• 제목/요약/키워드: Thermal Cracking

검색결과 372건 처리시간 0.025초

석유정제산업 공정과 공정장비에 기인한 휘발성 유해 대기오염물질(HAPs)의 배출량 산정기법 (Estimation Technique of Volatile Hazardous Air Pollutants(HAPs) Emitted from Petroleum Industrial Process/Equipment)

  • 조완근;권기동;동종인;강경희
    • 한국환경과학회지
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    • 제13권7호
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    • pp.703-710
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    • 2004
  • Petroleum refineries have been considered as an important emission source for atmospheric volatile hazardous air pollutants(HAPs). The emission source includes petroleum refinery processes and process equipment. The control strategy for volatile HAPs requires emission estimations of these pollutants. However, systematic methods of volatile HAPs emission from petroleum refineries have not yet been established. Accordingly, present study surveyed the estimation method of volatile HAPs emitted from the petroleum refinery processes and process equipment. The emission estimation methods for the petroleum refinery processes are applied for 11 petroleum refining facilities: fluidized catalytic cracking, thermal cracking, moving bed catalytic cracking, compressed engine, blowdown system, vacuum distilled column condensator, natural gas or distilled boiler, natural gas or distilled heater, oil boiler, oil heater and flare. Four emission estimation methods applied for the petroleum refinery process equipment are as follows: average emission factor approach, screening ranges approach, EPA correlation approach and unit-specific correlation approach. The process equipment for which emission factors are available are valves, pump seals, connectors, flanges and open-ended lines.

수화열 해석 프로그램에 의한 저발열 콘크리트의 특성에 미치는 부재두께 및 양생온도의 영향에 관한 연구 (A Study on Effect of Specimen Thickness and Curing Temperature on Properties of Low Heat Concrete by Analysis Program for Heat of Hydration)

  • 이승민;노형남;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2008년도 추계 학술논문 발표대회
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    • pp.31-36
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    • 2008
  • This study aims to examine the effects of thickness of the concrete members and curing temperature on the properties of low heat concrete through heat of hydration analysis. Type of the members that was analyzed in the experiment is ternary mixture of ordinary portland cement, blast-furnace slag incorporating ratio(20%) and fly ash incorporating ratio(30%), which formed a mat foundation. Thicknesses of the concrete members were 1, 2 and 3(m) and three levels of curing temperatures were 10, 20 and 30(℃). They were applied to analyze the effects on the temperature and thermal cracking index. As a result, for temperature history, temperature difference between the central area and the surface tended to decrease as the thickness of the concrete members get thinner. For the temperature cracking index, on the other hand, the risk of cracking tended to decrease as the curing temperature gets higher and as the thickness gets thinner.

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선박용 Al-황동세관의 SCC에 미치는 부식환경의 영향 (Effect of corrosion environment on the SCC of Al-brass tube for vessel)

  • 임우조;정해규
    • 수산해양기술연구
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    • 제39권4호
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    • pp.291-297
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    • 2003
  • Al-brass is usually used as the tube material of vessel's heat exchanger for seawater cooling system because it has high thermal conductivity and good mechanical properties and high corrosion resistance due to cuprous oxide (Cu20) layer against seawater. However, Al-brass tubes of heat exchanger for vessel at the actual environment is reported that local corrosion such as stress corrosion cracking occurred by synergism effect between mechanical factor and corrosion environment In this paper, the effect of corrosion environment on the stress corrosion cracking of Al-brass in various NH4OH of 3.5% NaCl solution, under flow by constant displacement tester. Based on the test results, the behavior of polarization, stress corrosion crack propagation and dezincification phenomenon of Al-brass are investigated. The main results are as follows:(1) Increasing range of potential from open circuit potential to repassivation gets lower, as the contain rate of NH4OH gets higher. (2) As contain rate of NH4OH gets higher, SCC of Al-brass is become activation but the protection film(Cu20) of Al-brass is created in 3.5% NaCl solution. (3) According as content of NH4OH increases in 3.5% NaCl solution, the dezincifiction area is spread. It is concluded that dezincification occurred by localized preferential anodic dissolution at stress focusing region.

