• 한국표면공학회지
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• 제55권6호
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• pp.308-318
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• 2022

The surface modification and treatment using thermal plasma were reviewed in academic fields. In general, thermal plasma is generated by direct current (DC) and radiofrequency (RF) power sources. Thermal spray coating, a typical commercial process using thermal plasma, is performed by DC thermal plasma, whereas other promising surface modifications have been reported and developed using RF thermal plasma. Beyond the thermal spray coating, physical and chemical surface modifications were attempted widely. Superhydrophobic surface treatment has a very high industrial demand particularly. Besides, RF thermal plasma system for large-area film surface treatment is being developed. Thermal plasma is especially suitable for the surface modification of low-dimensional nanomaterial (e.g., nanotubes) by utilizing high temperature and rapid quenching. It is able to synthesize and modify nanomaterials simultaneously in a one-pot process.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 2000년도 Proceedings of 2000 International Nano Crystals/Ceramics Forum and International Symposium on Intermaterials
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• pp.179-193
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• 2000

Aluminium titanate (Al₂TiO5) with an excellent thermal shock resistant and a low the expansion coefficient was obtained by solid solution with MgO, SiO₂, and ZrO₂ in the Al₂TiO5 lattice or in the grain boundary solution through electrofusion in an arc furnace. However, these materials have low mechanical strength due to the presence of microcracks developed by a large difference in thermal expansion coefficients along crystallographic axes. Pure Al₂TiO5 tends to decompose into α-Al₂O₃ and TiO₂-rutile in the temperature range of 750-1300℃ that rendered it apparently useless for industrial applications. Several thermal shock tests were performed: Long therm thermal annealing test at 1100℃ for 100h; and water quenching from 950 to room temperature (RT). Cyclic thermal expansion coefficients up to 1500℃ before and after decomposition tests was also measured using a dilatometer, changes in the microstructure, thermal expansion coefficients, Young's modulus and strengths were determined. The role of microcracks in relation to thermal shock resistance and thermal expansion coefficient is discussed.

• 공업화학
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• 제7권3호
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• pp.504-510
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• 1996

새로운 상용성 조절 기법인 compositional quenching 공정을 이용하여 LDPE(Low-density polyethylene)/LLDPE(Linear low-density polyethylene) 블렌드를 제조하고, 기존의 mechanical blending과 solution blending 방법으로 제조한 블렌드와 물성 등을 비교 고찰하였다. DSC thermogram에서는 $T_m$ peak와 $T_c$ peak가 세 가지 블렌드 방법에 따라 변하였다. Compositional quenching 공정에 의한 블렌드의 열적 성질은 solution blending에 의한 블렌드와 거의 유사하였으나 mechanical blending에 의한 블렌드와는 서로 다른 경향을 보였다. 이러한 결과는 matrix 내에 분산된 domain 크기에 의한 것으로 생각된다. 인장실험에서는 compositional quenching 공정과 solution blending에 의한 블렌드의 파괴신율이 mechanical blending방법에 의한 것에 비해 상대적으로 컸으며, Young's modulus는 mechanical blending에 의한 결과가 상대적으로 컸다. 또한 compositional quenching 공정과 solution blending에 의한 블렌드의 인장강도가 mechanical blending에 의한 것보다 큰 경향을 보였다.

• 공업화학
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• 제18권2호
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• pp.136-141
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• 2007

본 연구에서는 열플라즈마를 이용하여 클로로메탄 즉 사염화탄소($CCl_4$), 삼염화탄소($CCl_3H$), 이염화탄소($CCl_2H_2$)를 분해하는 실험을 수행하였으며 열플라즈마분해공정의 특성에 대한 연구를 진행하였다. Factsage program을 이용하여 열역학적 평형조성을 알아보았으며, 또한 Gas chromatography를 이용하여 농도, 캐리어 가스의 유량 및 quenching 속도등 세가지 변수의 변화에 따른 분해율을 살펴보았다. 실험 결과 92%이상의 높은 분해율을 얻었다. FT-IR을 이용하여 최종 생성물을 확인한 결과 중성 분위기에서는 주로 카본, 염소, 염화수소가 생성되었고 산화 분위기에서는 카본의 생성이 억제되었으며 주로 이산화탄소, 염화수소, 염소가 생성되었다. FT-IR생성물에 대한 분석과 Factsage program에 의한 온도 분포 별 생성된 라디칼 및 기타 입자의 종류와 결부하여 이에 따른 분해 메커니즘에 대해 알아보았다. 분해 경로는 주로 라디칼에 의한 산화반응과 전자 부착에 의한 분해 반응으로 이루어짐을 확인하였다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.562-566
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• 2004

Thermal shock is a physical phenomenon that occurs in the condition of the exposure of a rapidly large temperature and pressure change of in the quenching condition of material. The rocket nozzle is exposed to high temperature combustion gas, it may have failure and erosion deformation. So, it is important to select a suitable material having excellent thermal shock properties and evaluate these materials in rocket design. In this study, the temperature gradient and crack initiation of rocket nozzle material is investigated using by FEM under thermal shock condition. This is very important information in the design process of thermal structure.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2003년도 제20회 춘계학술대회 논문집
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• pp.164-167
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• 2003

열충격은 재료가 갑작스런 온도나 압력변화 혹은 급냉 조건하에 있을때 발생하는 물리적 현상이다. 본 논문에서는 레이저 조사를 이용하여 열충격 강도와 열충격 파괴인성을 평가하였다. 시험편의 온도 분포는 타입 K와 C 열전대를 이용하여 측정하였다. 조사된 표면은 SEM을 이용하여 관찰하였다. 파괴에 필요한 임계 레이저 파워가 재료의 열충격 강도와 열충격 파괴인성을 결정짓는 주요한 요소라고 할 수 있다.

