• Title/Summary/Keyword: Thermal exposure

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Oxidation Characteristic Changes in Insulation Oil Depending upon Storage Environments and Oil Resources (저장 환경 및 원료에 따른 전기절연유 산화특성 연구)

  • Lee, Don-Min;Park, Cheon-Kyu;Ha, Jong-Han;Lee, Bong-Hee
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.495-501
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    • 2016
  • Mineral oil has been widely used as an insulating oil for electrical transformers for a long time, but the necessity of employing new insulation oil such as vegetable oil has been increased due to urgent needs for the biodegradability when it leaks and also for the thermal stability at a higher operation temperature. Although specific periods are required between the production and consumption, there are still short of the data to prove the insulation oils' storage stability depending upon various circumstances and their resources. Thus, this paper demonstrates the insulation oils' oxidation characteristics of both mineral and vegetable oils when each was exposed to different environments for 12 weeks. From this test, some properties including total acid number, water content and dielectric breakdown were changed under specific conditions and resources. Vegetable oils showed higher hydrophilicity and water saturation than those of mineral oils due to their molecular compositions. Under sunlight exposure condition, all insulation oils oxidized and changed their properties when exposing to the direct light, regardless of the resource used.

Synthesis and Photoalignment of Soluble Polyimides with Styrylpyridine Side Groups (스티릴피리딘 곁사슬기를 가지는 용해성 폴리이미드의 합성과 광배향)

  • Kim, Jin-Woo;Kim, Min-Woo;Ahn, Deuk-Kyoon;Kim, Woo-Sik
    • Polymer(Korea)
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    • v.33 no.3
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    • pp.207-212
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    • 2009
  • The precursor polyimide of the photoreactive polyimides(PI-SP6 and PI-SP12) was prepared from a derivative of 2, 2, 2-trifluoroethane dianhydride and 3,3'-dihydroxy-4,4'-diaminobiphenyl. PI-SP6 and PI-SP12 were then prepared by the polymer reactions of the precursor polyimide with photoreactive 2-styrylpyridine alkylene (hexylene and dodecylene) derivatives, respectively. The photoreactive polymers were soluble in organic solvents. The polymers showed the initial decomposition temperatures around $350^{\circ}C$. The glass transition temperatures of PI-SP6 and PI-SP12 were found to be $130^{\circ}C$ and $85^{\circ}C$, respectively. This result means that the latter polymer is more flexible than the former polymer. Their transmittance in the film state was 90% at $250^{\circ}C$, which indicates that the photosensitive polyimides with thermal stability have high optical transparency even at the high temperature. The respective dichroic ratios of PI-SP6 and PI-SP12 were found to be 0.01 and 0.03 at an exposure energy of $1.5\;J/cm^2$. This result suggests that the latter polymer with larger flexibility compared to the former polymer is more effective for the photoalignment.

A STUDY ON THE MARGINAL LEAKAGE OF RESTORATIONS WITH DIFFERENT CAVOSURFACE MARGINS (와연형태(窩緣形態)에 따른 와연누출(邊緣漏出)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Shin, Han-Ju;Choi, Ho-Young;Min, Byung-Soon;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.12 no.1
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    • pp.119-129
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    • 1986
  • The purpose of this study was to evaluate the marginal leakage of glass ionomer cement with different cavosurface margins. 192 class V cavities were prepared on freshly extracted non-carious teeth and glass ionomer cement were inserted according to the manufacturer's instructions. Cavity preparations for this investigation were performed in four groups. The experimental specimens were made by packing the glass ionomer cement (Fuji Ionomer Type II G-C Co. Japan) into the prepared 192 cavities of four groups with different modes: Group I. - The 48 cavities with $90^{\circ}$ butt-joint cavosurface preparation and restored with glass ionomer cement. Group II. - The 48 cavities with butt-joint preparation modified by $135^{\circ}$ beveling the cavosurface in the dentin and restored with glass ionomer cement. Group III. - The 48 cavities with butt-joint preparation modified by cutting a chamfer in the dentin and restored with glass ionomer cement. Group IV. - The same 48 cavities as group I, and overfilled with glass ionomer cement beyond the cavosurface angle. And four groups above described divided into three subgroups by means of conditioning the cavity walls: Control group. - Glass ionomer cement filled in the prepared 64 cavities after being cleaned with a stream of tap water. Phosphoric acid treatment group. - Glass ionomer cement filled in the prepared 64 cavities after being conditioned with a 50% phosphoric acid. Citric acid treatment group. - Glass ionomer cement filled in the prepared 64 cavities after being conditioned with a 50% citric acid. All 192 specimens were immersed in the 2.0% basic fuchsin solution and subjected to thermal stress at one-minute intervals ($4{\pm}2^{\circ}C$ to $60{\pm}2^{\circ}C$) for 70 minutes before exposure to the dye. The specimens were sectioned ecclesiologically through the center of the restorations for different periods of immersion time, 24 hours, 7 days, 14 days 30 days. The sections were examined under a stereoscopic microscope. The results were as follows: 1. The degree of marginal leakage in group II and III was greater than that in group I and IV. 2. The degree of marginal leakage in phosphoric acid treatment group was similar with that in control group. 3. The degree of marginal leakage in citric acid treatment group was less than that in control group. 4. In all groups, the degree of marginal leakage in phosphoric acid treatment group was greater than that in citric acid treatment group. 5. There is no statistical difference of the degree of marginal leakage according to the immersion time in the dye solution.

