• Analytical Science and Technology
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• v.22 no.4
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• pp.285-292
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• 2009

It has been observed that, after long term storage, some ammunitions are misfired by tamping (combustionstopping) due to aging of the chemicals loaded in the ammunitions. Used in ammunitions are percussion powder which provides the initial energy, igniter which ignites the percussion powder, and a delay system that delays the combustion for a period of time. The percussion powder is loaded first, followed by the igniter and then the delay system, and the ammunitions explode by the energy being transferred in the same order. Tamping occurs by combustion-stopping of the igniter or insufficient energy transfer from the igniter to the delay system or the combustion-stopping of the delay system, which are suspected to be caused by low purity of the components, inappropriate mixing ratio, size distribution of particulate components, type of the binder, blending method, hydrolysis by the humidity penetrated during the long term storage, and chemical changes of the components by high temperature. Goal of this study is to find the causes of the combustion-stopping of the igniter and the delay system of the ammunitions after long term storage. In this study, a method was developed for testing of the combustion-stopping, and the size distributions of the particulate components were analyzed with field-flow fractionation (FFF), and then the mechanism of chemical change during long term storage was investigated by thermal analysis (differential scanning calorimetry), XRD (X-ray diffractometry), and XPS (X-ray photoelectron spectroscopy). For the ignition system, M (metal)-O (oxygen) and M-OH peaks were observed at the oxygen's 1s position in the XPS spectrum. It was also found by XRD that $Fe_3O_4$ was produced. Thus it can be concluded that the combustion-stopping is caused by reduction in energy due to oxidation of the igniter.

• Korean Chemical Engineering Research
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• v.52 no.2
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• pp.233-239
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• 2014

The slagging which generated from ash deposition on furnace wall and tube in boiler reduces the heat transfer efficiency and damages to safety of boiler. The slag flow behavior in boiler is affected by melting temperature which is related to ash compositions. In this study, the behavior of slag is researched by using ash fusibility test, called TMA (Thermo-Mechanical Analysis). The technique measures the percentage shrinkage as the function of temperature, T25%, T50%, T75%, T90%. These temperatures indicate different stages of melting. Then, the effect of ash chemical compositions measured from XRF (X-ray Fluorescence Spectrometer) to ash fusion temperatures is discussed. Among the chemical compositions, refractory and fluxing influence on ash fusibility is described. High levels of refractory component and limited amount of fluxing components ($Fe_2O_3$, $K_2O$, CaO) increase overall melting temperatures. High $SiO_2/Al_2O_3$ ratio decrease high melting temperatures (T75%, T90%). Meanwhile, the presence of reasonable levels of fluxing components reduces overall melting temperature. A presence of fluxing component such as $K_2O$ and CaO is found to decrease the T25% values significantly. From this research, it is possible to make a reasonable explanation and prediction of ash fusion characteristic from analysis of TMA results and ash chemical compositions.

• Journal of the Society of Naval Architects of Korea
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• v.39 no.2
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• pp.52-60
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• 2002

Line heating is a forming process which makes the curved surface with the residual strain created by applying heat source of high temperature to steel plate. in order to control the residual strain, it is necessary to understand not only conductive heat transfer between heat source and steel plate, but also temperature distribution of steel plate. In this paper we attempted to analyze is temperature distribution of steel plate by simplifying a line heating process to collision-effusive flux of high temperature and high velocity, and conductive heat transfer phenomenon. To analyze this, combustion in the torch is simplified to collision effusive phenomenon before analyzing turbulent heat flux. The distribution of temperature field between the torch and steel plate is computed through turbulent heat flux analysis, and the convective heat transfer coefficient between effusive flux and steel plate is calculated using approximate empirical Nusselt formula. The velocity of heat flux into steel plate is computed using the temperature distribution and convective heat transfer coefficient, and temperature field in the steel plate is obtained through conductive heat transfer analysis in which the traction is induced by velocity of heat flux. In this study, Finite Element Method is used to accomplish turbulent heat flux analysis and conductive heat transfer analysis. FEA results are compared with empirical data to verify results.

• Current Research on Agriculture and Life Sciences
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• v.33 no.2
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• pp.41-47
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• 2015

This study calculated the overall heat transfer coefficient (U-value) of greenhouse covering materials with thermal screens using a simulation model and then estimated the validity of the calculated results by comparison with measured values. The U-value decreased gradually as the thickness of the air space between the double glazing increased, and then remained essentially constant at thicknesses exceeding 25 mm. The U-value also increased with the difference in temperature between the inside and outside of the hot box. The vigorous convective heat transfer between two plastic films caused unsteady heat flow and then created a nonlinear temperature distribution in the air space. The distance did not affect the U-value at distances of 50~200 mm between the plastic covering and thermal curtain. The numerical calculation results, with and without sky radiation, were in accord with the experimental results for a $30^{\circ}C$ temperature difference between the inside and outside of the hot box. In conclusion, a reliable U-value can be calculated for a temperature difference of $30^{\circ}C$ or more between the inside and outside of the hot box.

• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.250-254
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• 2006

Reaction of $CO_2$ with $Li_{2}ZrO_{3}$ has been investigated in a TGA and the effects of $H_{2}$ and CO on the removal of $CO_{2}$ using $Li_{2}ZrO_{3}$ were evaluated in a packed bed reactor. The initial rate of $CO_{2}$ removal reaction of $Li_{2}ZrO_{3}$ increased with the increase of gas flow rate up to 100 mL/min and then was maintained, which implied the disappearance of the gas film resistance. The reaction of $CO_{2}$ with $Li_{2}ZrO_{3}$ took place as the first order and the range of optimum temperature was found to be about $500{\sim}600^{\circ}C$. XRD and SEM analysis showed the formation of crystalline $Li_{2}ZrO_{3}$ and porous $Li_{2}ZrO_{3}$/$ZrO_{2}$. The presence of $H_{2}$ did not affect the adsorption of $CO_2$ with $Li_2ZrO_3$. On the other hand, CO inhibited the sorption of $CO_{2}$ into $Li_{2}CO_{3}$(L) on $Li_{2}ZrO_{3}$.

• Polymer(Korea)
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• v.33 no.4
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• pp.358-363
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• 2009

Maleic anhydride-grafted polypropylene has been widely used to improve the interfacial interaction between the components in PP/polar polymer blends and PP/filler composites and to maximize the physical properties and thermal properties. In this paper. the maleic anhydride (MAH)-grafted polypropylene (co-PP) was fabricated through reactive extrusion process with di-cumyl peroxide (DCP) as an initiator. The grafting degree of MAH depending on the contents of DCP and MAH was investigated by FT-IR spectra and chemical titration. The grafting degree increased with increasing MAH concentration and also showed maximum value at 0.06 wt% of DCP concentration. Melt flow index (MFI) of the grafted copolymer was increased with increasing the contents of MAH. The DSC and TGA analysis data indicate the melting temperature and thermal degradation of PP depending on the grafting degree of MAH.

• Transactions of the KSME C: Technology and Education
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• v.5 no.2
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• pp.135-143
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• 2017

The domestic unique research reactor, HANARO (Hi-flux Advanced Neutron Application ReactOr), has been constructed with the open-pool, the core is submerged in, for the multi-purpose neutron application. The reactor has a primary cooling system to remove the fission heat from the core and its connected fluidic systems. Since the works are required at the reactor pool top as a characteristic of the research reactor, the radiation shall be minimized with the operation of the hot water layer system to avoid unnecessary radiation exposure on the workers during work at the pool top. Moreover, the pool water management system is connected to the reactor pool to maintain the pool temperature below $50^{\circ}C$ to minimize the uprising radioactive gas or impurity from the colder pool bottom. For the efficient flow rate of the PWMS, the thermal capacity of heat exchanger is selected with 260 kW in the normal operation condition. In this paper, the modeling is formulated to figure out whether or not each pool temperature maintains below the temperature limit and the calculation results show that the designed PWMS heat exchanger has enough capacity with the design margin regardless of the reactor operation mode.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.99-105
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• 2005

To evaluate structural safety factor of the jet vane for the thrust deflection system under the dynamic pressure and very high temperature($2700^{\circ}C$) of the combustion gas flow, the high temperature tension tests of refractory metals and 3-D nonlinear numerical simulations are performed. Through the analysis of high temperature structural behavior for jet vane, the structural safety of jet vane is evaluated, and numerical results are compared with static pound tests of jet vanes. It has been found that most of structural and thermal loading is concentrated on the vane shaft which worked as safe under $1400^{\circ}C$. From the comparison of static ground tests and numerical results, the evaluation criterion using the vane load and shaft displacement is more useful to estimate the structural safety than using the equivalent stress.

• Journal of Sensor Science and Technology
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• v.3 no.2
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• pp.74-80
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• 1994

Silicon direct bonding technology is very attractive for both silicon-on-insulator devices and sensor fabrication because of its thermal stress free structure and stability. The process of SDB includes hydration of silicon wafer and heat treatment in a wet oxidation furnace. After hydration process, hydroxyl groups of silicon wafer were analyzed by using Fourier transformation-infrared spectroscopy. In case of hydrophilic treatment using a ($H_{2}O_{2}\;:\;H_{2}SO_{4}$) solution, hydroxyl groups are observed in a broad band around the 3474 $cm^{-1}$ region. However, hydroxyl groups do not appear in case of diluted HF solution. The bonded wafer was etched by using tetramethylammonium hydroxide etchant. The surface of the self etch-stopped silicon dioxide is completely flat, so that it can be used as sensor applications such as pressure, flow and acceleration, etc..

• Journal of Biosystems Engineering
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• v.26 no.3
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• pp.263-270
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• 2001

This study was conducted in order to develop wind-water heating system where frictional heat is creased between the rotor and working fluid when they are rotating in the cylindrical heat generator. The wind-water heating system is composed of rotor, stator, working fluid, motor, inverter and heat generation tank. Instead of wind turbine, we have used an electrical motor of 30㎾ to rotate the rotor in this system. Two working fluids and six levels of rotor rpm were tested to quantify heat amounts generated by the system. Generally, as motor rpm goes up heat amount increases that we have expected. At the same rpm, viscous fluid showed up better performance than the water, generating more heat by 10$\^{C}$ difference. The greatest heat amount of 31,500kJ/h was obtained when the system constantly drained out the hot water of at the flow rate of 500ℓ/h. Power consumption rate of the motor was measured by thee phase electric power meter where the largest power consumption rate was 14㎾ when motor rpm was 600 and gained heat was 31,500kJ/h, that indicated total thermal efficiency of the wind power water heating system was 62%.