• 공업화학
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• 제9권6호
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• pp.829-834
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• 1998

환경문제와 관련하여 오존층 파괴의 주요 원인으로 알려진 CFC를 열플라즈마를 이용하여 완전하게 분해하였다. CFC113($C_2Cl_3F_3$)을 선정하여 열플라즈마 분해에서의 적절한 공정 조건을 검토하였다. 실험에 앞서, 상압에서 300 K~5000 K범위에서 CFC113, $H_2$, $O_2$간의 열역학적 화학평형조성을 고찰함으로써 CFC113의 분해 생성의 경향을 알 수 있었다. 실험은 상압, 상온에서 CFC113과 $H_2$, $O_2$혼합가스의 주입량, 그리고 냉각관 직경의 변화에 따른 분해생성물을 조사하였고 이를 기체크로마토그래피로 분석하였다. 그 결과, 각각 99.99%이상의 분해율을 보였다. CFC113/$H_2$=1/3에서 $O_2$비가 증가할수록 CO로의 전화율은 감소하였다. CFC113/$O_2$=1/1, 1/1.5, 1/2에서 $H_2$비가 3이상 증가될수록 CO로의 전화율이 증가하였다. 그 이유는 $H_2$첨가가 증가할수록 환원분위기에서 $H_2O$가 생성되고 $CO_2$생성량이 감소하기 때문이다. DC power가 증가하여도 CO로의 전화율 변화는 차이가 없었으며, 총유량이 증가할 경우 CO전화율이 약간 감소하는 경향을 보였다. 냉각관의 직경을 8 mm에서 4 mm로 작게 할 경우 빠른 냉각속도로 인하여 CO로의 전화율이 증가하였다.

• 한국재료학회지
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• 제30권8호
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• pp.435-440
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• 2020

The relationship between the precipitation of secondary phase and the thermal properties of Al-4.5%Cu alloy (in wt.%) after various heat treatments has been studied. Solid solution treatment of alloy was performed at 808 K for 6 hours, followed by warm water quenching; then, the samples were aged in air at 473 K for different times. The thermal diffusivity of the Al-4.5%Cu alloy changed with the heat treatment conditions of the alloy at temperatures below 523 K. The as-quenched specimen had the lowest thermal diffusivity, and as the artificial aging time increased, the thermal diffusivity of the specimen increased in the temperature range between 298 and 523 K. For the specimen aged for five hours, the thermal conductivity was 12% higher than that of the as-quenched specimens at 298 K. It is confirmed that the thermal diffusivity and thermal conductivity of the Al-4.5%Cu alloy significantly depend on their thermal history at temperatures below 523 K. The precipitation and dissolution of the Al₂Cu phase were confirmed via DSC for the alloys, and the formation of coefficient of thermal expansion peaks in TMA was caused by precipitation. The precipitation of supersaturated solid solution of Al-4.5%Cu alloys had an additional linear expansion of ≈ 0.05 % at 643 K during thermal expansion measurement.

• 한국표면공학회지
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• 제34권5호
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• pp.395-402
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• 2001

An induction thermal plasma system have been newly designed for advanced operation with a pulse modulated mode to control the plasma power in time domain and to create non-equilibrium effects such as fast quenching of the plasma to produce new functional materials in high rate. The system consists of MOSFET power supply with a maximum power of 50 kW with a frequency of 460 kHz, an induction plasma torch with a 10-turns coil of 80 mm diameter and 150 mm length and a vacuum chamber. The pulse modulated plasma was successfully generated at a plasma power of 30 kW and a high pressure of 100 kPa, with taking the on and off time as 10 ms, respectively. Measurements were carried out on the time-dependent spectral lines emitted from Ar species. The dynamic behavior of plasma temperature in a pulse cycle was estimated by the Boltzmann plot and the excitation temperature of Ar atom was found to be changed periodically from around 0.5 to 1.7 eV during the cycle. Two application regions of the induction thermal plasma newly generated were introduced to material processing with high rate synthesis based on non equilibrium effects, and to the finding of new arc quenching gases coming necessary for power circuit breaker, which is friendly with earth circumstance alternative to SF6 gas.

• Bulletin of the Korean Chemical Society
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• 제30권9호
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• pp.1973-1977
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• 2009

In the present study, at first, 2,4-Dihydroxy Salophen (2,4-DHS), has been synthesized by combination of 1, 2-diaminobenzene and 2,4-dihydroxybenzaldehyde in a solvent system. This ligand containing meta-quinone functional groups were characterized using UV-Vis and IR spectroscopies. Subsequently, the interaction between native calf thymus deoxyribonucleic acid (ct-DNA) and 2,4-DHS, was investigated in 10 mM Tris/HCl buffer solution, pH 7.2, using UV-visible absorption and fluorescence spectroscopies, thermal denaturation technique and viscosity measurements. From spectrophotometric titration experiments, the binding constant of 2,4-DHS with ct-DNA was found to be (1.1 ${\pm}\;0.2)\;{\times}\;10^4\;M^{-1}.$ The fluorescence study represents the quenching effect of 2,4-DHS on bound ethidium bromide to DNA. The quenching process obeys linear Stern-Volmer equation in extended range of 2,4-DHS concentration. Thermal denaturation experiments represent the increasing of melting temperature of DNA (about 3.5 ${^{\circ}C}$) due to binding of 2,4-DHS. These results are consistent with a binding mode dominated by interactions with the groove of ct-DNA.