approximately 30% is also investigated.

• Journal of Advanced Marine Engineering and Technology
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• 제35권1호
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• pp.46-52
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• 2011

A study on the improvement for cycle efficiency of closed-type ocean thermal energy conversion (OTEC) was studied to obtain the basic data for the optimal design of cycle. For that, OTEC cycle with a generator, a reheater and a multi-turbine was simulated and analyzed. The basic thermodynamic model for OTEC is Rankine cycle and the surface seawater of $26^{\circ}C$ and deep seawater of $5^{\circ}C$ were used for the heat source of evaporator and condenser, respectively. Ammonia is used as the working fluid. The cycle efficiency increased when generator is added with 0.9 generator effectiveness. When the reheater and multi-turbine are applied in the basic cycle, the cycle efficiency showed 3.14% and the capacity of heat exchanger decreased for same total cycle power. For the OTEC cycle with the generator, the reheater and the multi-turbine showed the highest cycle efficiency and increased the efficiency by more than 6.5% comparing with the basic OTEC cycle.