복합재 원통구조물의 열-점탄성적 잔류음력 및 열좌굴 해석 (Analysis of Thermo-Viscoelastic Residual Stresses and Thermal Buckling of Composite Cylinders)

  • 김철;김영국;최웅
    • 대한기계학회논문집A
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    • 제26권8호
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    • pp.1653-1665
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    • 2002
  • One of the most significant problems in the processing of composite materials is residual stresses. The residual stresses may be high enough to cause cracking in the matrix even before external loads are applied and can degrade the integrity of composite structures. In this study, thermo-viscoelastic residual stresses occurred in the polymeric composite cylinder are investigated. This type of structure is used for the launch vehicle fuselage. The time and degree of cure dependent thermo-viscoelastic constitutive equations are developed and coupled with a thermo-chemical process model. These equations are solved with the finite element method to predict the residual stresses in the composite structures during cure. A launch vehicle experiences high thermal loads during flight and re-entry due to aerodynamic heating or propulsion heat, and the thermal loads may cause thermal buckling on the structure. In this study the thermal buckling analysis of composite cylinders are performed. Two boundary conditions such as all clamped and all simply supported are used for the analysis. The effects of laminates stacking sequences, shapes and residual stresses on the critical buckling temperatures of composite cylinders are investigated. The thermal buckling analysis is performed using ABAQUS.

CRM 아스팔트의 최적 혼합비와 환경친화적 특성 (Environmental Friendly Characteristics of CRM Asphalt Concrete and Optimal Mixing Ratio)

  • 류병로;한양수
    • 한국환경과학회지
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    • 제10권4호
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    • pp.311-314
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    • 2001
  • The asphalt mixture with CRM(Crumb Rubber Modifier) is known to show a better performance in resisting thermal cracking, fatigue cracking and rutting compared with the conventional mixture. The laboratory tests on the physical characteristics of indirect tensile strength, density, flow and Marshall value of the CRM asphalt were conducted. The test results show that CRM asphalt has better physical characteristics than that of conventional asphalts. And the analysis on the noise reduction effect, penetration capacity from the field test on the national road in Haksan of Chungbuk, and recycling of tire waste were conducted. From this study, the results show that 1% CRM asphalt has higher the noise reduction effect and penetration capacity that those of conventional asphalts. And, optimal contents of crumb rubber modifier in the asphalt binder is one percent. In this case, crumb rubber modifier were used 10 kg to make the asphalt binder of one cubic meter. So it was named as Eco-asphalt.

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와이어링 PVC 테이프 내구 수명 예측 (Prediction Method of Useful Life of PVC Tape for Wiring Harness)

  • 김성우;정원욱;박종구;안미정
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제7권4호
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    • pp.163-172
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    • 2007
  • Phenomenon, such as hardening, cracking or breaking etc.. of PVC tape for wiring harness by aging were detected on driven automobile in field. Hardening or cracking of PVC tape were confirmed decline of elongation by surrounding stress. The accelerated heat aging test was carried out applying temperature most important factor of aging, and then deduced an equation of useful life using arrhenius model. Prediction method of useful life of PVC tape was developed using miner rule calculating damage value by thermal energy classified temperature by matching deduced equation of useful life and measured temperature value on driven automobile in field.

