• 제목/요약/키워드: Thermal NO

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유기질 단열재 열전도율의 경시 변화 (Changes in the Thermal Conductivity of Organic Insulators over Time)

  • 김해나;홍상훈;정의인;김봉주
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
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    • pp.219-220
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    • 2023
  • The thermal conductivity of the insulation material has a great influence on the heat transmission coefficient, which is currently used for energy evaluation of buildings. The thermal conductivity of insulation changes with changes in the environment, such as humidity and ultraviolet rays, and can be expected to with the passage of time. But there is a lack of data on this, so this study measured the thermal conductivity of organic insulation according to environmental conditions and time, As a result, in the case of XPS, the thermal conductivity value increased over time, which is estimated to be due to the decrease in insulation performance as the foaming gas escapes to the outside, and in the case of PIR class2 No.2 and PIR noncombustible, the increased thermal conductivity value is similar, but in the case of PIR class2 No.2, a relatively moderate increase can be seen, and in the case of PIR noncombustible, a large increase is seen at the beginning, which is judged to be due to the decrease in insulation performance as the internal foaming gas is substituted with air from the outside.

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수소/이산화탄소/알곤 혼합 연료의 비예혼합 대향류 화염에서 NO 배출 특성 연구 (A Study of NO Fmission Characteristics in a Non-premixed Counterflow Flame with $H_2/CO_2/Ar$ Blended-fuel)

  • 이기만
    • 한국자동차공학회논문집
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    • 제15권4호
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    • pp.146-153
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    • 2007
  • The detailed chemistry with reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions, have been numerically conducted to investigate the flame structure and NO emission characteristics in a non-premixed counterflow flame of blended fuel of $H_2/CO_2/Ar$. The combination of $H_2,\;CO_2$, and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of $CO_2$. Radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. All mechanisms including thermal, $NO_2,\;N_2O$, and Fenimore are also taken into account to separately evaluate the effects of $CO_2$ addition on NO emission characteristics. The increase of added $CO_2$ quantity causes flame temperature to fall since at high strain rates diluent effect is prevailing and at low strain rates the breakdown of $CO_2$ produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the ratio of the contribution by Fenimore mechanism to that by thermal mechanism in the total mole production rate becomes much larger with increase in the $CO_2$ quantity and strain rate, even though the absolute quantity of NO production is deceased. Consequently, as strain rate and $CO_2$ quantity increase, NO production by Fenimore mechanism is remarkably augmented.

The Adsorption and Decomposition of NO on a Steped ppt(111) Surface

  • Lee, S.B.;Kang, C.Y.;Park, C.Y.;Kwak, H.T.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1995년도 제8회 학술발표회 논문개요집
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    • pp.113-113
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    • 1995
  • The adsorpption and decompposition of NO on a stepped ppt(111) surface have been studied using thermal desorpption sppectroscoppy and Auger electron sppectroscoppy. NO adsorbs molecularly in two different states of the terrace and the stepp, which are distinguishable in thermal desorpption sppectra. NO dissociates via a bent sppecies at the stepp sites on the basis of vibrational sppectrum data repported ppreviously. The dissociation of NO is activation pprocess : the activation energy is estimated to be about 2 kcal/mol. Increase in the NO dissociation with adsorpption tempperature is expplained by a pprocess controlled by different of the dissociated atomic nitrogen from the stepp to the terrace of the surface. In addition to No and N2, the desorpption ppeak of N2O is observed. We conclude that the formation of N2O is attributed to surface reaction of No and N adsorbed on the surface.

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Thr Adsorption and Decomposition of NO on a Stepped Pt(111) Surface

  • Lee, S. B.;Kang, D. H.;Park, C. Y.;Kwak, H. T.
    • Bulletin of the Korean Chemical Society
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    • 제16권2호
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    • pp.157-163
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    • 1995
  • The adsorption and decomposition of NO on a stepped Pt(111) surface have been studied using thermal desorption spectroscopy and Auger electron spectroscopy. NO adsorbs molecularly in two different states of the terrace and the step, which are distinguishable in thermal desorption spectra. NO dissociates via a bent species at the step sites on the basis of vibrational spectrum data reported previously. The dissociation of NO is an activation process : the activation energy is estimated to be about 2 kcal/mol. Increase in the NO dissociation with adsorption temperature is explained by a process controlled by diffusion of the dissociated atomic nitrogen from the step to the terrace of the surface. In addition to NO and N2, the desorption peak of N2O is observed. We conclude that the formation of N2O is attributed to surface reaction of NO and N adsorbed on the surface.

