• Title/Summary/Keyword: Thermal Reaction

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Evaluation Methods on ONDOL Thermal Environmental Index (온돌 온열환경지표 평가방법)

  • Kim, Sung-Jo
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.1
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    • pp.101-110
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    • 2022
  • For this purpose, the authors proposed and proved usefulness of the modified mean skin temperature which is integrated mean radiation temperature and the effect of floor contacted heat conduction. The mean radiation temperature is applied form factor between half cross-legged human body and surrounding wall of indoor. In addition the floor contacted heat conduction is applied heat transfer coefficient of half cross-legged human body. Eight Korean young men were targeted for the experiment. From the experiment the authors excerpted physiological reaction and psychological reaction in Ondol environment which is combined physiccal environmental factor of artificial climate chamber, air and floor temperature. As a result of the experiment it is confirmed that heat conduction has more impact than heat exchange from existing research for the heat exchange between half cross-legged human body and surrounding wall in Ondol thermal environment. Thereby, it is proved the effectiveness of the modified mean skin temperature which is added floor contacted temperature to the Ondol thermal environmental evaluation index.

Conceptual design of a copper-bonded steam generator for SFR and the development of its thermal-hydraulic analyzing code

  • Im, Sunghyuk;Jung, Yohan;Hong, Jonggan;Choi, Sun Rock
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.2262-2275
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    • 2022
  • The Korea Atomic Energy Research Institute (KAERI) studied the sodium-water reaction (SWR) minimized steam generator for the safety of the sodium-cooled fast reactor (SFR), and selected the copper bonded steam generator (CBSG) as the optimal concept. This paper introduces the conceptual design of the CBSG and the development of the CBSG sizing analyzer (CBSGSA). The CBSG consists of multiple heat transfer modules with a crossflow heat transfer configuration where sodium flows horizontally and water flows vertically. The heat transfer modules are stacked along a vertical direction to achieve the targeted large heat transfer capacity. The CBSGSA code was developed for the thermal-hydraulic analysis of the CBSG in a multi-pass crossflow heat transfer configuration. Finally, we conducted a preliminary sizing and rating analysis of the CBSG for the trans-uranium (TRU) core system using the CBSGSA code proposed by KAERI.

Synthesis of $Zn(BH_4)_2$ powders by mechanochemical reaction and study of thermal decomposition behavior (기계 화학적 반응법을 이용한 $Zn(BH_4)_2$ 분말의 합성과 열분해 특성)

  • Jeon Eun;Jo Yeong Hwan
    • 한국전기화학회:학술대회논문집
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    • 2005.07a
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    • pp.373-378
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    • 2005
  • [ $Zn(BH_4)_2$ ] ($8.4\;wt\%$ theoretical hydrogen storage capacity) powders have been successfully synthesized by mechanochemical reaction from mixtures of $ZnCl_2$ and $NaBH_4$ powders in a 1:2 molar ratio in different times. $$ZnCl_2\;+\;2NaBH_4\rightarrow\;Zn(BH_4)_2\;+\;2NaCl\;(1)$$ $Zn(BH_4)_2$ powders were characterized by X-ray diffractometry(XRD), and Furier Transform Infrared spectrometry(FT-IR). The thermal stabilities of $Zn(BH_4)_2$ powders were studied by Differential scanning calorimetry(DSC), Thermogravimetry analysis(TGA), and Mass spectrometry(MS). $Zn(BH_4)_2$ can be tested for hydrogen evolution without further purification. The reaction to yield hydrogen is irreversible, the other products being compounds of Zn, and borane. $Zn(BH_4)_2$ thermally decomposes to release borane and hydrogen gas between about 85 and $150^{\circ}C$.

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The Investigation of Influence of Chlorinated Hydrocarbons on $NO_x$ Formation from Methane Flames (메탄 화염에서 염화 탄화수소 화합물이 질소산화물 생성에 미치는 영향 조사)

  • Jang, Kyoung;Jang, Bong-Choon;Lee, Ki-Yong
    • Journal of the Korean Society of Combustion
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    • v.13 no.1
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    • pp.10-16
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    • 2008
  • Numerical simulations of freely propagating premixed flames burning mixtures of methane and chlorinated hydrocarbons in fuel are performed at atmospheric pressure in order to understand the effect of chlorinated hydrocarbons on the formation of nitrogen oxide. A detailed chemical reaction mechanism is used, the adopted scheme involving 89 gas-phase species and 1017 elementary forward reaction steps. Chlorine atoms available from chlorinated hydrocarbons inhibit the formation of nitrogen oxides by lowering the concentration of radical species. The reduction of NO emission index calculated with thermal or prompt NO mechanism is not linear and is probably related to the saturation effect as $CH_3Cl$ addition is increased, In the formation or consumption of nitrogen oxide, the $NO_2$ and NOCl reactions play an important role in lean flames while the HNO reactions do in rich flames. The molar ratio of Cl to H in fuel has an effect on the magnitude of NO emission index.

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Synthesis of GaN nanowires using thermal chemical vapor deposition (열화학기상증착법을 이용한 GaN nanowire 합성)

  • 류승철;이태재;이철진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.931-934
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    • 2001
  • GaN nanowires has much interest as one-dimensional materials for blue light LED. GaN-based materials have been the subject of intensive research for blue light emission and high temperature/high power electronic devices. In this letter, the synthesis of GaN nanowires by the reaction of mixture of GaN nanowires by the reaction of mixture of Ga meta and GaN powder with NH$_3$ using thermal chemical vapor deposition is reported. X-ray diffraction, energy dispersive x-ray spectrometer, scanning electron microscopy, and transmission electron microscopy indicate that those GaN nanowires with hexagonal wurtzite structure were about 60nm in diameter and up to several hundreds of micrometers in length.