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Climate Change-induced High Temperature Stress on Global Crop Production (기후변화로 인한 작물의 고온 스트레스 전망)

  • Lee, Kyoungmi;Kang, Hyun-Suk;Cho, ChunHo
    • Journal of the Korean Geographical Society
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    • v.51 no.5
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    • pp.633-649
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    • 2016
  • Exposure to high temperatures during the reproductive period of crops decreases their productivity. The Intergovernmental Panel on Climate Change's (IPCC) fifth Assessment Report predicts that the frequency of high temperatures will continue to increase in the future, resulting in significant impacts on the world's food supply. This study evaluate climate change-induced heat stress on four major agricultural crops (rice, maize, soybean, and wheat) at a global level, using the coupled atmosphere-ocean model of Hadley Centre Global Environmental Model version 2 (HadGEM2-AO) and FAO/IIASA Global Agro-Ecological Zone (GAEZ) model data. The maximum temperature rise ($1.8-3.5^{\circ}C$) during the thermal-sensitive period (TSP) from the baseline (1961-1990) to the future (2070-2090) is expected to be larger under a Representative Concentration Pathway (RCP) 8.5 climate scenario than under a RCP2.6 climate scenario, with substantial heat stress-related damage to productivity. In particular, heat stress is expected to cause severe damage to crop production regions located between 30 and $50^{\circ}N$ in the Northern Hemisphere. According to the RCP8.5 scenario, approximately 20% of the total cultivation area for all crops will experience unprecedented, extreme heat stress in the future. Adverse effects on the productivity of rice and soybean are expected to be particularly severe in North America. In Korea, grain demands are heavily dependent on imports, with the share of imports from the U.S. at a particularly high level today. Hence, it is necessary to conduct continuous prediction on food security level following the climate change, as well as to develop adaptation strategy and proper agricultural policy.

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Introduction of Dental X-ray Imaging with New Concept - intra Oral x-ray Tube (신개념 치과용 X-선 영상장치 소개 - 강내형 X-선 튜브)

  • Cho, Sung-Ho;Kim, Dong-Young;Baek, Kwang-Woo;Lee, Re-Na
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.48 no.4
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    • pp.94-101
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    • 2011
  • Various kinds of medical imaging devices have been studied to develop periapical radiography. However, there are some problems such as high x-ray exposure rate and pains for patients because of the problems caused by intra-oral sensor based radiography system. In this study, a new concept of periapical radiography, intra oral X-ray tube and detector system, is introduced to solve these problems. This system is made up of miniature X-ray tube based on subminiature thermal electron or cold electron, CMOS based detector, and a body including automatic position and system control devices. In order to confirm the possibility of proposed new concept to periapical radiography, miniature x-ray tube from XOFT corporation is used to develop new x-ray system, and the performance evaluation of this system is performed according to collimator. Also, dental images are compared after acquiring both images from existing system versus new concept of system. As a result, new concept of system showed excellent image. Thus, it is considered that new concept of system will have a significant effect on medical imaging technology.

