• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
• /
• pp.207-208
• /
• 2007

Recently, high performance microelectronic devices are designed in multi-layer structure in order to make dense wiring of metal conductors in compact size. Imprint lithography have received significant attention due to an alternative technology for photolithography on such devices. In this work, we synthesized dielectric composite materials based on epoxy resin, and investigated their thermal stabilities and dynamic mechanical properties for thermal imprint lithography. In order to enhance the mechanical properties and toughness of dielectric material, various modified polyetherimide(PEI) was applied in the resin system. Curing behaviours, thermal stabilities, and dynamic mechanical properties of the dielectric materials cured with various conditions were studied using dynamic differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA), and Universal Test Method (INSTRON).

• Bulletin of the Korean Chemical Society
• /
• 제32권6호
• /
• pp.1965-1969
• /
• 2011

1,2,4,5-tetraoxane, mono and dinitrate glycerol carbonate ester derivatives of stearic acid were synthesized along with the known 9(10)-keto methyl sterate, methoxy mono-nitrate and dinitrate of methyl stearate. Their cetane numbers (CNs) were investigated to evaluate their viability for use as CN improvers. The CN performances of tetraoxane and all of the nitrate derivatives were investigated at 500 and 1000 ppm concentrations and compared to that of a traditional CN improver 2-ethylhexyl nitrate (2-EHN). The experimental results suggest that all derivatives evaluated in this study showed better CN improvement than base diesel fuel. Specifically, the 1,2,4,5-tetraoxane derivative of stearic methyl ester was superior to all derivatives studied, also being superior to 2-EHN. We also discussed the correlations between the observed CN trends and thermo-analytical data resulted from thermo gravimetric analysis curves (TGA) and differential scanning calorimetry (DSC).

• 폴리머
• /
• 제36권4호
• /
• pp.525-530
• /
• 2012

본 연구에서는 다양한 조성의 스티렌(styrene, St)과 3-(trimethoxy)propyl methacrylate(TMSPM)를 poly(ethylene-co-tetrafluoroethylene)(ETFE) 필름에 방사선 동시조사법으로 그래프트시킨 후 졸-젤 반응 및 설폰화 반응을 진행하여 실란 가교된 유/무기 복합막을 제조하였다. 졸-젤 반응을 통해 형성된 실란 가교 구조는 Fourier transform infrared spectroscopy(FTIR) 및 thermo gravimetric analysis(TGA)를 사용하여 관찰하였다. 설폰화 관능기를 도입하여 막을 제조한 후 유사한 이온교환용량을 가지면서 TMSPM의 함량이 다른 연료전지막을 선별하여 함수율, 치수 안정성, 수소이온전도도 등의 물성을 측정하였다. 또한 제조된 유/무기 복합막을 이용하여 membrane electrode assemblies(MEA)를 제조한 후 단위전지 성능을 평가하였다.

• 한국재난정보학회 논문집
• /
• 제19권3호
• /
• pp.532-544
• /
• 2023

연구목적: 신규로 사용되는 바이오연료를 기존 연료와 혼합하여 사용하는 경우 발생하는 위험성과 물성 변화를 열분석 방법(DSC, TGA)을 사용하여 화학 화재의 원인물질의 위험성을 확인하고, 평가할 방법과 그에 따른 물질의 위험성 관련 데이터를 확보함으로써 화재 원인 감식과 감정에 활용하기 위함이다. 연구방법: 본 실험에 사용된 연구 방법으로는 시차주사열량계(DSC : Differential Scanning Calorimeter)에 의하여 피크의 위치, 모양, 개수, 피크의 면적으로부터 열량 변화의 정량적인 정보를 통하여 열유속 차이(Difference in heat flux)를 측정하였고, 열중량분석(TGA : Analyzer)을 시행함으로써 특정한 온도에서 분해열 등에 의해 발생한 무게 변화를 연속적으로 측정하였다. 연구결과: 먼저 열 유속의 그래프에서 물질의 끓는점과 물질이 가지고 있는 고유 특성치 또는 분해에 필요한 에너지를 확인할 수 있다. 둘째 바이오디젤의 함량이 증가할수록 많은 피크를 확인 할 수 있었다. 셋째 비점이 낮은 물질들이 함유하고 있다는 것을 분석 결과로 확인할 수 있었다. 결론: 현재 새로운 에너지원으로 사용되고 있는 바이오디젤의 위험성을 다양한 물리·화학적 분석기법(DSC+TGA)을 통하여 사용함으로써 물질의 물적 위험성을 평가할 수 있음을 보여주었다. 아울러 본 연구의 시험방법별 차이의 비교와 실험에 대한 노하우를 축적하고 활용한다면 향후 위험물의 물성 연구와 물질 위험성 평가 연구에 있어 도움이 되리라 기대한다.

