• Title/Summary/Keyword: Thermal expansion data

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The Nature of Water in Tactic Poly (2-Hydroxyethyl Methacrylate) Hydrogels

  • Kim, Eui-Hwan;Jeon, Sang-Il;Yoon, Sung-Chul;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.2 no.2
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    • pp.60-66
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    • 1981
  • The hypothesis that three classes of water exist in hydrogels, namely X water (free water-like), Z-water (bound water-like), and Y water (interfacial water-like), has been verified and generally accepted. To further check the validity of this hypothesis and to study the nature of X, Y, and Z water as conformation changes, several experiments have been done using Tactic Poly(2-hydroxyethyl methacrylate) (P-HEMA) gels. Thermal expansively data for tactic P-HEMA gel was obtained. In each case of isotactic and syndiotactic P-HEMA, the higher water content gels showed an extremely sharp volume change at $0^{\circ}C$, indicating the presence of normal free water-like. Lower water content gels showed no anomalous change in thermal expansion, indicating that the water is bound water-like. The medium water content gels exhibited intermediate behavior. These results were also confirmed by bulk gel conductivity measurments. The differential scanning calorimeter(DSC) experiment was simply introduced to further verify the bound water-like quantities which was obtained by the method of dilatometry and specific conductivity. Observing the amounts of X, Y, and Z water with the change of tacticity, the similar content of bound water-like may be due to the same primary structure of isotactic and syndiotactic polymer and the difference in free and interfacial water-like content may be due to the difference in secondary and tertiary structure of tactic polymer. Therefore, as the polymer conformation varies, the free and interfacial water-like content will be varied. In order to demonstrate these concepts, Russel et al.'s CPK space-filling molecular models of isotactic and syndiotactic P-HEMA was utilized.

Feasibility Study to Actively Compensate Deformations of Composite Structure in a Space Environment

  • Farinelli, Ciro;Kim, Hong-Il;Han, Jae-Hung
    • International Journal of Aeronautical and Space Sciences
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    • v.13 no.2
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    • pp.221-228
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    • 2012
  • An active compensation method for the deformation of composite structures using additional controllable metal parts is proposed, and its feasibility is experimentally investigated in a simulated space environment. Composite specimens are tested in a vacuum chamber, which is able to maintain pressure on the order of 10-3 torr and interior temperature in the range of ${\pm}30^{\circ}C$. The displacement-measuring interferometer system, which consists of a heterodyne HeNe laser and an interferometer, is used to measure the displacement of the whole structure. Meanwhile, the strain of the composite part and temperature of both parts are measured by fiber Bragg grating sensors and thermistors, respectively. The displacement of the composite structure is maintained within a tolerance of ${\pm}1{\mu}m$ by controlling the elongation of the metal part, which is bonded to the end of the composite part. Also, the possibility of fiber Bragg grating sensors as control input sensors is successfully demonstrated using a proper corrective factor based on the specimen temperature gradient data.

ABLATION OF PTFE NOZZLE DRIVEN BY ARC PLASMA (아크 플라즈마에 의한 PTFE 노즐 용삭현상)

  • Lee J.C.;Kim Y.J.
    • 한국전산유체공학회:학술대회논문집
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    • 2005.10a
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    • pp.311-317
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    • 2005
  • It has been the most progressive interruption technique to use the ablation gas from the surface of PTFE nozzle driven by arc plasma during switching process in $SF_6$ gas circuit breakers. This advanced interruption technique can reduce the required mechanical energy to compress and blow the gas for extinguishing the arc plasma between the electrodes due to using the ablation effect instead. In order to consider the phenomena during calculation of switching process, it is required to confirm the principles of ablation from PTFE nozzle as well as of arc plasma during switching process. In this study, we have calculated the switching process considered the ablation of PTFE nozzle driven by arc plasma using multidisciplinary simulation technique and compared the results with the data without the ablation effect. More $50\%$ difference of pressure rise inside expansion chamber has been found from the results and it should be indispensable for this type of computational work to consider and include the ablation effect of PTFE nozzle. Further study on turbulence and radiation will be followed.