Effect of acute heat stress on feed intake and plasma concentrations of tumor necrosis factor-α and free amino acids in growing pigs

  • Kim, Byeonghyeon;Kim, Minji;Kim, Hye Ran;Ji, Sang Yun;Kim, Ki Hyun;Chun, Ju Lan;Baek, Youl-Chang;Lee, Yookyung;Jeong, Jin Young;Lee, Sung Dae
    • Korean Journal of Agricultural Science
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    • v.47 no.3
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    • pp.597-604
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    • 2020
  • Exposure to heat stress (HS) has negative effects on pig production and health. Plasma concentrations of amino acids (AAs) can be used as indicators of HS. Therefore, this study was conducted to evaluate the effect of acute HS on feed intake, water drink, and plasma AAs in pigs. A total of 6 growing pigs (n = 6, 3 boars and 3 gilts) were raised in thermal neutral (TN; 25℃) conditions for the 5-d adaptation period as a control. After the adaptation, pigs were exposed to HS at 33℃ (HS33) for 24 h. All the pigs were fed the same diet formulated to meet or exceed predicted requirements during the whole experimental period. Blood samples were collected after the adaptation and heat treatment to verify the AAs. Measurements were the average daily feed intake (ADFI), average daily water intake (ADWI), water loss, tumor necrosis factor (TNF)-α, nitrate, total nitric oxide, and AAs in the plasma samples. Data were analyzed using the PROC GLM of SAS. HS33 had a lower ADFI (p < 0.05) and a tendency for an increased ADWI and water loss compared to TN. The level of TNF-α was significantly decreased (p < 0.05) in HS33. HS33 had a lower concentration of histidine and sarcosine compared to TN; however, there were no differences in the levels of nitrates and total nitric oxide. In conclusion, the results of this study show the differential effect of HS on the plasma concentration of AAs. We expect that the changed AAs could be potential indicators of HS.

The Effects of Nd:YAG Laser Irradiation on the Root Surface;A Scanning Electron Microscopic Study (Nd:YAG 레이저 조사시 치근면에 미치는 효과에 관한 주사전자현미경적 연구)

  • Lee, Su-Jeong;Kim, Soo-Ah;Seo, Seok-Ran;Kim, Hyung-Seop
    • Journal of Periodontal and Implant Science
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    • v.27 no.3
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    • pp.495-514
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    • 1997
  • The purpose of this study was to evaluate the in vitro effects of Nd:YAG laser irradiation on removal of a root surface smear layer after root planing in comparison with Tetracycline HCl. The 60 extracted human teeth due to severe periodontal disease were vigorously scaled and root planed with Gracey curet. Thirty specimen($5{\times}5{\times}2mm$) were obtained from root planed surface of 30 human teeth and assigned randomly to one of three groups : root planed group(5 specimen), Tetracycline HCI group(5 specimen, burnished for 5 minutes), and Nd:YAG laser group(25 specimen, German Dental Laser, Fotona Twinlight). Nd:YAG laser group was divided into 4 subgroups according to power of 1W, 1.5W, 2W, 3W at frequency to 10Hz. The specimen were then fixed, and examed by Scanning electron microscopic study. 30 of 60 human teeth used to measurement of the intrapulpal temperature rise during laser irradiation. Laser-irradiated surface exhibited various surface texture from relative flat surface to irregular surface with patent dentinal tubules of various shape and size. In some area, the root surface alteration which are carbonization, pit and crater formation and melting and resolidification were observed. The number of exposed dentinal tubules per unit($100_{\mu}m^2$) on tetracycline HCI group was more than that in the laser group below 1.5W of power(150mJ/pulse) and was significantly less than that in laser group above 2W of power(200mJ/pulse)(P<0.OOl). As power increased the intrapulpal temperature rise also increased. The result suggested that the parameter which effectively remove root surface smear layer than tetracycline HCI may cause thermal damage to pulp and root surface alteration result from laser exposure would indicate need for additional instrumentation. Thus, Nd:YAG laser irradiation in these parameter may not be appropriate for clinical use as adjunct to conventional periodontal therapy.

