• Title/Summary/Keyword: Thermal environment stability

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Studies on the Activity Properties of Pd-only Three-Way Catalyst for the Purification of Automobile Exhaust Emissions (자동차 배기가스 정화용 Pb-only 삼원촉매의 활성특성에 관한 연구)

  • 신병선;김상수;이길우;정명근;배재호;정석진
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.667-676
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    • 1999
  • The roles of ceria on three-way catalyst is to improve the noble metal dispersion and thermal stability of support ${\gamma}$-$Al_2O_3$. And, ceria has a oxygen storage capacity(OSC) under fuel rich/lean conditions to improve the operating windows of NOx, THC and CO conversion. However, ceria has weak thermal stability under high temperature due to the crystallite growth. So that, the OSC of ceria is decreased, and then the conversions of NOx, THC and CO is decreased. One way of enhancing the thermal stability and NOx, THC and CO conversion Pd-only catalyst is to improve as well as its thermal stability and oxygen storage capacity of the ceria. Especially, the appropriate mixing ratios of bulk and stabilized ceria are very important for designing principles of Pd-only three-way catalysts. In this paper, we discussed the thermal properties of stabilizedand unstabilized (bulk) ceria, and the oxygen storage capacity (OSC) of catalysts, and found the correlation between activity and the OSC of Pd-only catalysts with various different mixing ratios of bulk and stabilized ceria. Finally, we propose the design principles to improve the thermal stability of washcoated Pd-only catalysts.

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Evaluation of thermal stability of quasi-isotropic composite/polymeric cylindrical structures under extreme climatic conditions

  • Gadalla, Mohamed;El Kadi, Hany
    • Structural Engineering and Mechanics
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    • v.32 no.3
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    • pp.429-445
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    • 2009
  • Thermal stability of quasi-isotropic composite and polymeric structures is considered one of the most important criteria in predicting life span of building structures. The outdoor applications of these structures have raised some legitimate concerns about their durability including moisture resistance and thermal stability. Exposure of such quasi-isotropic composite/polymeric structures to various and severe climatic conditions such as heat flux and frigid climate would change the material behavior and thermal viability and may lead to the degradation of material properties and building durability. This paper presents an analytical model for the generalized problem. This model accommodates the non-linearity and the non-homogeneity of the internal heat generated within the structure and the changes, modification to the material constants, and the structural size. The paper also investigates the effect of the incorporation of the temperature and/or material constant sensitive internal heat generation with four encountered climatic conditions on thermal stability of infinite cylindrical quasi-isotropic composite/polymeric structures. This can eventually result in the failure of such structures. Detailed critical analyses for four case studies which consider the population of the internal heat generation, cylindrical size, material constants, and four different climatic conditions are carried out. For each case of the proposed boundary conditions, the critical thermal stability parameter is determined. The results of this paper indicate that the thermal stability parameter is critically dependent on the cylinder size, material constants/selection, the convective heat transfer coefficient, subjected heat flux and other constants accrued from the structure environment.

Nonlocal strain gradient model for thermal stability of FG nanoplates integrated with piezoelectric layers

  • Karami, Behrouz;Shahsavari, Davood
    • Smart Structures and Systems
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    • v.23 no.3
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    • pp.215-225
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    • 2019
  • In the present paper, the nonlocal strain gradient refined model is used to study the thermal stability of sandwich nanoplates integrated with piezoelectric layers for the first time. The influence of Kerr elastic foundation is also studied. The present model incorporates two small-scale coefficients to examine the size-dependent thermal stability response. Elastic properties of nanoplate made of functionally graded materials (FGMs) are supposed to vary through the thickness direction and are estimated employing a modified power-law rule in which the porosity with even type of distribution is approximated. The governing differential equations of embedded sandwich piezoelectric porous nanoplates under hygrothermal loading are derived through Hamilton's principle where the Galerkin method is applied to solve the stability problem of the nanoplates with simply-supported edges. It is indicated that the thermal stability characteristics of the porous nanoplates are obviously influenced by the porosity volume fraction and material variation, nonlocal parameter, strain gradient parameter, geometry of the nanoplate, external voltage, temperature and humidity variations, and elastic foundation parameters.