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Neuro-fuzzy based prediction of the durability of self-consolidating concrete to various sodium sulfate exposure regimes

  • Bassuoni, M.T.;Nehdi, M.L.
    • Computers and Concrete
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    • v.5 no.6
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    • pp.573-597
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    • 2008
  • Among artificial intelligence-based computational techniques, adaptive neuro-fuzzy inference systems (ANFIS) are particularly suitable for modelling complex systems with known input-output data sets. Such systems can be efficient in modelling non-linear, complex and ambiguous behaviour of cement-based materials undergoing single, dual or multiple damage factors of different forms (chemical, physical and structural). Due to the well-known complexity of sulfate attack on cement-based materials, the current work investigates the use of ANFIS to model the behaviour of a wide range of self-consolidating concrete (SCC) mixture designs under various high-concentration sodium sulfate exposure regimes including full immersion, wetting-drying, partial immersion, freezing-thawing, and cyclic cold-hot conditions with or without sustained flexural loading. Three ANFIS models have been developed to predict the expansion, reduction in elastic dynamic modulus, and starting time of failure of the tested SCC specimens under the various high-concentration sodium sulfate exposure regimes. A fuzzy inference system was also developed to predict the level of aggression of environmental conditions associated with very severe sodium sulfate attack based on temperature, relative humidity and degree of wetting-drying. The results show that predictions of the ANFIS and fuzzy inference systems were rational and accurate, with errors not exceeding 5%. Sensitivity analyses showed that the trends of results given by the models had good agreement with actual experimental results and with thermal, mineralogical and micro-analytical studies.

Experimental Study to Investigate the Factors Affecting Durability of Spalled Cement Concrete Pavements (스폴링이 발생한 콘크리트 포장의 내구성 영향인자 조사를 위한 실험적 연구)

  • Yoo, Tae Seok;Ryu, SungWoo;Kim, Jin Cheol
    • International Journal of Highway Engineering
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    • v.20 no.2
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    • pp.27-34
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    • 2018
  • PURPOSES : It is necessary to prevent premature failure of concrete pavements caused by durability problems. The purpose of this study was to find factors affecting the durability of concrete pavements, and suggest improvement methods for existing concrete mix design. METHODS : Factors influencing durability were derived from laboratory test data for common field failure conditions and main properties of concrete cores taken from the field. The improvement of concrete properties was investigated by evaluating the performance of existing and proposed mix proportion designs and curing methods. RESULTS : The compressive strength and the absorbing performance of the low Blaine cement and the high-strength mixture were better than those of the Type I cement. Wet curing showed better compressive strength, elastic modulus, coefficient of thermal expansion, and absorption performance than air curing or compound curing. As a result of comparing concrete cores collected in the field, the sections with good durability showed good performance in terms of resistance to chloride ion penetration, absorption, and initial absorption rate. CONCLUSIONS : The absorption performance was considered as a possible foactor affecting durability of cement concrete pavements as a result of field core tests. In order to improve the durability of the pavement concrete, it is necessary to improve the existing mixtures and curing methods.

Degradation Prediction of Piezo-Composite Actuator under Cyclic Electric Field (반복하중을 받는 압전 복합재료 작동기의 피로 특성)

  • Setiawan Hery;Goo Nam Seo;Yoon Kwang Joon
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.286-289
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    • 2004
  • This paper presents the fatigue characteristics of LIPCA (LIghtweight Piezo-Composite Actuator) device system. The LIPCA device system is composed of a piezoelectric ceramic layer and fiber reinforced lightweight composite layers. Typically a PZT ceramic layer is sandwiched by a top fiber layer with low CTE (coefficient of thermal expansion) and base layers with high CTE. The advantages of the LIPCA design are weight reduction by using the lightweight fiber reinforced plastic layers without compromising the generation of high force and large displacement and design flexibility by selecting the fiber direction and the size of prepreg layers. To predict the degradation of actuation performance of LIPCA due to fatigue, the cyclic electric loading tests using PZT specimens were performed and the strain for a given excitation voltage was measured during the test. The results from the PZT fatigue test were implemented into CLPT (Classical Laminated Plate Theory) model to predict the degradation of LIPCA's actuation displacement. The fatigue characteristic of PZT was measured using a test system composed of a supporting jig, a high voltage power supplier, data acquisition board, PC, and evaluated.

