• Journal of Powder Materials
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• v.15 no.3
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• pp.188-195
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• 2008

Carbon nanotube (CNT)/$Mg_2Ni$ composites were synthesized to enhance the hydrogen storage properties. The emphasis was made on the effect of different shortening methods of CNTs on the open-tip structure and the resulting properties. The use of open CNTs as a starting material resulted in an enhanced hydrogen properties of CNT/$Mg_2Ni$ composites. Among the employed methods for the shortening of CNTs, wet milling using ethanol was the most efficient, while ultrasonic acid treatment or thermal decomposition resulted in a less hydrogen storage capacity.

• New & Renewable Energy
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• v.17 no.1
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• pp.33-39
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• 2021

The energy use is increasing as the quality of human life improves. and research on the efficient use of energy in ESS (Energy Storage System) is ongoing. An air conditioner is required for the efficient use of an ESS, as are data on the distribution of the temperature of the latter based on the capacity of the air conditioner. In the absence of an air conditioner, the battery of the ESS reaches its maximum temperature of 40℃ after 2 h. When an air conditioner is present, the temperature of the battery stabilizes as the capacity of the former increases.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.43 no.5
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• pp.555-566
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• 2023

In this study, a composite phase change material (CPCM) produced using the SOL-GEL technique was developed as a thermal energy storage medium for low-temperature applications. Tetradecane and activated carbon (AC) were used as the core and supporting materials, respectively. The tetradecane phase change material (PCM) was impregnated into the porous structure of AC using the vacuum impregnation method, and a thin layer of silica gel was coated on the prepared composite using the SOL-GEL process, where tetraethyl orthosilicate (TEOS) was used as the silica source. The thermal performance of the CPCM was analysed using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). DSC results showed that the pure tetradecane PCM had melting and freezing temperatures of 6.4℃ and 1.3℃ and corresponding enthalpies 226 J/g and 223.8 J/g, respectively. The CPCM exhibited enthalpy of 32.98 J/g and 27.7 J/g during the melting and freezing processes at 7.1℃ and 2.4℃, respectively. TGA test results revealed that the AC is thermally stable up to 500℃, which is much higher than the decomposition temperature of the pure tetradecane, which is around 120℃. Moreover, in the case of AC-PCM and CPCM thermal degradation started at 80℃ and 100℃, respectively. The chemical stability of the CPCM was studied using Fourier-transform infrared (FT-IR) spectroscopy, and the results confirmed that the developed composite is chemically stable. Finally, the surface morphology of the AC and CPCM was analysed using scanning electron microscopy (SEM), which confirmed the presence of a thin layer of silica gel on the AC surface after the SOL-GEL process.

• Journal of Biosystems Engineering
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• v.19 no.3
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• pp.211-221
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• 1994

In this study, to maximize the solar energy utilization for greenhouse heating during the winter season, solar energy-underground latent heat storage system was constructed, and the thermal performance of the system has been analyzed to obtain the basic data for realization of greenhouse solar heating system. The results are summarized as follows. 1. $Na_2SO_4{\cdot}10H_20$ was selected as a latent heat storage material, its physical properties were stabilized and the phase change temperature was controlled at $13{\sim}15^{\circ}C$. 2. Solar radiation of winter season was the lowest value in December, and Jinju area was the highest and the lowest value was shown in Jeju area. 3. The minimum inner air temperature of greenhouse with latent heat storage system(LHSS) was $7.0{\sim}7.5^{\circ}C$ higher than that of greenhouse without LHSS and was $7.0{\sim}11.2^{\circ}C$ higher than the minimum ambient air temperature. 4. Greenhouse heating effect of latent heat storage system was getting higher according to the increase of solar radiation and was not concerned with the variation of minimum ambient air temperature. 5. The relative humidity of greenhouse with latent heat storage system was varied from 50 to 85%, but that of greenhouse without LHSS was varied from 30 to 93%. 6. The heating cost of greenhouse with solar energy-latent heat storage system was about 24% of that with the kerosene heating system.

• Journal of Hydrogen and New Energy
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• v.16 no.3
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• pp.262-268
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• 2005

[ $Zn(BH_4)_2$ ](8.4 wt% theoretical hydrogen storage capacity powders have been successfully synthesized by mechanochemical reaction from mixtures of $ZnCl_2$ and $NaBH_4$ powders in a 1:2 molar ratio in different times. $$ZnCl_2+2NaBH_4{\rightarrow}Zn(BH_4)_2+2NaCl$$ (1) $Zn(BH_4)_2$ powders were characterized by X-ray diffractometry(XRD), and Furier Transform Infrared spectrometry(FT-IR). The thermal stabilities of $Zn(BH_4)_2$ powders were studied by Differential scanning calorimetry(DSC), Thermogravimetry analysis(TGA), and Mass spectrometry(MS). $Zn(BH_4)_2$ can be tested for hydrogen evolution without further purification. The reaction to yield hydrogen is irreversible, the other products being compounds of Zn, and borane. $Zn(BH_4)_2$ thermally decomposes to release borane and hydrogen gas between about 85 and 150$^{\circ}C$.

