• 제목/요약/키워드: Thermal Conductivity Ratio

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리튬 폴리머전지용 PVDF/PAN계 전해질의 이온 전도 특성 (Son Conduction Properties of PVDF/PAN based for Lithium Polymer Battery)

  • 이재안;김종욱;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.374-377
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    • 1999
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. This paper describes temperature dependence of conductivity, impedance spectroscopy, electrochemical properties of PVDF/PAN electrolytes as a function of a mixed ratio. PVDF/PAN based polymer electrolyte films were prepared by thermal gellification method of preweighed PVDF/PAN, plasticizer and Li salt. The conductivity of PVDF/PAN electrolytes was 10-3S/cm. 20PVDF5PANLiCIO$_4$PC$\sub$10//EC$\sub$10/ electrolyte shows the better conductivity of the others. 20P7DF5PANLiCI$_4$PC$\sub$10//EC$\sub$10/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and ac impedance used for the determination of transference numbers in PVDF/PAN electrolyte film. The transference number of 20PVDF5ANLICIO$_4$/PC $\sub$10//EC$\sub$10/ electrolyte is 0.48

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바이오차를 혼입한 콘크리트의 물성 특성과 단열성능에 미치는 영향 (Effect of Concrete Containing the Biochar on Properties and Thermal Insulation Performance)

  • 김경철;임광모;손민수;류금성;고경택
    • 한국건설순환자원학회논문집
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    • 제10권4호
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    • pp.428-434
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    • 2022
  • 본 연구에서는 바이오차를 혼입한 친환경 콘크리트 패널을 개발하고자 한다. 단열성능과 탄소 포집이 가능한 바이오차를 혼입시킨 다공성 콘크리트의 물리적 특성, 역학적 특성 및 열적 특성 실험을 수행하였다. 다공성 콘크리트 배합은 바이오차 혼입율 0, 5, 10 및 15 %와 물-시멘트 비를 0.35로 고정하여 배합조건을 구성하였다. 기본 역학적 특성을 평가하기 위해 단위중량, 총 공극률 및 투수계수를 측정하였다. 바이오차 혼입율이 증가함에 따라 총 공극률과 투수계수는 증가하지만 단위중량은 감소하였다. 콘크리트 압축강도는 바이오차 혼입율이 증가할수록 감소하지만 설계기준 압축강도 이상을 확보하였다. 열전도율은 바이오차 혼입율이 증가할수록 감소하는 경향을 나타내어 단열성능에 뛰어난 재료임을 증명하였다. 또한 회귀분석을 통해 다공성 콘크리트의 단위중량, 총 공극률, 콘크리트 압축강도 및 열전도율과 상관관계를 제시하였다. 상관관계 분석을 통해 바이오차의 적용 범위를 확대하기 위한 주요 변수를 제시하였다.

전도체가 존재하는 자연대류 현상에 대한 수치적 유동 가시화 (Thermal Convection with Conducting Lid)

  • 하만영;이재룡
    • 한국가시화정보학회:학술대회논문집
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    • 한국가시화정보학회 2005년도 추계학술대회 논문집
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    • pp.117-120
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    • 2005
  • This study of thermal convection uses the following geometry: a horizontal layer of fluid heated from below of solid lid at bottom and cooled from above. A variety range of thermal conductivity ratio, $\kappa$ is considered to investigate the interface temperature, $\theta_{i}$ between solid and fluid region. Periodic boundary conditions are employed in the horizontal direction to allow for lateral freedom for the convection cells. A two-dimensional solution for unsteady natural convection is obtained, using an accurate and efficient Chebyshev spectral multi-domain methodology, for different effective Rayleigh numbers, $Ra_{eff}$ varying over the range of $10^{4}\;to\;10^{7}$ in which the effective Rayleigh number is defined as $Ra{\times}<\overline{T}_{i}>$.

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폐타이어 분말 및 시멘트를 혼합한 동결토의 특성 (The Property of Frozen Soil Mixed with Shredded Tire and Cement)

  • 김영진;손승모
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 추계 학술발표회
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    • pp.1487-1493
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    • 2008
  • The frost heaving is related with thermal conduction rate and permeability. If the thermal conduction rate can be controlled, it is effective to prevent from frost heaving. If soil mixed with shredded tire which has relatively lower thermal conduction rate than soil, it helps preventing from frost heaving. However, in this case, the shear strength can get weak. In this study, we compared thermal conduction rate of soil and shredded tire, and test uniaxial compression strength of soil which is mixed with shredded tire and cement in different ratio.

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A Compilation and Evaluation of Thermal and Mechanical Properties of Bentonite-based Buffer Materials for a High- level Waste Repository

  • Cho, Won-Jin;Lee, Jae-Owan;Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • 제34권1호
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    • pp.90-103
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    • 2002
  • The thermal and mechanical properties of compacted bentonite and bentonite-sand mixture were collected from the literatures and compiled. The thermal conductivity of bentonite is found to increase almost linearly with increasing dry density and water content of the bentonite. The specific heat can also be expressed as a function of water ontent, and the coefficient of thermal expansion is almost independent on the dry density. The logarithm of unconfined compressive strength and Young’s modulus of elasticity increase linearly with increasing dry density, and in the case of constant dry density, it can be fitted to a second order polynomial of water content. Also the unconfined compressive strength and Young’s modulus of elasticity of the bentonite-sand mixture decreases with increasing sand content. The Poisson’s ratio remains constant at the dry density higher than 1.6 Mg/m$_3$, and the shear strength increases with increasing dry density.