Seasonal characteristics of thermal and chemical stratification in Lake Paldang (팔당호의 계절별 열적 및 화학적 층화 특성)

  • Son, Ju Yeon;Park, Jin Rak;Noh, Hye Ran;Yu, Soon Ju;Im, Jong Kwon
    • Journal of Korean Society on Water Environment
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    • v.36 no.1
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    • pp.1-13
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    • 2020
  • The purpose of this study was to investigate the thermal and chemical stratification in Lake Paldang 2013-2018 weekly using Schmidt's stability index (SSI) and the index of chemical stratification (IC-i). The annual average for SSI was 19.1 g cm/㎠ with the maximum value of 45.3 g cm/㎠ in the summer and the minimum value of 4.8 g cm/㎠ in fall-winter showing seasonal differences as well as increased vertical mixing in the summer. The lake stability increased higher in 2016 as compared with the other period. The most influential factors of thermal stratification were temperature and heavy rainfall. Especially, high water temperature and a prolonged residence duration caused by reduced rainfall and inflows could result in an increase of the stratification period. While decreasing inflow and outflow at the end of the rainfall, the thermal stratification was restrengthened within 7-14 days, and then stabilized rapidly before the rainfall. IC-DO increased with high air temperature in the spring and fall-winter. However increasing sunshine duration and residence time and decreasing rate of outflow caused an increase of IC-DO in the summer. Rainfall (less than 800 mm/year) and discharge (less than 200 CMS) significantly declined in 2015 resulting in IC-DO (0.77) increased more than three times over the other years and bottom water hypoxia occurred. The SSI and IC-i used in this study could be applied to other lakes to understand changes in stratification and mixing dynamics.

Stability characteristic of bi-directional FG nano cylindrical imperfect composite: Improving the performance of sports bikes using carbon nanotubes

  • Chaobing Yan;Tong Zhang;Ting Zheng;Tayebeh Mahmoudi
    • Steel and Composite Structures
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    • v.50 no.4
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    • pp.459-474
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    • 2024
  • Classical and first-order nonlocal beam theory are employed in this study to assess the thermal buckling performance of a small-scale conical, cylindrical beam. The beam is constructed from functionally graded (FG) porosity-dependent material and operates under the thermal conditions of the environment. Imperfections within the non-uniform beam vary along both the radius and length direction, with continuous changes in thickness throughout its length. The resulting structure is functionally graded in both radial and axial directions, forming a bi-directional configuration. Utilizing the energy method, governing equations are derived to analyze the thermal stability and buckling characteristics of a nanobeam across different beam theories. Subsequently, the extracted partial differential equations (PDE) are numerically solved using the generalized differential quadratic method (GDQM), providing a comprehensive exploration of the thermal behavior of the system. The detailed discussion of the produced results is based on various applied effective parameters, with a focus on the potential application of nanotubes in enhancing sports bikes performance.

Static stability and vibration response of rotating carbon-nanotube-reinforced composite beams in thermal environment

  • Ozge Ozdemir;Huseyin Ural;Alexandre de Macedo Wahrhaftig
    • Advances in nano research
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    • v.16 no.5
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    • pp.445-458
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    • 2024
  • The objective of this paper is to present free vibration and static stability analyses of rotating composite beams reinforced with carbon nanotubes (CNTs) under uniform thermal loads. Beam structural equations and CNT-reinforced composite (CNTRC) beam formulations are derived based on Timoshenko beam theory (TBT). The temperature-dependent properties of the beam material, such as the elastic modulus, shear modulus, and material density, are assumed to vary over the thickness according to the rule of mixture. The beam material is modeled as a mixture of single-walled carbon nanotubes (SWCNTs) in an isotropic matrix. The SWCNTs are aligned and distributed in the isotropic matrix with different patterns of reinforcement, namely the UD (uniform), FG-O, FG-V, FG- Λ and FG-X distributions, where FG-V and FG- Λ are asymmetric patterns. Numerical examples are presented to illustrate the effects of several essential parameters, including the rotational speed, hub radius, effective material properties, slenderness ratio, boundary conditions, thermal force, and moments due to temperature variation. To the best of the authors' knowledge, this study represents the first attempt at the finite element modeling of rotating CNTRC Timoshenko beams under a thermal environment. The results are presented in tables and figures for both symmetric and asymmetric distribution patterns, and can be used as benchmarks for further validation.

