• 연구논문집
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• s.27
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• pp.101-108
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• 1997

The characteristics of combustion and emissions in multi-staged oil burner have been experimentally studied for the various range of equivalence ratios, drop sizes and fuel formulations. Malvern system was used to measure droplet size of fuel. Light fuel oil and light fuel oil doped with pyridine($C_5H _5N$) were used to investigate the effects on fuel NOx emission. The emissions of NO and CO in exhaust gas and the flame temperatures were measured by the gas analyzer and thennocouples. NOx emissions were increased by increasing the excess air ratio (range:$lambda=1.1-1.4$) or decreasing the SMD of droplet in single-staged burner. In comparison with the single-staged burner, the emission of NOx in multi-staged burner was reduced by 50% but CO emission was slightly increased. It is found that multi-staged burner has a good capability in reducing thermal NOx resulting from the distributed heat release rate and lower flame temperature in fuel-rich and fuel-lean combustion zone. Moreover, the fuel NOx emission of the multi-staged burner is lower than that of single-staged burner, because multi-staged burner has fuel rich zone where fuel N is converted to $N_2$ more than NO. In 3-staged burner, the percentage of each stage combustion air have strong influence on emission characteristics. It is also found that NOx emission can be reduced by decreasing inner and outer air percentage or increasing middle air flow rate and CO emission is vice versa.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.5
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• pp.667-676
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• 1999

The roles of ceria on three-way catalyst is to improve the noble metal dispersion and thermal stability of support ${\gamma}$-$Al_2O_3$. And, ceria has a oxygen storage capacity(OSC) under fuel rich/lean conditions to improve the operating windows of NOx, THC and CO conversion. However, ceria has weak thermal stability under high temperature due to the crystallite growth. So that, the OSC of ceria is decreased, and then the conversions of NOx, THC and CO is decreased. One way of enhancing the thermal stability and NOx, THC and CO conversion Pd-only catalyst is to improve as well as its thermal stability and oxygen storage capacity of the ceria. Especially, the appropriate mixing ratios of bulk and stabilized ceria are very important for designing principles of Pd-only three-way catalysts. In this paper, we discussed the thermal properties of stabilizedand unstabilized (bulk) ceria, and the oxygen storage capacity (OSC) of catalysts, and found the correlation between activity and the OSC of Pd-only catalysts with various different mixing ratios of bulk and stabilized ceria. Finally, we propose the design principles to improve the thermal stability of washcoated Pd-only catalysts.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.4
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• pp.487-494
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• 1996

Simultaneous effects of $C_2H_4$ injection and heterogeneous chemical reactions on non-thermal plasma process to remove $SO_2$ and NOx from flue gas were investigated in the present experimental study. The present results showed that 40% of the electrical power can be reduced in $C_2H_4$ injection and heterogeneous chemical reaction are simultaneously included in the non-thermal plasma precess. As an effort to apply the non-thermal plasma technique to practical flue gas treatment system, a wire-plate type reactor which has technically similar geometry of industrial electrostatic precipitators is used instead of other types of reactors, such as wire-cylinder, packed-bed and surface discharge which are inappropriate to industrial application. In the present study, the photo pictures of positive streamer corona taken by ICCD camera, voltage and current oscillograms, and design criteria of a wire-plate type reactor are also shown, which are needed for industrial application of the non-thermal plasma process.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.2
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• pp.193-204
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• 1998

Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymmetric 2-D CH$_{4}$ jet diffusion flame. Calculations were carried out twice with the $C_{2}$-Thermal Mechanism including $C_{2}$ and thermal NO reactions and the $C_{2}$-Full Mechanism including prompt NO reactions in addition to the above $C_{2}$-Thermal NO mechanism. The results show that the flame structures such as flame temperature, major and minor species concentration are indifferent to respective mechanisms. The production path of Thermal NO is dominant comparing with that of Prompt NO in total NO production of pure CH$_{4}$ jet diffusion flame. This is because thermal NO mechanism mainly contributes to positive formation of NO in the whole flame region, but Prompt NO mechanism contributes to negative formation in the fuel rich region. In addition, 0$_{2}$ penetration near the nozzle outlet affects the flame structures, especially N0$_{2}$ formation characteristics.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.947-949
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• 1998

