• 제목/요약/키워드: Thermal Relaxation Rates

검색결과 12건 처리시간 0.023초

분자간 충돌과정에 따른 병진-회전-진동에너지의 이완율 (The Effect of the Collision Process Between Molecules on the Rates of Thermal Relaxation of the Translational-Rotational-Vibrational Energy Exchange)

  • 허중식
    • 대한기계학회논문집B
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    • 제28권12호
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    • pp.1494-1500
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    • 2004
  • A zero-dimensional direct simulation Monte Carlo(DSMC) model is developed for simulating diatomic gas including vibrational kinetics. The method is applied to the simulation of two systems: vibrational relaxation of a simple harmonic oscillator and translational-rotational-vibrational energy exchange process under heating and cooling. In the present DSMC method, the variable hard sphere molecular model and no time counter technique are used to simulate the molecular collision kinetics. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies.

An evaluation system for determining the stress redistribution of a steel cable-stayed bridge due to cable stress relaxation at various temperatures

  • Tien-Thang Hong;Duc-Kien Thai;Seung-Eock Kim
    • Steel and Composite Structures
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    • 제46권6호
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    • pp.805-821
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    • 2023
  • This study developed an evaluation system to explore the effect of the environmental temperature on the stress redistribution produced by cable stress relaxation of structural members in a steel cable-stayed bridge. The generalized Maxwell model is used to estimate stress relaxation at different temperatures. The environmental temperature is represented using the thermal coefficients and temperature loads. The fmincon optimization function is used to determine the set of stress relaxation parameters at different temperatures for all cables. The ABAQUS software is employed to investigate the stress redistribution of the steel cable-stayed bridge caused by the cable stress relaxation and the environmental temperature. All of these steps are set up as an evaluation system to save time and ensure the accuracy of the study results. The developed evaluation system is then employed to investigate the effect of environmental temperature and cable type on stress redistribution. These studies' findings show that as environmental temperatures increased up to 40 ℃, the redistribution rate increased by up to 34.9% in some girders. The results also show that the cable type with low relaxation rates should be used in high environmental temperature areas to minimize the effect of cable stress relaxation.

Nuclear Magnetic Resonance Study of the Raman Spin-Phonon Processes in the Relaxation Mechanisms of Double Sulfate Li3Rb(SO4)2 Single Crystals

  • Heo, Cheol;Lim, Ae-Ran
    • 한국자기공명학회논문지
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    • 제15권1호
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    • pp.40-53
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    • 2011
  • The NMR spectra of $Li_3Rb(SO_4)_2$ crystals and their relaxation processes were investigated by using $^7Li$ and $^{87}Rb$ NMR. The relaxation rates of the $^7Li$ and $^{87}Rb$ nuclei in the crystals were found to increase with increasing temperature, and can be described by the relation $T_1^{-1}{\propto}AT^2$. The dominant relaxation mechanism for these nuclei with electric quadrupole moments is provided by the coupling of these moments to the thermal fluctuations of the local electric field gradient via Raman spin-phonon processes.

유지시간 효과를 고려한 12Cr 내열강의 열피로 및 저주기 피로 특성 (Thermal-Mechanical and Low Cycle Fatigue Characteristics of 12Cr Heat Resisting Steel with Hold Time Effects)

  • 하정수;고승기;옹장우
    • 한국자동차공학회논문집
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    • 제3권1호
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    • pp.1-12
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    • 1995
  • Isothermal and thermal-mechanical fatigue characteristics of 12Cr heat resisting steel used for high temperature applications were investigated including hold time effects. Isothermal low cycle fatigue test at $600^{\circ}C$ and in-phase, out-of-phase thermal-mechanical fatigue test at 350 to $600^{\circ}C$ were conducted using smooth cylindrical hollow specimen under strain-control with total strain ranges from 0.006 to 0.015. Regardless of thermal-mechanical and isothermal fatigue tests, cyclic softening behavior was observed and much more pronounced in the thermal-mechanical fatigue tests with hold times due to the stress relaxation during the hold time. The phase difference between temperature and strain in thermal-mechanical fatigue tests resulted in significantly shorter fatigue life for out-of-phase compared to in-phase. The differences in fatigue lives were dependent upon the magnitudes of plastic strain ranges and mean stresses. During the hold time in the strain-controlled fatigue tests, the increase in the plastic strain range and the stress relaxation were observed. It appeared that the increase in plastic strain range per cycle and the introduction of creep damage made important contributions to the reduction of thermal-mechanical fatigue life with hold time, and the life reduction tendency was more remarkable in the in-phase than in the out-of-phase thermal-mechanical fatigue. Isothermal fatigue tests performed under the combination of fast and slow strain rates at $600^{\circ}C$ showed that the fatigue life decreased as the strain rate and frequency decreased,especially for the low strain ranges.