• Bulletin of the Korean Chemical Society
• /
• 제35권12호
• /
• pp.3535-3541
• /
• 2014

Bisphenol A is considered as pollutant, because it is toxic and hazardous to living organisms even at very low concentrations. Biological oxidation used for removing this organic from waste water is not suitable and consequently application of catalytic wet oxidation has been considered as one of the best options for treating bisphenol A. We have developed Fe/SBA-15, Ni/SBA-15 and Fe-Ni/SBA-15 as heterogeneous catalysts using the advanced impregnation method for oxidation of bisphenol A in water. The catalysts were characterized with physico-chemical characterization methods such as, powder X-ray diffraction (PXRD), FT-IR measurements, N2 adsorption-desorption isotherm, thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. This work illustrates activity of the catalysts for heterogeneous catalytic degradation reaction revealed with excellent conversion and recyclability. The degradation products identified were not persistent pollutants. GC-MS analysis identified the products: 2,4-hexadienedioic acid, 2,4-pentadienic acid and isopropanol or acetic acid. The leachability study indicated that the catalysts release very little metals to water. Therefore, the possibility of water contamination through metal leaching was almost negligible.

• 한국안전학회지
• /
• 제20권2호
• /
• pp.56-60
• /
• 2005

We studied fire properties of MOF(Metering Out Fit) insulation cover and field condition of 22.9kV power receiving system. $49.5\%$ of formal equipments were installed indoors, whereas $40.8\%$ of informal equipments were installed as H-type. Insulation treatment was not done at a $22.4\%$ ratio of main line($27.7\%$ of transformer, $70.2\%$ of COS, $10.4\%$ of MOF). Fire pattern analysis showed that the fire started at the secondary part of OC wire. In the result of DTA(Differential Thermal Analysis), normal cover showed exothermic reactions at $310^{\circ}C,\;399^{\circ}C\;and\;510^{\circ}C$ (endothermic reactions at $382^{\circ}C$). Whereas damaged cover showed exothermic reactions at $412^{\circ}C$(endothermic reactions at $389^{\circ}C$). In the result of TGA(Thermo Gravimetric Analysis), the thermal weight change of normal cover was similar compared to damaged cover. In the result of FT-IR analysis, normal cover showed absorption peaks at $3,024cm^{-l},\;2,921cm^{-l},\;1,600cm^{-1},\;1,492cm^{-1},\;1,451cm^{-1},\;1,154cm^{-l},\;1,027cm^{-1},\;906cm^{-1}$. Whereas, in case of tracked cover, the absorption peaks that were shown in normal cover disappeared and different absorption peak was shown at $966cm^{-1}$.

• 대한본초학회지
• /
• 제21권4호
• /
• pp.149-158
• /
• 2006

Objectives : This study was carried out to characterize the 'Kaolinitum' used as mineral medicine before and after physical and chemical manipulation. Methods : The mineralogy of the original raw kaolinitumes with different localities was identified by X-ray diffraction analysis. The concentrations of major, minor and trace elements of samples, furthermore, measured by the X-ray fluorescence spectrometer (XRF) and inductively coupled plasma-mass spectrometer (ICP-MS). In order to understand the variety of kaolinitum after thermal treatment, the differential thermal analysis (DTA) and the thermo-gravimetric analysis (TGA) were carried out. Results : According to the result of X-ray diffraction analysis, the kaolinitumes are composed ofcalcite, alunite and quartz. Si and Al are the major ions and heavy metals such as Cd, Cr, Pb, Zn, As, Ni and Cu are included in the kaolinitumes as trace ions. The concentration of these metals in the samples decreased after physical and chemical manipulation. The weight of kaolinitum was also decreased at $500^{\circ}C$ and about $700^{\circ}C$during experiment of TGA. Conclusion : The results of this study can be used to provide the scientific basis of the medical usage of kaolinitum.