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Reaction Processes of the Formation of Mg-Al Spinel by a Thermal Decomposition of a Mixed Sulfate Hydrate (복합 황산염 수화물의 열분해에 의한 Mg-Al 스피넬의 생성반응)

  • 박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.23 no.6
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    • pp.71-75
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    • 1986
  • The forming reaction processes of magnesium aluminate spinel by a thermal decomposition of sulfate hydrate were studied with DTA, TG. SEM and X-ray powder diffraction methods. The hydrous salt composed of the mixture of the two compounds of $MgSO_4$ $6H_2O$ and ${AL_2}({SO_4})_17H_2O_3$ in which both sulfates were crystalline. On heating the hydrous slat the crystalline magnesium and aluminum sulfate anhydride to amorphous alumina magnesium sulfate anhydride decomposed to amorphous magnesia and these amorphous oxides reacted completely each other to form a spinel at $1000^{\circ}C$ The apparent activation energy of forming reaction of spinel was 36.5 kcal/mole($900^{\circ}C$~$1000^{\circ}C$) The crystallite size of spinel obtained at $1000^{\circ}C$ after 1 h was 380$\AA$.

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The effect of hexamethylenetetramine contents and cure properties on friction characteristics of phenolic resin (페놀수지의 마찰특성에 미치는 HEXA의 함량 및 경화도의 영향)

  • Kim, Dae-Kyeun;Jang, Ho;Yoon, Ho-Gyu
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.11a
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    • pp.49-56
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    • 1999
  • A material was formulated with Phenol novolac and HEXA only. The cure kinetics and thermal characteristics of phenol novolac with various HEXA contents were peformed by differential scanning calorimetry and thermal gravimetric analysis. All kinetic parameters of the curing reaction including the reaction order, activation energy, and rate constant were calculated and reported. The results indicate that the curing reaction goes through an autocatalytic kinetic mechanism. The friction and wear characteristics of this material were determined using friction material testing machine. The friction coefficient of phenol novolac with various HEXA contents was determined using the PV(pressure & velocity) factor. The most stable and highest friction coefficient with a various pressure and velocity condition was found at HEXA 10 wt.% material. The specific wear rate per unit sliding distance with a various HEXA contents was reported.

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Investigation of Interface Reaction between TiAl Alloys and Mold Materials

  • 김명균;김영직
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.289-289
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    • 1999
  • This paper describes the investment casting of TiAl alloys. The effects of mold material and mold preheating temperature for the investment casting of TiAl on metal-mold interfacial reaction were investigated by means of optical micrography, hardness profiles and an electron probe microanalyzer. The mold materials examined were colloidal silica bonded ZrO₂, ZrSiO₄, A1₂O₃and CaO stabilized ZrO₂. When compared with conventional titanium a1loy, the high aluminum concentration of TiAl alloys helps to lower their reactivity in the molten state. The A1₂O₃mold is a promising mold material for the investment casting of TiAl in terms of the thermal stability, formability and cost. Special attention need to be paid to thermal stability and mold preheating when developing the investment calling of TiAl alloys.

Effect of Garlic, Chili and Ginseng on the Thermal Gelation of Alaska Pollack Surimi

  • Takeuchi, Atsuyoshi;Lee, Nam-Hyouck;Cho, Young-Je;Konno, Kunihiko
    • Food Science and Biotechnology
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    • v.14 no.1
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    • pp.16-20
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    • 2005
  • Additions of ground garlic, chili and ginseng powder did not affect the breaking force and strain of directly heated gel of Alaska pollack surimi. In comparison, these additives reduced the setting effect achieved by incubation of the salted surimi at $25^{\circ}C$, and resulted in a decreased breaking force and strain for the two step heated gel. Garlic almost completely inhibited the myosin cross-linking reaction, an important reaction for improving the gel properties occurring in the setting process. However, chili and ginseng powder minimally inhibited the cross-linking reaction. Thus, this study proposes that the mechanism for the suppression of the setting effect by chili and ginseng is different from that of garlic.

Phosgen-free Synthesis of Oligoureas Having Amino End-groups: Their Application to the Synthesis of Poly(urea-imide)

  • Chang, Ji-Young;Kim, Beom-Jin
    • Fibers and Polymers
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    • v.3 no.2
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    • pp.55-59
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    • 2002
  • The thermal reaction of acetoacetanilide in the presence of aniline or phenol yielded carbanilide in quantitative yields. This reaction was applied to the synthesis of polyurea. Bisacetoacetamides were prepared from diamines and diketene in DMF. They were thermally polymerized in the presence of phenol or a diamine (6FDA) to yield polyureas of low molecular weights. The polymers were soluble in DMSO and NMP. $^1{H-NMR}$ analysis showed that they had amino group terminated structures. Poly(urea-imide) was synthesized by the reaction of an oligourea diamine with pyromellitic dianhydride in NMP. The concentration of terminal amino groups was determined by an acid-base titration. The thermal property of poly(urea-imide) was evaluated by thermogravimetric analysis (TGA). Initial decompisition took place at 332-$350^{\circ}C$.