• 분석과학
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• 제7권4호
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• pp.505-515
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• 1994

DMSO(dimethylsuloxide-$d_6$) 용액 속에 존재하는 CN/CN 리간드의 hemin 착물과 CN/DMSO의 hemin 착물이 $^1H$ NMR로 기록되어지고 분석되어졌다. Hemin으로의 CN 착물화 과정은 온도에 따라 변화함을 NMR 스펙트럼이 보여 주며, 한 개의 CN 리간드에서 두 개의 CN 리간드착물로 바뀌는 과정의 열역학함수는 ${\Delta}H^{\circ}=736.6cal/mol$ 및 ${\Delta}S^{\circ}=16.4eu$인 흡열과정을 나타낸다. CN/DMSO의 hemin 착물은 Curie behavior로부터의 벗어남은 high-spin 성격의 존재를 나태내고, 이는 Fe-DMSO 결합이 순간적으로 깨짐을 의미하며, 이러한 CN/DMSO hemin 착물이 한 개의 axial ligand가 약한 heme 단백질의 전자 및 분자구조의 model complex로 작용할 수 있음을 보여 준다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.277-284
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• 2017

본 연구는 이중모드 스크램제트 엔진의 흡입구, isolator, 연소기, 노즐에서의 flowpath 유동특성에 대한 해석적 연구결과이다. 이중모드 스크램제트 엔진의 설계와 성능을 파악하기 위해서는 공력, 열역학적 특성, 추진 그리고 전체 시스템에 대한 성능 모델과 해석 도구의 개발이 반드시 요구된다. 본 연구에서는 이중모드 스크램제트 엔진의 각 구성품인 흡입구, isolator, 연소기, 노즐에 대한 해석 모델을 정립하고, 개발된 해석 도구를 사용하여 이중모드 스크램제트 엔진의 성능특성을 파악해 보았다.

• Geomechanics and Engineering
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• 제25권2호
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• pp.111-121
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• 2021

Large deformation and rapid pressure propagation take place inside the rock mass under the dynamic loads caused by the explosives, on quarry faces in order to extract aggregate material. The complexity of the science of rock blasting is due to a number of factors that affect the phenomenon. However, blasting engineering computations could be facilitated by innovative software algorithms in order to determine the results of the violent explosion, since field experiments are particularly difficult to be conducted. The present research focuses on the design of a Finite Element Analysis (FEA) code, for investigating in detail the behavior of limestone under the blasting effect of Ammonium Nitrate & Fuel Oil (ANFO). Specifically, the manuscript presents the FEA models and the relevant transient analysis results, simulating the blasting process for three types of limestone, ranging from poor to very good quality. The Finite Element code was developed by applying the Jones-Wilkins-Lee (JWL) equation of state to describe the thermodynamic state of ANFO and the pressure dependent Drucker-Prager failure criterion to define the limestone plasticity behavior, under blasting induced, high rate stress. A progressive damage model was also used in order to define the stiffness degradation and destruction of the material. This paper performs a comparative analysis and quantifies the phenomena regarding pressure, stress distribution and energy balance, for three types of limestone. The ultimate goal of this research is to provide an answer for a number of scientific questions, considering various phenomena taking place during the explosion event, using advanced computational tools.

• 대한기계학회논문집B
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• 제27권1호
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• pp.76-83
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• 2003

Exergetic and thermoeconomic analyses were performed fer a 137-MW steam power plant. In these analyses, mass and energy conservation laws were applied to each component of the system. Quantitative balance of the exergy and exergetic cost for each component, and for the whole system was carefully considered. The exergo-economic model, which represented the productive structure of the system was used to visualize the cost formation process and the productive interaction between components. The computer program developed in this study can determine production costs of power plants, such as gas-and steam-turbines plants and gas-turbine cogeneration plants. The program can also be used to study plant characteristics, namely, thermodynamic performance and sensitivity to changes in process and/or component design variables.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.379-381
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• 2009