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Improvement of $^{4}I_{11/2}{\to}^{4}I_{13/2}$ Transition Rate and Thermal Stabilities in $Er^{3+}-Doped\;TeO_2-B_2O_3\;(GeO_2)-ZnO-K_2O$ Glasses

  • Cho, Doo-Hee;Choi, Yong-Gyu;Kim, Kyong-Hon
    • ETRI Journal
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    • 제23권4호
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    • pp.151-157
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    • 2001
  • Spectroscopic and thermal analysis indicates that tellurite glasses doped with $B_2O_3$ and $GeO_2$ are promising candidate host materials for wide-band erbium doped fiber amplifier (EDFA) with a high 980 nm pump efficiency. In this study, we measured the thermal stabilities and the emission cross-sections for $Er^{3+}:^{4}I_{13/2}\;{\to}\;^{4}I_{15/2}$ transition in this tellurite glass system. We also determined the Judd-Ofelt parameters and calculated the radiative transition rates and the multiphonon relaxation rates in this glass system. The 15 mol% substitution of $B_2O_3$ for $TeO_2$ in the $Er^{3+}-doped\;75TeO_2-20ZnO-5K_2O$ glass raised the multiphonon relaxation rate for $^4I_{11/2}\;{\to}\;^4I_{13/2}$ transition from 4960 $s^{-1}$ to 24700 $s^{-1}$, but shortened the lifetime of the $^4I_{13/2}$ level by 14 % and reduced the emission cross-section for the $^4I_{13/2}\;{\to}\;^4I_{15/2}$ transition by 11%. The 15 mol% $GeO_2$ substitution in the same glass system also reduced the emission cross-section but increased the lifetime by 7%. However, the multiphonon relaxation rate for $^4I_{11/2}{\to}^4I_{13/2}$ transition was raised merely by 1000 $s^{-1}$. Therefore, a mixed substitution of $B_2O_3$ and $GeO_2$ for $TeO_2$ was concluded to be suitable for the 980 nm pump efficiency and the fluorescence efficiency of $^4I_{13/2}{\to}^4I_{15/2}$ transition in $Er^{3+}-doped$ tellurite glasses.

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AZ31 Mg 합금의 고온 변형 시의 동적 연화 현상 (Flow Softening Behavior during the High Temperature Deformation of AZ31 Mg alloy)

  • 이병호;;염종택;이종수
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2006년도 춘계학술대회 논문집
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    • pp.70-73
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    • 2006
  • In the present study, the flow-softening behavior occurring during high temperature deformation of AZ31 Mg alloy was investigated. Flow softening of AZ31 Mg alloy was attributed to (1) thermal softening by deformation heating and (2) microstructural softening by dynamic recrystallization. Artificial neural networks method was used to derive the accurate amounts of thermal softening by deformation heating. A series of mechanical tests (High temperature compression and load relaxation tests) was conducted at various temperatures ($250^{\circ}C{\sim}500^{\circ}C$) and strain rates ($10^{-4}/s{\sim}100/s$) to formulate the recrystallization kinetics and grain size relation. The effect of DRX kinetics on microstructure evolution (fraction of recrystallization) was evaluated by the unified SRX/DRX (static recrystallization/dynamic recrystallization) approaches

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핫엠보싱 공정의 폴리머 점탄성 거동에 대한 연구 (Experimental and numerical study on viscoelastic behavior of polymer during hot embossing process)

  • 송남호;손지원;임성한;오수익
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2007년도 춘계학술대회 논문집
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    • pp.191-194
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    • 2007
  • In hot embossing lithography which has shown to be a good method to fabricate polymeric patterns for IT and bio components, it is very important to determine the proper process conditions of pressure, temperature, and time. It is also a key factor for predicting the optical properties of final product to calculate residual stress distribution after the embossing process. Therefore, to design the optimum process with right conditions, the ability to predict viscoelastic behavior of polymer during and after the hot embossing process is required. The objective of the present investigation is to establish simulation technique based on constitutive modeling of polymer with experiments. To analyze deformation behavior of viscoelastic polymer, the large strain material properties were obtained from quasi-static compression tests at different strain rates and temperatures and also stress relaxation tests were executed. With this viscoelastic material model, finite element simulation of hot embossing was executed and stress distribution is obtained. Proper process pressure is very important to predict the defect and incomplete filling.

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Curing Induced Residual Stresses in Laminated Cylindrical Shells

  • Lee, Soo-Yong
    • Journal of Mechanical Science and Technology
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    • 제14권1호
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    • pp.19-29
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    • 2000
  • A viscoelastic finite element analysis is presented to investigate residual stresses occurred in a laminated cylindrical shell during cure. An incremental viscoelastic constitutive equation that can describe stress relaxation during the cure is derived as a recursive formula which can be used conveniently for a numerical analysis. The finite element analysis program is developed on the basis of a 3-D degenerated shell element and the first order shear deformation theory, and is verified by comparing with an one dimensional exact solution. Viscoelastic effect on the residual stresses in the laminated shell during the cure is investigated by performing both the viscoelastic and linear elastic analyses considering thermal deformation and chemical shrinkage simultaneously. The results show that there is big difference between viscoelastic stresses and linear elastic stresses. The effect of cooling rates and cooling paths on the residual stresses is also examined.

