• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.406-414
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• 2010

A novel polyacrylamide grafted hydrous ferric oxide adsorbent composite has been synthesized by using glow discharge electrolysis plasma. To optimize the synthesis conditions, the following parameters were examined in detail: applied power, discharge time, post polymerization temperature, post polymerization time, amount of crosslinking agent and hydrous ferric oxide gel added and so on. The adsorbent was characterized by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). The removal percentage of the adsorbent in Pb(II) solution was examined and the data obtained showed that the adsorbent composite has a high capacity for lead ion. For the use in wastewater treatment, the thermodynamic and kinetic of Pb(II)-capture were also studied. Results indicated that the adsorption reaction was a spontaneous and an endothermic process, and it seems to be obeyed a pseudo-secondorder rate model. Moreover, the adsorption isotherm of Pb(II)-capture is following the Langmuir and Freundlich isotherm models.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.201-207
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• 2001

We modeled the liquid film dryout(LFD) process for both tube and annulus which have uniformly heated vertical channels. We set phenomenological initial conditions in the model. The initial void fraction on the onset of the annular flow location is derived from the physical chum-to-annular flow criterion with the help of the drift-flux-model. The initial thermodynamic-equilibrium-quality is calculated by iteration with the flow quality to find the onset of the annular-flow location. Present model tends to predict very well at the lower exit quality but under-estimates at the higher exit quality. We found that the prediction error of the present model is gradually bigger as the inlet subcooling approaches near the saturation. We obtained excellent results for both tube and annulus channels as the mean of 0.97 and root-mean-square error of 11% for the number of 3883 experimental data on tubes, and of 0.96 and of 12% for 593 on annuli. The present model extended the applicable range to the relatively low exit quality region than previous LFD models.

• Bulletin of the Korean Chemical Society
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• v.30 no.9
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• pp.2051-2056
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• 2009

The rate constants of alkaline fading of malachite green ($MG^+$) was measured in the presence of nonionic (TX-100), cationic (DTAB) and anionic (SDS) surfactants. This reaction was studied under pseudo-first-order conditions at 283∼303 K. The rate of fading reaction showed noticeable dependence on the electrical charge of the used surfactants. It was observed that the reaction rate constants were increased in the presence of TX-100 and DTAB and decreased in the presence of SDS. According to Hughs-Ingold rules for nucleophilic substitution reactions, the electric charge of MG/surfactant compound along with decrease in dielectric constant of $MG^+$ micro-environment in this compound varies the rate of fading reaction. Binding constants of surfactant molecules to $MG^+$ were calculated using cooperativity, pseudo-phase ion exchange and classical models and the related thermodynamic parameters were obtained by classical model. The results show that the binding of $MG^+$ to TX-100 is exothermic and binding of $MG^+$ to DTAB and SDS in some concentration ranges of the used surfactants is endothermic and in the other ones is exothermic.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.3 no.1
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• pp.1-9
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• 2007

A steady-state simulation model for Dual-Source Heat Pump(DSHP) of 8RT was presented. A Dual-Source Heat Pump(DSHP) has been designed to make up for the conventional air source heat pumps. The performance evaluation has been conducted under internal standard test conditions such as ISO-13256-1 and KS C 9306. However, as test conditions such as entering water, indoor and outdoor air conditions could not be controlled to satisfy the standard test conditions in outdoor tests, a series of experiments have been conducted with the actual test conditions. Then, computer models for DSHP could be used for the standard condition have developed using EES program. The model was developed from basic thermodynamic principles and heat transfer relations. Most of the parameters were obtained with EES from the actual catalog data. The simulation results were in good agreement with the experiments.

• 유체기계공업학회:학술대회논문집
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• 1998.12a
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• pp.209-214
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• 1998

A thermodynamic simulation method is developed for the process design and the performance evaluation of the gas turbine in IGCC power plant. The present study adopts four clean coal gases derived from four different coal gasification and gas clean-up processes as IGCC gas turbine fuel, and considers the integration design condition of the gas turbine with ASU(Air Separation Unit). In addition, the present simulation method includes compressor performance map and expander choking models for considering the off-design effects due to coal gas firing and ASU integration. The present prediction results show that the efficiency and the net power of the IGCC gas turbines are seperior to those of the natural gas fired one but they are decreased with the air extraction from gas turbine to ASU. The operation point of the IGCC gas turbine compressor is shifted to the higher pressure ratio condition far from the design point by reducing the air extraction ratio. The exhaust gas of the IGCC gas turbine has more abundant wast heat for the heat recovery steam generator than that of the natural gas fired gas turbine.