• 한국화재소방학회논문지
• /
• 제27권4호
• /
• pp.41-46
• /
• 2013

본 연구는 가구류를 구성하는 주요 재료의 열적조건에 따른 반응특성과 화염전파해석에 필요한 열해리 물성을 제공하기 위해 열중량분석을 수행하였다. 실험대상 시편은 가구류에 널리 적용되는 MDF 판재와 코팅재, 합성피혁과 쿠션재 등이며 가열율 $10^{\circ}C/min$, 최대 온도 $600^{\circ}C$까지 실험을 수행하였다. 실험결과 MDF 소재의 경우 $324^{\circ}C$에서 피크 반응을 나타냈었으며 MDF 코팅재의 경우 초기 피크반응온도가 $270{\sim}280^{\circ}C$로 감소하였다. 합성피혁과 폼 소재의 경우 재료를 구성하는 폴리머의 종류에 따라 기준온도와 기준 반응율이 차이를 보였으나 기준온도는 $270^{\circ}C$와 $420^{\circ}C$ 정도로 비교적 유사한 경향을 나타냈다. Lyon 등이 제시한 방법에 의해 반응상수와 활성화 에너지를 산정하기 위해 시편의 기준 온도와 기준 반응율을 제시하였으며 이러한 기초 물성연구를 통해 화염전파특성을 이해함과 동시에 화재해석의 신뢰성을 향상시키는데 기여하고자 한다.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2004년도 춘계학술발표대회 논문집
• /
• pp.190-193
• /
• 2004

Two different diene monomers [dicyclopentadiene (DCPD) and 5-ethylidene-2-norbomene (ENB)] as self­healing agent for polymeric composites were microencapsuled by in-situ polymerization of urea and formaldehyde. The healing agents were investigated by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). Exothermic reaction and glass transition temperature from DSC and storage modulus (G') and tan $\delta$ from DMA curves were analyzed for the samples cured for 5 min and 24 h in the presence of different amounts of catalyst. Micorcapsules were successfully formed for both diene monomers. Microcapsules containing the healing agent were manufactured and its thermal properties were characterized by thermo gravimetric analysis (TGA). Optical microscope (OM) and particle size analyzer (PSA) were employed to observe morphology and size distribution of microcapsules, respectively. Comparison of the two self-healing agents and their microcapsules with the two was made in this study.

• 폴리머
• /
• 제31권1호
• /
• pp.31-36
• /
• 2007

플라스마 표면처리는 전체적인 물성은 유지하고 표면의 특성만을 변화시킨다고 전해지고 있다. 이번 연구에서는 플라스마 처리에 의해 높은 발수성을 나타내는 나일론 6 섬유로의 개질을 시도하였다. 발수성을 나타내는 나일론 섬유는 가스 종류, 처리시간, 인가 파워를 변수로 하여 RF 진공 플라스마 시스템에서 처리되었다. 플라스마 처리된 섬유의 표면을 scanning electron microscopy(SEM)과 atomic force microscopy(AFM)으로 모폴로지 변화를 살펴보았으며, 기계적 특성과 고분자 고유의 특성을 인장강도와 Differential scanning calorimetry(DSC), thermo-gravimetric analysis (TGA)로 각각 분석하였다. 또한 나일론 섬유의 발수성 평가는 물방울 흡수시간으로 테스트를 실시하였다. 이러한 결과들은 플라스마 표면처리로 인해서 나일론 섬유의 발수성이 향상됨을 나타내었다.