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Investigation of acrylic/boric acid composite gel for neutron attenuation

  • Ramadan, Wageeh;Sakr, Khaled;Sayed, Magda;Maziad, Nabila;El-Faramawy, Nabil
    • Nuclear Engineering and Technology
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    • 제52권11호
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    • pp.2607-2612
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    • 2020
  • The present work was aimed to show the possibility of using hydrogel (acrylic/boric acid) for evaluation of the neutron radiation shielding. The influence of acrylic acid concentration, different gamma doses and relative contents of boric acid were studied. The physical properties and the thermomechanical stability of the studied samples were investigated. The shielding property of the composite for neutron was tested by Pu-Be neutron source (5 Ci) under room temperature. The neutron fluence rates and gamma fluxes were measured using a stilbene organic scintillator. The macroscopic effective removal cross-section ΣR (cm-1) of fast neutrons and total attenuation coefficient μ (cm-1) of gamma rays has been studied experimentally. The transmission parameters, the relaxation length (??) and the half-value layer (HVL) were obtained. The obtained results indicated that the addition of boric acid to acrylic acid tends to increase the macroscopic effective removal cross-section ΣR (cm-1) to 0.141 compared to 0.094 of ordinary concrete.

STRAIN AND TEMPERATURE CHANGES DURING THE POLYMERIZATION OF AUTOPOLYMERIZING ACRYLIC RESINS

  • Ahn Hyung-Jun;Kim Chang-Whe;Kim Yung-Soo
    • 대한치과보철학회지
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    • 제39권6호
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    • pp.709-734
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    • 2001
  • The aims of this experiment were to investigate the strain and temperature changes simultaneously within autopolymerzing acrylic resin specimens. A computerized data acquisition system with an electrical resistance strain gauge and a thermocouple was used over time periods up to 180 minutes. The overall strain kinetics, the effects of stress relaxation and additional heat supply during the polymerization were evaluated. Stone mold replicas with an inner butt-joint rectangular cavity ($40.0{\times}25.0mm$, 5.0mm in depth) were duplicated from a brass master mold. A strain gauge (AE-11-S50N-120-EC, CAS Inc., Korea) and a thermocouple were installed within the cavity, which had been connected to a personal computer and a precision signal conditioning amplifier (DA1600 Dynamic Strain Amplifier, CAS Inc., Korea) so that real-time recordings of both polymerization-induced strain and temperature changes were performed. After each of fresh resin mixture was poured into the mold replica, data recording was done up to 180 minutes with three-second interval. Each of two poly(methyl methacrylate) products (Duralay, Vertex) and a vinyl ethyl methacrylate product (Snap) was examined repeatedly ten times. Additionally, removal procedures were done after 15, 30 and 60 minutes from the start of mixing to evaluate the effect of stress relaxation after deflasking. Six specimens for each of nine conditions were examined. After removal from the mold, the specimen continued bench-curing up to 180 minutes. Using a waterbath (Hanau Junior Curing Unit, Model No.76-0, Teledyne Hanau, New York, U.S.A.) with its temperature control maintained at $50^{\circ}C$, heat-soaking procedures with two different durations (15 and 45 minutes) were done to evaluate the effect of additional heat supply on the strain and temperature changes within the specimen during the polymerization. Five specimens for each of six conditions were examined. Within the parameters of this study the following results were drawn: 1. The mean shrinkage strains reached $-3095{\mu}{\epsilon},\;-1796{\mu}{\epsilon}$ and $-2959{\mu}{\epsilon}$ for Duralay, Snap and Vertex, respectively. The mean maximum temperature rise reached $56.7^{\circ}C,\;41.3^{\circ}C$ and $56.1^{\circ}C$ for Duralay, Snap, and Vertex, respectively. A vinyl ethyl methacrylate product (Snap) showed significantly less polymerization shrinkage strain (p<0.01) and significantly lower maximum temperature rise (p<0.01) than the other two poly(methyl methacrylate) products (Duralay, Vertex). 2. Mean maximum shrinkage rate for each resin was calculated to $-31.8{\mu}{\epsilon}/sec,\;-15.9{\mu}{\epsilon}/sec$ and $-31.8{\mu}{\epsilon}/sec$ for Duralay, Snap and Vertex, respectively. Snap showed significantly lower maximum shrinkage rate than Duralay and Vertex (p<0.01). 3. From the second experiment, some expansion was observed immediately after removal of specimen from the mold, and the amount of expansion increased as the removal time was delayed. For each removal time, Snap showed significantly less strain changes than the other two poly(methyl methacrylate) products (p<0.05). 4. During the external heat supply for the resins, higher maximum temperature rises were found. Meanwhile, the maximum shrinkage rates were not different from those of room temperature polymerizations. 5. From the third experiment, the external heat supply for the resins during polymerization could temporarily decrease or even reverse shrinkage strains of each material. But, shrinkage re-occurred in the linear nature after completion of heat supply. 6. Linear thermal expansion coefficients obtained from the end of heat supply continuing for an additional 5 minutes, showed that Snap exhibited significantly lower values than the other two poly(methyl methacrylate) products (p<0.01). Moreover, little difference was found between the mean linear thermal expansion coefficients obtained from two different heating durations (p>0.05).

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