The simulation model for metal-supported Solid Oxide Fuel Cell(SOFC) is developed in this study. Open circuit voltage is calculated using Nernst equation and Gibbs free energy is required by thermodynamic. The exchange current densities are compared with experimental results since exchange current density is most effective factor for the activation loss. Liu's study is used for the exchange current density of cathode, BSCF, and Koide's result is applied for the exchange current density of anode, Ni/YSZ. For the ohmic loss, ionic conductivity of YSZ is described from Kilner's mode and the data are compared with Wanzenberg's experimental data. Diffusivity is an important factor for the mass transfer through the porous medium. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1998년도 제27회 춘계학술대회
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• pp.218-227
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• 1998

Present study is undertaken to optimize the lubrication reliability and frictional loss of the dynamically-loaded journal bearing in hermetic reciprocating compressor with alternative refrigerant R600a application. Thermodynamic and dynamic analysis has been conducted to investigate cylinder pressure variations by substitution alternative refrigerant R600a for R12. The modeling of the dynamics of the compressor mechanism has been performed with lumped mass method. A mathematical model is developed for analyzing the dynamics of the journal bearing system with the mobility method. It takes into account the effects of the refrigerant species, aspect ratio, clearance ratio and surface roughness. A corresponding computer program is described which enables to obtain the minimum film thickness and frictional loss. Design optimization is graphically performed by parametric studies of the aspect ratio and clearance ratio.

• KSBB Journal
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• 제4권2호
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• pp.150-156
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• 1989

안정상태 일차원적 모델을 이용하여 막으로 덮힌 상업적인 산소 적극의 특성을 공기포화된 식염수에서 연구하였다. 전극은 세 개의 층으로 이루어져 있는데. 이는 외부 농도 경계층(용액), 반투성 막, 내부 전해질 용액 층으로 구분된다. 정체용액에서, 물은 외부 용액층으로부터 내부 전해질 용액쪽으로 열역학적 평형을 이룰 때까지 이동한다. 한편 유동 용액에서, 불은 수력학적 압력차 때문에 전해질 층의 두께가 막의 두께와 같아질 때까지 반대방향으로 이동한다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.255.2-255.2
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• 2014

Electrode erosion is indispensable for atmospheric plasma systems, as well as for switching devices, due to the high heat flux transferred from arc plasmas to contacts, but experimental and theoretical works have not identified the characteristic phenomena because of the complex physical processes. Our investigation is concerned with argon free-burning arcs with anode erosion at atmospheric pressure by computational fluid dynamics (CFD) analysis. We are also interested in the energy flux and temperature transferring to the anode with a simplified unified model of arcs and their electrodes. In order to determine two thermodynamic quantities such as temperature and pressure and flow characteristics we have modified Navier-Stokes equations to take into account radiation transport, electrical power input and the electromagnetic driving forces with the relevant Maxwell equations. From the simplified self-consistent solution the energy flux to the anode can be derived.

• Bulletin of the Korean Chemical Society
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• 제20권8호
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• pp.939-942
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• 1999

The tie lines delineating ion-exchange equilibria between NiFe2O4-NiCr2O4 spinel solid solution and Fe2O3-Cr2O3 corundum solid solution were determined at 900, 1000, and 1200 ℃ by electron microprobe and energy dispersive X-ray analysis of oxide phases, using the flux growth technique. Activities of the spinel components were calculated from the tie lines, assuming Temkin's ideal mixing in the corundum solid solution. The spinel phase could be expressed by a regular solution with negative deviations from ideality. The Gibbs free energies of mixing for spinel solid solution were discussed in terms of the cation distribution model, based on site preference energies and assuming random mixing on both tetrahedral and octahedral sites.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2008년 영문 학술대회
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• pp.413-418
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• 2008

Flow instability in the rocket turbo pump system can be caused by various reasons such as valve, orifice and venturi, etc. The inception of cavitation, especially in the propellant feeding system, is the primary cause of the mass flow and pressure oscillation due to cyclic formation and depletion of cavitation. Meanwhile, the main propellant in liquid rocket engine is the cryogenic one, which is very sensitive to temperature variation, and the variation of propellant properties caused by thermodynamic effect should be accounted for in the flow analysis. The present study focuses on the formation of cryogenic cavitations by adopting IDM model suggested by Shyy and coworkers. Also, the flow instability was investigated in the downstream of orifice by using a developed numerical code. Calculation results show that cryogenic cavitations can lead to flow instability resulting in mass flow fluctuations due to pressure oscillations. And the prediction of cavitations in cryogenic fluid is of vital importance in designing feeding system of LRE.