A Study on the Thermal Properties of CNT reinforced Semiconductive Shield Materials Used in Power Cables

  • Yang, Hoon;Bang, Jeong-Hwan;Chang, Hong-Soon;Nah, Chang-Woon;Park, Dae-Hee
    • Journal of Electrical Engineering and Technology
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    • 제3권1호
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    • pp.115-120
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    • 2008
  • Use of the carbon nanotube is superior to general powder state materials of mechanical and electrical properties. Because its ratio of diameter and length (aspect ratio) is very large, it has been known as a type of ideal nano-reinforcement material. Based on this advantage, the existing carbon black of semiconductive shield materials used in power cables can acquire excellent properties by using a small amount of carbon nanotubes. Thus, we investigated the thermal properties of the carbon nanotube, such as thermal conductivity, specific heat, and DSC (Differential Scanning Calorimetry). We found that a high thermal resistance level is demonstrated by using a small amount of carbon nanotubes. As a result, this tendency confirms high cross-linking density in a new network in which the carbon nanotube between carbon black constitute molecules shows a bond by similar constructive properties.

Performance evaluation of natural fiber reinforced high volume fly ash foam concrete cladding

  • Raj, Amritha;Sathyan, Dhanya;Mini, K.M.
    • Advances in concrete construction
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    • 제11권2호
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    • pp.151-161
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    • 2021
  • The major shortcoming of concrete in most of the applications is its high self-weight and thermal conductivity. The emerging trend to overcome these shortcomings is the use of foam-concrete, which is a lightweight concrete consisting of cement, filler, water and a foaming agent. This study aims at the development of a cost-effective high-volume fly-ash foam-concrete insulation wall cladding for existing buildings using natural fiber like rice straw in different proportions. The paper reports the results of systematic studies on various mechanical, acoustic, thermal and durability properties of foam-concrete with and without replacement of cement by fly-ash. Fly-ash replaces 60 percent by weight of cement in foam-concrete. The water-solid ratio of 0.3, the filler ratio of 1:1 by weight, and the density of 1100 kg/㎥ (approx.) are fixed for all the mixes. Rice straw at 1%, 3% and 5% by weight of cement was added to improve the thermal and acoustic efficiency. From the investigations, it was inferred that the strength properties were increased with fly-ash replacement up to 1% rice straw addition. In furtherance, addition of rice straw and fly-ash resulted in improved acoustic and thermal properties.

탄소/페놀릭 8-매 주자직 복합재료의 열전도도 (Thermal Conductivity of Carbon-Phenolic 8-Harness Satin Weave Composite)

  • 우경식;구남서
    • 한국항공우주학회지
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    • 제31권9호
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    • pp.18-25
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    • 2003
  • 본 연구에서는 탄소/페놀릭 8-매 주자직 복합재료인 ACP302의 등가열전도계수를 단위구조해석을 통하여 계산하였고 또한 실험적으로 측정하였다. 먼저 8-매 주자직 복합재료의 직조섬유다발구조를 3차원 유한요소를 사용하여 미세역학적으로 상세히 모델링하였으며, 단위구조 경계면에는 주기경계조건을 가하고 해석을 수행하였다. 계산결과로부터 적층 형상 및 굴곡도, 섬유 체적비 등이 등가열전도도에 미치는 영향을 조사하였다. 또한 실험을 수행하여 열전도도를 계측하였으며 그 결과를 계산결과와 비교하였다.

나노/마이크로 에폭시 복합체의 전기적, 열적특성 분석 (Analysis of electrical, thermal characteristic of Nano/Micro Epoxy composite)

  • 정의환;윤재훈;임기조;정수현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.99-99
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    • 2010
  • Polymer nanocomposite has been attracting much attention as a new insulation material, since homogeneous dispersion of nm-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy based nanocomposites were made and AC breakdown strength of Nano-TiO2 and micro-silica filler mixture of epoxy based composites were studied by sphere to sphere electrode. Moreover, nano- and micro-filler combinations were adopted as an approach toward practical application of nanocomposite insulation materials. Nano-TiO2 particle size is about 10nm and composites ratio was resin (100) : hardener (82) : accelerator (1.5). AC breakdown test was performed at room temperature (25 [$^{\circ}C$], 80 [$^{\circ}C$] and 100 [$^{\circ}C$] in the vicinity of Tg (90[$^{\circ}C$]). And thermal conductivity were measured by ASTM-D5470.

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열가소성 고분자를 이용한 다공질 알루미나의 제조 (Fabrication of Porous Al2O3 Ceramics Using Thermoplastic Polymer)

  • 이상진;김해두
    • 한국세라믹학회지
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    • 제41권7호
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    • pp.513-517
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    • 2004
  • 기공크기와 형태를 제어하여 열전도도 이방성을 나타내기 위해 판상의 기공이 배향된 다공질 알루미나 소결체의 제조방법을 연구하였다. 속이 가스로 차있는 열가소성 고분자 microsphere를 알루미나 분말과 혼합한 후 일축 가압 열변형 방법을 이용하여 15 MPa의 압력으로 가압한 상태에서 20$0^{\circ}C$까지 승온하여 microsphere를 판상으로 변형시킨 후, 1,00$0^{\circ}C$에서 1시간동안 소결하였다. Microsphere의 함량이 10wt%인 경우 45.3%의 기공율을 나타내었으며, 44 MPa의 꺾임강도 값을 나타내었다. 미세구조를 살펴본 결과 판상기공이 압축방향과 수직방향으로 배향되었으며, 열전도도를 측정한 결과 압축방향으로 3.803 W/mK, 측면방향으로는 7.818 W/mK로서 두 값의 비는 2 이상이었다.