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Study of Combustion and Emission Characteristics for DI Diesel Engine with a Swirl-Chamber

  • Liu, Yu;Chung, S.S.
    • Journal of ILASS-Korea
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    • v.15 no.3
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    • pp.131-139
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    • 2010
  • Gas motion within the engine cylinder is one of the major factors controlling the fuel-air mixing and combustion processes in diesel engines. In this paper, a special swirl-chamber is designed and applied to a DI (direct injection) diesel engine to generate a strong swirl motion thus enhancing gas motion. Compression, combustion and expansion strokes of this DI diesel engine with the swirl-chamber have been simulated by CFD software. The simulation model was first validated through comparisons with experimental data and then applied to do the simulation of the spray and combustion process. The velocity and temperature field inside the cylinder showed the influences of the strong swirl motion to spray and combustion process in detail. Cylinder pressure, average temperature, heat release rate, total amount of heat release, indicated thermal efficiency, indicated fuel consumption rate and emissions of this DI diesel engine with swirl-chamber have been compared with that of the DI diesel engine with $\omega$-chamber. The conclusions show that the engine with swirlchamber has the characteristics of fast mixture formulation and quick diffusive combustion; its soot emission is 3 times less than that of a $\omega$-chamber engine; its NO emission is 3 times more than that of $\omega$-chamber engine. The results show that the DI diesel engine with the swirl-chamber has the potential to reduce emissions.

Analysis and Verification of High Temperature Heat Pump Dryer using Waste Heat Recovery Type for R245fa Refrigerant (배기가스 배열을 활용한 R245fa 냉매용 고온 히트펌프 건조기의 해석 및 검증)

  • Bae, Kyung-Jin;Cha, Dong-An;Kwon, Oh-Kyung
    • Journal of Power System Engineering
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    • v.20 no.2
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    • pp.73-78
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    • 2016
  • In this study, the performance characteristics of a high temperature heat pump dryer that is able to raise the air temperature up to $80^{\circ}C$ by using waste heat as heat source were investigated numerically. The main components of the heat pump dryer were modeling as a compressor, condenser, evaporator and expansion device, and R245fa was selected as refrigerant. Experiments were also conducted to validate the numerical data. As a result, when the evaporator air inlet temperature increased from $50^{\circ}C$ to $65^{\circ}C$, the numerical results of the hot air temperature at outlet and heat pump COP were about 8~11% and 5~8% higher than that of experimental ones, respectively.

An Experimental Study on the Mechanical Properties of High Strength of High Strength Concrete Subject to High Temperature Heating (고온가열을 받은 고강도 콘크리트의 역학적 특성에 관한 실험적 연구)

  • Lee, Tae-Gyu;Sin, Seung-Bong;Kim, Young-Sun;Lee, Seung-Hoon;Kim, Gyu-Yong;Kim, Moo-Han
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.04a
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    • pp.9-12
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    • 2007
  • Recently, research and development related to high strength concrete for the high rise and large scale reinforced concrete building has been actively promoted in worldwide by national and private research project. But, it is reported that violent explosive explosion would be happened when it was exposed in fire. In the existed study, a explosion in a reinforced concrete structure looses the organism by the different contraction and expansion of hardened cement paste and aggregate, and causes crack by thermal stress. In case of the Europe, Japan and America, they have studied the explosion for a long time. However it would hardly study the explosion in domestic, So it is needed base on mechanical properties of fire deterioration in high strength concrete. Therefore, this study is intend as an mechanical properties of specimen to high heating by heating and load test machine and $700^{\circ}C$. As a result, it is willing to propose fundamental data for quick and accurate diagnosis of deteriorated concrete structure by fire damage with experiment according to the design high strength concrete.

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Holographic interferometric tomography for reconstructing a three- dimensional flow field (3차원 유동장 측정용 홀로그래피 간섭토모그래피)

  • ;S. S. Cha
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.6
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    • pp.749-757
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    • 1999
  • Holographic interferornetric tomography can provide reconstruction of instantaneous three dimensional gross flow fields. The technique however confronts ill-posed reconstruction problems in practical applications. Experimental data are usually limited in projection and angular scanning when a field is captured instantaneously or under the obstruction of test models and test section enclosures. An algorithm, based on a series expansion method, has been developed to improve the reconstruction under the ill-posed conditions. A three-dimensional natural convection flow around two interacting isothermal cubes is experimentally investigated. The flow can provide a challenging reconstruction problem and lend itself to accurate numerical solution for comparison. The refractive index fields at two horizontal sections of the thermal plume with and without an opaque object are reconstructed at a limited view angle of 80" The experimental reconstructions are then compared with those from numerical calculation and thermocouple thermometry. It confirms that the technique is applicable to reconstruction of reasonably complex, three-dimensional flow fields.elds.

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