• International Journal of Aeronautical and Space Sciences
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• v.18 no.4
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• pp.651-661
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• 2017

A truss-braced wing (TBW) aircraft has recently received increasing attention due to higher aerodynamic efficiency compared to conventional cantilever wing aircraft. For conceptual TBW aircraft design, we developed a propulsion-and-airframe integrated design environment by replacing a semi-empirical turbofan engine model with a thermodynamic cycle-based one built upon the numerical propulsion system simulation (NPSS). The constructed NPSS model benefitted TBW aircraft design study, as it could handle engine installation effects influencing engine fuel efficiency. The NPSS model also contributed to broadening TBW aircraft design space, for it provided turbofan engine design variables involving a technology factor reflecting progress in propulsion technology. To effectively consolidate the NPSS propulsion model with the TBW airframe model, we devised a rapid, approximate substitute of the NPSS model by reduced-order modeling (ROM) to resolve difficulties in model integration. In addition, we formed an artificial neural network (ANN) that associates engine component attributes evaluated by object-oriented weight analysis of turbine engine (WATE++) with engine design variables to determine engine weight and size, both of which bring together the propulsion and airframe system models. Through propulsion-andairframe design space exploration, we optimized TBW aircraft design for fuel saving and revealed that a simple engine model neglecting engine installation effects may overestimate TBW aircraft performance.

• Journal of Environmental Science International
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• v.20 no.2
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• pp.215-222
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• 2011

The adsorption behavior of nitrate nitrogen was investigated from aqueous solution using char prepared from oak chip. The removal rate of nitrate nitrogen was found to be dependent on temperature and it is increased as the temperature increase. Adsorption equilibrium data of nitrate nitrogen on oak char. reasonably fitted Langmuir and Freundlich isotherm models. The adsorption energy obtained from D-R model was 12.5 kJ/mole at $20^{\circ}C$ indicating an ion exchange process as primary adsorption mechanism. Thermodynamic parameters such as ${\Delta}G^o$, ${\Delta}H^o$, and ${\Delta}S^o$ were -23.76 kJ/mole, 26.1 kJ/mole and 89.7 J/K mole at $20^{\circ}C$, respectively, indicated that the nature of nitrate nitrogen adsorption is spontaneous and endothermic.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.35 no.9
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• pp.805-815
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• 2007

In order to build a conceptual design program for a liquid rocket engine system, performance based sub-programs for each core component of the engine system were made. Parts included were the combustion chamber, supersonic nozzle, centrifugal pump, and impulsive turbine. Simple mathematical models based on classical thermodynamic and inviscid theories were adopted with proper tuning by empirical data. In Part I, aiming to validate each sub-program, we examined the results of each program qualitatively, and parametrically investigated the sensitivity due to the change in design parameters.

• Applied Chemistry for Engineering
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• v.8 no.4
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• pp.653-659
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• 1997

Due to the rising cost of energy, new separation processes based on extraction are becoming more attractive than before. Thus, the need for calculating and predicting liquid-liquid equilibria(LLE) compositions has very much increased. The purpose of this study is to determine the binodal curves, tie line, plait point, distribution and selectivity for the ternary systems of 2-propanol-water with methyl ethyl ketone, methyl isobutyl ketone, ethylacetate, toluene and o-xylene as solvents at $25^{\circ}C$. And those tie line data were used to examine thermodynamic consistency. The experimental tie line data were correlated with NRTL and UNIQUAC models.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2006.04a
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• pp.1009-1014
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• 2006

Synthetic materials with excellent thermodynamic characteristics and the merit of anti-corrosion are frequently used in buildings and constructions for enforcement of bent in stead of steel plates. Among them, many practical studies have been conducted on bond strength because of increased bond strength of FRP plates. Previous investigators identified the bond strength of FRP plates through experiments with settlement of various variables to identify the bond strength. However, the experiments to identify the bond force are difficult to be conducted because they requires large expenses and long time for equipment arrangement, thus, are conducted with limitation. In this study, for bond experiment, optimum neural network model was developed with use of Back-propagation and Conjugate gradient technique of previous investigators. Learning was performed with use of the variables of previous investigators in developed neural network model so as to identify the bond strength of FRP plates. for verification of developed model, credibility and excellence was proven by comparing with the models of previous investigators.