• Journal of the Korean Society of Industry Convergence
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• v.14 no.3
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• pp.87-93
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• 2011

When applying back panel(this material is aluminum complex panel coated with fire resistance substances) for curtain wall, solar radiation and heat storage of indoor air occurs to result in thermal warpage for back panel. The purpose of this analysis is to find out the cause of thermal warpage and come up with a solution to prevent changes of back panel and reduce elements that bring negative visual elements. Also to solve this problem analyse that case to reduce heat transfer by inserting additional material and cases to increase air space distance.

• Journal of Hydrogen and New Energy
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• v.34 no.5
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• pp.431-438
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• 2023

Recently, study on hydrogen is being conducted due to environmental pollution and fossil fuel depletion. High-pressure gas hydrogen commonly used is applied to vehicle and tube trailers. In particular, high-pressure hydrogen storage tank for vehicles must comply with the guidelines stipulated in SAE J2601. There is a charging temperature limitation condition for the safety of the storage tank material. In this study, numerical analysis method were verified based on previous studies and the nozzle angle was changed for thermal management to analyze the increase in forced convection effect and energy uniformity due to the promotion of circulation flow. The previously applied high-pressure hydrogen storage tank has a length/diameter ratio of about 2.4 and was analyzed by comparing the length/diameter ratio with 8. As a result, the circulation flow of hydrogen flowing into the high-pressure hydrogen storage tank is promoted at a nozzle angle of 30° than the straight nozzle and accordingly, the effect of suppressing temperature rise by energy uniformity and forced convection was confirmed.

• Journal of the Korean Solar Energy Society
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• v.39 no.5
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• pp.65-78
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• 2019

In this study, we investigated the paraffin encapsulation using double-walled encapsulation technique. The first encapsulation used methyl methacrylic acid as the main component in acrylic polymer and the second encapsulation used melamine polymer. Particles size and distribution of the capsules were analyzed using scanning electron microscopy. In the first encapsulation, the stable capsules were obtained at 67% of phase change material ratio to methyl methacrylic acid monomer and the size of the capsule was from 0.2 to $0.3{\mu}m$. In the second encapsulation, the size of the capsules was almost the same with those capsules prepared in the first encapsulation. The particle size of single wall and double wall was about $0.3{\mu}m$. As a result of the encapsulation of paraffin using double-walled encapsulation technique, it was confirmed that the particle size was determined in the process of encapsulating using the acrylic polymer at the first wall material, and the physical and thermal stability of the capsules were imparted using melamine at the secondary wall material.

• Journal of Hydrogen and New Energy
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• v.26 no.5
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• pp.469-476
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• 2015

The purpose of this work is to investigate main factors to design a solid-state hydrogen stroage system with magnesium hydride with 10 wt% graphite using numerical simulation tools. The heat transfer characteristic of this material was measured in order to perform the highly reliable simulation for this system. Based on the measured effective thermal conductivity, a transient heat and mass transfer simulation revealed that the total performance of hydrogen storage system is prone to depend on heat and mass transfer behaviors of hydrogen storage medium instead of its inherent kinetic rate for hydrogen adsorption. Furthermore, we demonstrate that the thermodynamic aspect between equlibrium presssure and temperature is one of key factor to design the hydrogen storage system with high performance using magnesium hydride.

• Journal of Bio-Environment Control
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• v.7 no.3
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• pp.214-218
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• 1998

This study was performed to stabilize the physical properties of Sodium Carbonate Decahydrate that was selected as a highly concentrative thermal energy storage medium. The addition of ARS(additives to prevent supercooling) showed to prevent the supercooling of Na$_{2}$CO$_{3}$.10H$_{2}$O, and the supercooling was decreased below $1.5^{\circ}C$ with ARS of 3 wt% and the addition of PSC(phase separation controller) of 1.5 wt% controlled the phase separation of Na$_{2}$CO$_{3}$ .10H$_{2}$O with the phase change cycles increased from 0 to 1,500, the phase change temperature and the latent heat has changed in the range of 30$\pm$1.$0^{\circ}C$ and 54$\pm$2.0Kcal.kg$^{-1}$ respectively.