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고온의 염기성 수용액에서 Ni기 합금의 응력부식파괴

  • 김홍표;황성식;국일현;김정수
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1998년도 춘계학술발표회논문집(2)
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    • pp.84-89
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    • 1998
  • Alloy 600 및 alloy 690과 Ni-8Cr-lOFe 합금 등의 응력부식(stress corrosion cracking, SCC) 거동을 고온의 염기성 분위기에서 C-ring 시편을 사용하여 연구하였다. Alloy 600과 alloy 690을 여러 조건에서 열처리하여 etching한 후 탄화물의 분포와 입계 주변의 Cr고갈 정도 등의 미세조직을 광학현미경과 주사 전자현미경(SEM)으로 관찰하였다. 이들 재료에 대한 SCC 시험을 315$^{\circ}C$의 40% NaOH 수용액에서 일정한 부하전위(부식전위 + 200㎷)를 가하면서 수행하였으며, 동일 조건에서의 분극거동도 측정하였다. Alloy 600 MA(mill anneal) 및 TT(thermal treatment)의 SCC 저항성은 alloy 690 TT와 Ni-8Cr-10Fe SA(solution anneal)보다 낮았다. Alloy 600 TT 재료는 alloy 600 MA 및 SA 재료에 비해 SCC 저항성이 더 컸다. 고용 탄소농도는 alloy 600의 SCC 저항성에 큰 영향을 주지 못했다. 대부분의 Alloy 600은 균열전파 입계균열을 보였으나, 일부에서는 입계 및 입내 혼합양상(mixed mode cracking)을 보였다. 염기성 분위기에서 Ni기 합금의 SCC 거동을 미세조직, 분극거동의 관점에서 고찰하였다.

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다양한 개질 아스팔트 시멘트와 혼합물의 실험적 공용 특성 평가에 관한 연구 (A Study on Laboratory Performance Characteristics of Modified Asphalt Cements and Mixtures)

  • 김낙석;임정순;박현식;이종만
    • 한국재난정보학회 논문집
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    • 제3권1호
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    • pp.21-35
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    • 2007
  • The principal objective of this research is to evaluate the laboratory mechanical characteristics of color asphalt binders and mixtures. The dynamic shear rheometer (DSR) tests were performed to analyze the viscous and elastic behavior of asphalt binders. Various tests were also conducted to investigate the laboratory performance characteristics of color asphalt mixtures. The test results revealed that the values of $G^*$ and ${\delta}$ of modified color binders were higher than those of the conventional binders at low temperatures. These results are expected to increase the thermal cracking resistance of asphalt mixtures at low temperatures. It should be noted that the color asphalt mixtures with modified asphalt binder can be widely used as a common pavement material with a proper mix design.

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$620^{\circ}C$급 터빈 케이싱용 고Cr 페라이트강의 용접성 (Weldability of $620^{\circ}C$ Grade High Cr Ferrite Cast Steel for Turbine Casing)

  • 변지철;방국수;권희경;지병하
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2006년도 춘계 학술대회 개요집
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    • pp.274-276
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    • 2006
  • Weldability of high Cr ferritic steel for $620^{\circ}C$ grade turbin casing were investigated. The effect of carbon content on the cold and hot cracking susceptibility and HAZ softening was determined. The cast steel with higher carbon content showed higher HAZ hardness because of the dissolution of cabonitrides during welding thermal cycle. Moreover, it showed higher solidification cracking sensitivity because of the little S-ferrite formation in weld metal. Both steels showed HAZ softening at $900^{\circ}C$ peak temperature after PWHT.

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플라이애쉬를 혼합한 매스콘크리트의 품질관리 (The Quality Control of Mass Concrete mixed with Fly-Asy)

  • 박칠림;권영호;이상수;김동석;박상준
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1998년도 가을 학술발표대회 논문집(III)
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    • pp.940-945
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    • 1998
  • Recently, serious cracking problems have been reported in this country while the process of actual massive concrete construction. he hydration heat arising from the chemical reaction of cement with water causes temperature differentials in between inside and outside of a structural member, and these temperature differentials induce thermal stresses. In this paper, we described on the practical application and quality control of the mass concrete mixed with fly-ash. This project is investigating adiabatic temperature rise test of concrete, mock-up test in the laboratory, ad B/P before placing the mass concrete in site. As a result, we can be prevent temperature cracking from the cement hydration heat of mass concrete and also can be showed up secure quality control flow chart of mass concrete.

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