In this paper, the NO was oxidized $NO_2$ by using the non-thermal plasma and NOx removal characteristics were measured by showering NaOH water-solution to $NO_2$. The NO oxidation increased in the order of DC, AC, and Pulse. NOx oxidation for two stage with applied voltage was better than that for one stage with applied voltage. NO oxidation didn't depend on applied voltage. While NO oxidation was going on, NOx removal efficiency was 20-25%, however, significantly depended on the injection method of air and $H_2O$ + air. When NaOH water-solution density of 20% was showered to flue gases, NOx removal efficiency increased to 64%.

• Journal of Energy Engineering
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• v.9 no.2
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• pp.109-116
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• 2000

저발열량 석탄가스의 thermal/fuel NOx 생성특성과 화염 안정성을 규명하기 위한 실험적 연구를 수행하였다. 저발열량 합성 연료 가스는 일산화탄소, 수소, 질소 및 암모니아를 천연가스 연료와 동일한 입열량을 가지도록 혼합하여 만들었고 , 합성가스는 평면 화염 버너를 공급하여 태웠다. 특정한 합성가스에 대해 당량비를 변화시켜 가며, 비화 또는 역화에 의한 화염안정성을 규명하였고 안정된 화염 영역을 정의하였다. 저발열향 합성가스의 연소시 발생하는 thermal 및 fuel NOx를 측정하여 천연가스 연소시의 경우와 비교하였다.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.2
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• pp.106-114
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• 1996

Extensive experiments were conducted to investigate the emission of DI diesel engine by using DMC(dimethyl carbonate) as an oxygenated fuel additives. The results indicate that smoke reduces almost linearly with fuel oxygen contents. Reductions of HC and CO were attained noticeably, while a small increase in NOx was encountered concurrently. The effective reduction in smoke with DMC was maintained with the presence of CO2, which suggested a low NOx and smoke operation could be obtained in combination of using oxygenated fuel and EGR. Further experiment was conducted a thermal cracking set-up for mechanism studies.

• 한국연소학회:학술대회논문집
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• 2000.05a
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• pp.26-34
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• 2000

Geometry change of burner nozzle has influence on fuel atomizing and combustion characteristics. NOx reduction technologies can be divided into two method; Before combustion method(NOx treatment of fuel) and After combustion method(NOx treatment of flue gas). In this study, experiments are carried out using difference nozzle and combustion condition change to reduce NOx in heavy oil fired thermal utility boiler. These methods have advantage like easy application and low installation cost. By this method NOx can be reduced by 18% and maintain CO emission level.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.65-74
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• 2003

Air pollution included Nitric Oxide(NOx) from heating boilers is increased by pursuing better life. Development of low NOx emission boiler is strongly needed. However commercial burner for heating boiler is also asked to be thermal efficient and low-cost manufactuable in addition to low NOx emission. Small space for combustor including burner is usually allowed. In this study, parametric study of compact low NOx burner for heating boiler was done using numerical analysis and experiments. Commerical computational fluid dynamic(CFD) program named CFX 5-6 was used for numerical analysis of low NOx burner using turbulent diffusion flame. Comparison of outlet NO and outlet temperature under various equivalence ratio and fuel flow rate was performed between experiment and numerical analysis.

• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.61-66
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• 2020

In this study, the effect of characteristics of colloidal silica, which was used as an additive in the compression/coating catalyst process, on activities and thermal stabilities of the catalysts was investigated. The shape, size, specific surface area and porosity, and composition of four different types of colloidal silica materials were analyzed, and the NOx conversion of V₂O₅/TiO₂ catalyst prepared by these colloidal silica were studied. Properties of the catalysts prepared by colloidal silica depend on the nature of the colloidal silica used, in particular the alkaline substances such as Na in the silica were evaluated to be directly effect on the deNOx conversion of the catalyst. In addition, higher silica contents in the colloidal silica were found to improve the deNOx activity and thermal stability of the catalyst.