Study on spaceborne telescope structure with high stability using new composite materials (신소재 복합재료를 이용한 우주용 카메라 구조의 고안정화 설계에 관한 연구)

  • EUNG-SHIK LEE;SUN-HEE WOO
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.132-136
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    • 2003
  • A Multi-Spectral Camera (MSC) is the payload of KOMPSAT-2 which is designed for earth imaging in visible and near-Infrared region on a sun-synchronous orbit. The telescope in the MSC is a Ritchey-Chretien type with large aperture. The telescope structure should be well stabilized and the optical alignment should be kept steady so that best images can be achieved. However, the MSC is exposed to adverse thermal environment on the orbit which can give impacts on optical performance. Metering structure which is exposed to adverse space environment should have tight requirement of low thermal expansion and hygroscopic stability. In order to meet those stability requirements in addition to fundamental structural ones telescope structure was designed with newly developed graphite-cyanate composite which has high tensile modulus, high thermal conductivity and low moisture absorption compared with conventional graphite-epoxy composite. In this paper, space-borne telescope structure with new composite material will be presented and fulfillment of stability requirements will be verified with designed structure.

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Projection of the Climate Change Effects on the Vertical Thermal Structure of Juam Reservoir (기후변화가 주암호 수온성층구조에 미치는 영향 예측)

  • Yoon, Sung Wan;Park, Gwan Yeong;Chung, Se Woong;Kang, Boo Sik
    • Journal of Korean Society on Water Environment
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    • v.30 no.5
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    • pp.491-502
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    • 2014
  • As meteorology is the driving force for lake thermodynamics and mixing processes, the effects of climate change on the physical limnology and associated ecosystem are emerging issues. The potential impacts of climate change on the physical features of a reservoir include the heat budget and thermodynamic balance across the air-water interface, formation and stability of the thermal stratification, and the timing of turn over. In addition, the changed physical processes may result in alteration of materials and energy flow because the biogeochemical processes of a stratified waterbody is strongly associated with the thermal stability. In this study, a novel modeling framework that consists of an artificial neural network (ANN), a watershed model (SWAT), a reservoir operation model(HEC-ResSim) and a hydrodynamic and water quality model (CE-QUAL-W2) is developed for projecting the effects of climate change on the reservoir water temperature and thermal stability. The results showed that increasing air temperature will cause higher epilimnion temperatures, earlier and more persistent thermal stratification, and increased thermal stability in the future. The Schmidt stability index used to evaluate the stratification strength showed tendency to increase, implying that the climate change may have considerable impacts on the water quality and ecosystem through changing the vertical mixing characteristics of the reservoir.

A Study on the Summer Thermal Environment in Korean Urban Residences (도시주택의 여름철 온열환경에 관한 측정실험 연구)

  • 윤정숙
    • Journal of the Korean Home Economics Association
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    • v.27 no.1
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    • pp.71-83
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    • 1989
  • This is a basic study designed to discover the most comfortable thermal environment for Korean residences. The purpose of the research is to observe and measure the summer thermal environment in Korean urban detached single family houses and apartments by utilising proposed evaluation standards and methods. The technique used involves the measurement of environmental elements, such as indoor temperature, relative humidity and radiant temperature both in detached single family houses and apartments. Also, in order to understand the resident's thermal comfort response. ASHRAE' thermal sensation 9th level, indoor temperature 5th level, and thermal discomfort 4th level in the psycho-physical voting scale (1972) was used. In conclusion, among Korean urban residences, detached single family houses provided a more stable thermal environment than apartments, as shown by physical psychological evaluations. The possible reason for such stability in detached single family houses may be the usage of reinforced concrete structures which maintain consistent temperatures.

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Numerical assessment of nonlocal dynamic stability of graded porous beams in thermal environment rested on elastic foundation

  • Al-Toki, Mouayed H.Z.;Ali, Hayder A.K.;Faleh, Nadhim M.;Fenjan, Raad M.
    • Geomechanics and Engineering
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    • v.28 no.5
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    • pp.455-461
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    • 2022
  • Numerical assessment of the dynamic stability behavior of nonlocal beams rested on elastic foundation has been provided in the present research. The beam is made of fucntional graded (FG) porous material and is exposed to thermal and humid environments. It is also consiered that the beam is subjected to axial periodic mechanical load which especific exitation frequency leading to its instability behavior. Beam modeling has been performed via a two-variable theory developed for thick beams. Then, nonlocal elasticity has been used to establish the governing equation which are solved via Chebyshev-Ritz-Bolotin method. Temperature and moisture variation showed notable effects on stability boundaries of the beam. Also, the stability boundaries are affected by the amount of porosities inside the material.