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Deactivation Behavior of K2CO3 Catalyst in the Steam Gasification of Kideco Coal (Kideco 석탄의 스팀 가스화 반응에서 K2CO3 촉매의 비활성화 거동)

  • VICTOR, PAUL;KIM, SOOHYUN;YOO, JIHO;LEE, SIHYUN;RHIM, YOUNGJOON;LIM, JEONGHWAN;KIM, SANGDO;CHUN, DONGHYUK;CHOI, HOKYUNG;RHEE, YOUNGWOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.517-525
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    • 2016
  • The present work investigates the effect of $K_2CO_3$ catalyst on steam gasification of Kideco coal and the deactivation of the catalyst due to thermal exposure and interaction with coal ash. The gasification reactivity at $700^{\circ}C$ is highly enhanced by $K_2CO_3$, which is not deactivated by the heat treatment at $T{\leq}800^{\circ}C$. TGA and XRD results prove minor decomposition of $K_2CO_3$ after the calcination at $800^{\circ}C$. $K_2CO_3$ is, however, evaporated at the higher temperature. Assuming the conversion of $K_2CO_3$ into $K_2O$ by the decomposition and into $K_2O{\cdot}2.5SiO_2$ and $KAlO_2$ by the interaction with coal ash, the reactivity of the gasification is evaluated in the presence of $K_2O$, $K_2O{\cdot}2.5SiO_2$ and $KAlO_2$. Among them, $K_2O$ is the most active, but much lower in the activity than $K_2CO_3$. XRD results show that $K_2CO_3$ could react readily with the ash above $700^{\circ}C$.

State-of-Arts of Primary Concrete Degradation Behaviors due to High Temperature and Radiation in Spent Fuel Dry Storage (사용후핵연료 건식저장 콘크리트의 고열과 방사선으로 인한 주요 열화거동 분석)

  • Kim, Jin-Seop;Kook, Donghak;Choi, Jong-Won;Kim, Geon-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.243-260
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    • 2018
  • A literature review on the effects of high temperature and radiation on radiation shielding concrete in Spent Fuel Dry Storage is presented in this study with a focus on concrete degradation. The general threshold is $95^{\circ}C$ for preventing long-term degradation from high temperature, and it is suggested that the temperature gradient should be less than $60^{\circ}C$ to avoid crack generation in concrete structures. The amount of damage depends on the characteristics of the concrete mixture, and increases with the temperature and exposure time. The tensile strength of concrete is more susceptible than the compressive strength to degradation due to high temperature. Nuclear heating from radiation can be neglected under an incident energy flux density of $10^{10}MeV{\cdot}cm^{-2}{\cdot}s^{-1}$. Neutron radiation of >$10^{19}n{\cdot}cm^{-2}$ or an integrated dose of gamma radiation exceeding $10^{10}$ rads can cause a reduction in the compressive and tensile strengths and the elastic moduli. When concrete is highly irradiated, changes in the mechanical properties are primarily caused by variation in water content resulting from high temperature, volume expansion, and crack generation. It is necessary to fully utilize previous research for effective technology development and licensing of a Korean dry storage system. This study can serve as important baseline data for developing domestic technology with regard to concrete casks of an SF (Spent Fuel) dry storage system.

Sterilization of Rapeseed Sprouts by Intense Pulsed Light Treatment (고강도 광원을 이용한 새싹 채소의 살균)

  • Park, Heeran;Cha, Gyung-Hee;Shin, Jung-Kue
    • Korean Journal of Food Science and Technology
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    • v.48 no.1
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    • pp.36-41
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    • 2016
  • In this study, the effects of intense pulsed light (IPL) treatment on microbial inactivation and quality in rapeseed sprouts were investigated. Untreated rapeseed sprouts exhibit a high level of total aerobic bacteria (TAB) ($1.2{\times}10^7CFU/g$), coliform bacteria (coliform) ($3.3{\times}10^6CFU/g$), and pathogenic E. coli (PE) ($2.1{\times}10^5CFU/g$). The microorganisms found on rapeseed sprouts decreased with exposure to increasing light intensity and treatment time. The greatest reduction in microbial content was observed with a treatment of 1000 V, 5 pps for 10 min, where TAB, coliform, and PE levels decreased to 1.0 log CFU/g, 1.6 log CFU/g, and 1.8 log CFU/g, respectively. In agreement with these data, the microbial inactivation rate increased with the increase in the distance between the light source and the samples during IPL treatment. After IPL treatment of rapeseed sprouts, water content and vitamin C content decreased.