• 제목/요약/키워드: Thermally stable

검색결과 343건 처리시간 0.029초

Synthesis and Properties of Novel Flame-Retardant and Thermally Stable Poly(amideimide)s from N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino Acids and Phosphine Oxide Moiety by Two Different Methods

  • Faghihi, Khalil;Hajibeygi, Mohsen;Shabanian, Meisam
    • Macromolecular Research
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    • 제17권10호
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    • pp.739-745
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    • 2009

  • N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids 3a-g were synthesized by the condensation reaction of bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride 1 with two equimolars of Lalanine 2a, L-valine 2b, L-leucine 2c, L-isoleucine 2d, L-phenyl alanine 2e, L-2-aminobutyric acid 2f and L-histidine 2g in an acetic acid solution. Seven new poly(amide-imide)s PAIs 5a-g were synthesized through the direct polycondensation reaction of seven chiral N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids 3a-g with bis(3-amino phenyl) phenyl phosphine oxide 4 by two different methods: direct polycondensation in a medium consisting of N-methyl-2-pyrrolidone (NMP)/triphenyl phosphite (TPP)/calcium chloride ($CaCl_2$/pyridine (py), and direct polycondensation in a tosyl chloride (TsCl)/pyridine (py)/N,N-dimethylformamide (DMF) system. The polymerization reaction produced a series of flame-retardant and thermally stable poly(amide-imide)s 5a-g with high yield. The resulted polymers were fully characterized by FTIR, $^1H$ NMR spectroscopy, elemental analyses, inherent viscosity, specific rotation and solubility tests. Data obtained by thermal analysis (TGA and DTG) revealed that the good thermal stability of these polymers. These polymers can be potentially utilized in flame retardant thermoplastic materials.

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열적으로 성충화된 횡단류에 분류된 제트의 난류확산 거동 (II) (Turbulent Dispersion Behavior of a Jet issued into Thermally Stratified Cross Flows (II))

  • 김상기;김경천
    • 대한기계학회논문집B
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    • 제23권11호
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    • pp.1434-1443
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    • 1999

  • The turbulent fluctuations of temperature and two components of velocity have been measured with hot- and cold-wires in the Thermally Stratified Wind Tunnel(TSWT). Using the fin-tube heat exchanger type heaters and the neural network control algorithm, both stable ($dT/dz=109.4^{\circ}C$) and unstable ($dT/dz=-49.1^{\circ}C$) stratifications were realized. An ambient air jet was issued normally into the cross flow($U_{\infty}=1.0 m/s$) from a round nozzle(d = 6 mm) flushed at the bottom waII of the wind tunnel with the velocity ratio of $5.8(U_{jet}/U_{\infty})$. The characteristics of turbulent dispersion in the cross flow jet are found to change drastically depending on the thermal stratification. Especially, in the unstable condition, the vertical velocity fluctuation increases very rapidly at downstream of jet. The fluctuation velocity spectra and velocity-temperature cospectra along the jet centerline were obtained and compared. In the case of stable stratification, the heat flux cospectra changes Its sign from a certain point at the far field because of the restratification phenomenon. It is inferred that the main reason in the difference between the vertical heat fluxes is caused by the different length scales of the large eddy motions. The turbulent kinetic energy and scalar dissipation rates were estimated using partially non-isotropic and isotropic turbulent approximation. In the unstable case, the turbulent energy dissipation decreases more rapidly with the downstream distance than in the stable case.

  • https://doi.org/10.22634/KSME-B.1999.23.11.1434 인용 PDF

Formation Temperature Dependence of Thermal Stability of Nickel Silicide with Ni-V Alloy for Nano-scale MOSFETs

  • Tuya, A.;Oh, S.Y.;Yun, J.G.;Kim, Y.J.;Lee, W.J.;Ji, H.H.;Zhang, Y.Y.;Zhong, Z.;Lee, H.D.
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2005년도 추계종합학술대회
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    • pp.611-614
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    • 2005

  • In this paper, investigated is the relationship between the formation temperature and the thermal stability of Ni silicide formed with Ni-V (Nickel Vanadium) alloy target. The sheet resistance after the formation of Ni silicide with the Ni-V showed stable characteristic up to RTP temperature of $700\;^{\circ}C$ while degradation of sheet resistance started at that temperature in case of pure-Ni. Moreover, the Ni silicide with Ni-V indicated more thermally stable characteristic after the post-silicidation annealing. It is further found that the thermal robustness of Ni silicide with Ni-V was highly dependent on the formation temperature. With the increased silicidation temperature (around $700\;^{\circ}C$), the more thermally stable Ni silicide was formed than that of low temperature case using the Ni-V.

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A Boundary Element Solution Approach for the Conjugate Heat Transfer Problem in Thermally Developing Region of a Thick Walled Pipe

  • Choi, Chang-Yong
    • Journal of Mechanical Science and Technology
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    • 제20권12호
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    • pp.2230-2241
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    • 2006

  • This paper presents a sole application of boundary element method to the conjugate heat transfer problem of thermally developing laminar flow in a thick walled pipe when the fluid velocities are fully developed. Due to the coupled mechanism of heat conduction in the solid region and heat convection in the fluid region, two separate solutions in the solid and fluid regions are sought to match the solid-fluid interface continuity condition. In this method, the dual reciprocity boundary element method (DRBEM) with the axial direction marching scheme is used to solve the heat convection problem and the conventional boundary element method (BEM) of axisymmetric model is applied to solve the heat conduction problem. An iterative and numerically stable BEM solution algorithm is presented, which uses the coupled interface conditions explicitly instead of uncoupled conditions. Both the local convective heat transfer coefficient at solid-fluid interface and the local mean fluid temperature are initially guessed and updated as the unknown interface thermal conditions in the iterative solution procedure. Two examples imposing uniform temperature and heat flux boundary conditions are tested in thermally developing region and compared with analytic solutions where available. The benchmark test results are shown to be in good agreement with the analytic solutions for both examples with different boundary conditions.

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