고령자 온열 쾌적감 간이 측정방법 개발에 관한 연구 (Study for the development of portable thermal comfort measurement tool for elderly)

  • 배치혜;이현정;전정윤
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2009년도 추계학술발표대회 논문집
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    • pp.15-20
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    • 2009
  • The purpose of this study is to develop of portable thermal comfort measurement tool for elderly. Using prediction expression of thermal comfort for elderly which derived at previous study, a field studies were conducted. The objects of this survey are old persons over 60 years old and total 296 (male:111 persons, female:145 persons) persons were measured. The actual thermal sensation was compared with predicted thermal sensation calculated with PMV model, and the results shows that there were no correlation between them. Also, appling cheek temperature and hand temperature were useful to predict thermal sensation of elderly people. Especially, predicted thermal sensation using cheek temperature were closely connected with actual thermal sensation of elderly and presented most similar trend to actual thermal sensation.

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메탄 화염에서 염화 탄화수소 화합물이 질소산화물 생성에 미치는 영향 조사 (The Investigation of Influence of Chlorinated Hydrocarbons on $NO_x$ Formation from Methane Flames)

  • 장경;장봉춘;이기용
    • 한국연소학회지
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    • 제13권1호
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    • pp.10-16
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    • 2008
  • Numerical simulations of freely propagating premixed flames burning mixtures of methane and chlorinated hydrocarbons in fuel are performed at atmospheric pressure in order to understand the effect of chlorinated hydrocarbons on the formation of nitrogen oxide. A detailed chemical reaction mechanism is used, the adopted scheme involving 89 gas-phase species and 1017 elementary forward reaction steps. Chlorine atoms available from chlorinated hydrocarbons inhibit the formation of nitrogen oxides by lowering the concentration of radical species. The reduction of NO emission index calculated with thermal or prompt NO mechanism is not linear and is probably related to the saturation effect as $CH_3Cl$ addition is increased, In the formation or consumption of nitrogen oxide, the $NO_2$ and NOCl reactions play an important role in lean flames while the HNO reactions do in rich flames. The molar ratio of Cl to H in fuel has an effect on the magnitude of NO emission index.

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Thermal Fatigue Test of an Annular Structure

  • Hwang Jeong-Ki;Suh Chang-Min;Kim Chae-Ho
    • Journal of Mechanical Science and Technology
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    • 제20권1호
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    • pp.59-65
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    • 2006
  • A half-scaled large test model for the main components of the real annular structure was built and the thermal behaviors were experimented and obtained by thermal cyclic loads. The model design and the test conditions for the thermal loads were determined to take into consideration the thermal and mechanical loads acting on the real annular structure by finite element analyses. Temperature profiles and strains of the main components of the model were measured at an early stage of the test and periodically throughout the test in the given test conditions. After completion of the thermal cyclic tests, no evidence of crack initiation and propagation were identified by a dye penetration test. The measured strains at the critical parts were slightly increased proportionally with the increase in the number of the thermal cycles.

$CO_2$ 첨가가 $CH_4$-공기 대향류 확산화염의 구조 및 NOx 생성에 미치는 영향 (Effect of $CO_2$ Addition on Flame Structure and NOx Formation of $CH_4-Air$ Counterflow Diffusion Flames)

  • 이승로;한지웅;이창언
    • 한국연소학회지
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    • 제4권2호
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    • pp.97-108
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    • 1999
  • This numerical study was to investigate the effect of $CO_2$ addition on the structures and NOx formation characteristics in $CH_4$ counterflow diffusion flame. The importance of radiation effect was identified and $CO_2$ addition effect was investigated in terms of thermal and chemical reaction effect. Also the causes of NOx reduction were clarified by separation method of each formation mechanisms. The results were as follows : The radiation effect was intensified by $CO_2$ addition. Thermal effect mainly contributed to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. The reduction of thermal NO was dominant with respect to reduction rate, but that of prompt NO was dominant with respect to total amount.

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우유의 가열 및 비가열 살균 기술에 관한 연구 동향 (Impact of Thermal and Nonthermal Technologies in Milk Processing)

  • 박중근;이여진;윤준용;엄애선
    • Journal of Dairy Science and Biotechnology
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    • 제33권3호
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    • pp.223-229
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    • 2015
  • Milk is a food with high nutritional value as it contains abundant water, proteins, vitamins, lactose, fat, minerals, enzymes, etc. However, in order to make milk suitable for intake, it should be thermally treated to eliminate microbiologically hazardous factors. Heat treatment is an essential sanitation process for milk, but various precautions must be taken in order to process and preserve it. Therefore, various techniques should be developed to minimize the nutrient loss and to ensure that milk is safe for consumption, conservation, and distribution. However, the existing thermal pasteurization methods are harmful and increase the nutrient loss; moreover, no new thermal pasteurization methods are being researched that are safe for the human health and minimize the nutrient loss. Hence, this study aims to review new processes for thermal (low temperatures) and no thermal pasteurization methods that can minimize the nutrient loss during milk pasteurization.

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고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구 (A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas)

  • 이한민;윤재근;홍정구
    • 한국분무공학회지
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    • 제25권3호
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    • pp.132-138
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    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.