• Title/Summary/Keyword: Thermal Conductivity Ratio

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Son Conduction Properties of PVDF/PAN based for Lithium Polymer Battery (리튬 폴리머전지용 PVDF/PAN계 전해질의 이온 전도 특성)

  • 이재안;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.374-377
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    • 1999
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. This paper describes temperature dependence of conductivity, impedance spectroscopy, electrochemical properties of PVDF/PAN electrolytes as a function of a mixed ratio. PVDF/PAN based polymer electrolyte films were prepared by thermal gellification method of preweighed PVDF/PAN, plasticizer and Li salt. The conductivity of PVDF/PAN electrolytes was 10-3S/cm. 20PVDF5PANLiCIO$_4$PC$\sub$10//EC$\sub$10/ electrolyte shows the better conductivity of the others. 20P7DF5PANLiCI$_4$PC$\sub$10//EC$\sub$10/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and ac impedance used for the determination of transference numbers in PVDF/PAN electrolyte film. The transference number of 20PVDF5ANLICIO$_4$/PC $\sub$10//EC$\sub$10/ electrolyte is 0.48

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Effect of Concrete Containing the Biochar on Properties and Thermal Insulation Performance (바이오차를 혼입한 콘크리트의 물성 특성과 단열성능에 미치는 영향)

  • Kyoung-Chul, Kim;Kyung-Taek, Koh;Min-Su, Son;Gum-Sung, Ryu;Jae-Yoon, Kang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.428-434
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    • 2022
  • This study intends to develop an eco-friendly concrete panel mixed with biochars. Experiments about mechanical and thermal properties were conducted on porous biochar concrete, which has insulation and carbon-capture performance. The concrete has a mixing ratio of 0, 5, 10, and 15 % for biochar and a water-binder ratio of 0.35. The unit weight, porosity, and permeability were measured to evaluate the mechanical characteristics. From the results, as the biochar mixing rate increased, the porosity and the permeability increased, but the unit weight decreased. Even though a decreased trend was observed in the compressive strength results, they satisfied the design standard. Since the thermal conductivity was decreased during the increase of contents, biochar could be considered an excellent material for insulation performance. In addition, regression analyses were conducted regarding the relationship of unit weight with porosity, compressive strength with thermal conductivity, and porous with thermal conductivity. From the regression, significant variables for expanding the scope of the application of biochar were presented.

Thermal Convection with Conducting Lid (전도체가 존재하는 자연대류 현상에 대한 수치적 유동 가시화)

  • Ha Man Yeong;Lee Jae Ryong;Balachandar S.
    • 한국가시화정보학회:학술대회논문집
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    • 2005.12a
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    • pp.117-120
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    • 2005
  • This study of thermal convection uses the following geometry: a horizontal layer of fluid heated from below of solid lid at bottom and cooled from above. A variety range of thermal conductivity ratio, $\kappa$ is considered to investigate the interface temperature, $\theta_{i}$ between solid and fluid region. Periodic boundary conditions are employed in the horizontal direction to allow for lateral freedom for the convection cells. A two-dimensional solution for unsteady natural convection is obtained, using an accurate and efficient Chebyshev spectral multi-domain methodology, for different effective Rayleigh numbers, $Ra_{eff}$ varying over the range of $10^{4}\;to\;10^{7}$ in which the effective Rayleigh number is defined as $Ra{\times}<\overline{T}_{i}>$.

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The Property of Frozen Soil Mixed with Shredded Tire and Cement (폐타이어 분말 및 시멘트를 혼합한 동결토의 특성)

  • Kim, Young-Chin;Son, Seung-Mo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1487-1493
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    • 2008
  • The frost heaving is related with thermal conduction rate and permeability. If the thermal conduction rate can be controlled, it is effective to prevent from frost heaving. If soil mixed with shredded tire which has relatively lower thermal conduction rate than soil, it helps preventing from frost heaving. However, in this case, the shear strength can get weak. In this study, we compared thermal conduction rate of soil and shredded tire, and test uniaxial compression strength of soil which is mixed with shredded tire and cement in different ratio.

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A Compilation and Evaluation of Thermal and Mechanical Properties of Bentonite-based Buffer Materials for a High- level Waste Repository

  • Cho, Won-Jin;Lee, Jae-Owan;Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.90-103
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    • 2002
  • The thermal and mechanical properties of compacted bentonite and bentonite-sand mixture were collected from the literatures and compiled. The thermal conductivity of bentonite is found to increase almost linearly with increasing dry density and water content of the bentonite. The specific heat can also be expressed as a function of water ontent, and the coefficient of thermal expansion is almost independent on the dry density. The logarithm of unconfined compressive strength and Young’s modulus of elasticity increase linearly with increasing dry density, and in the case of constant dry density, it can be fitted to a second order polynomial of water content. Also the unconfined compressive strength and Young’s modulus of elasticity of the bentonite-sand mixture decreases with increasing sand content. The Poisson’s ratio remains constant at the dry density higher than 1.6 Mg/m$_3$, and the shear strength increases with increasing dry density.

A Study on the Thermal Properties of CNT reinforced Semiconductive Shield Materials Used in Power Cables

  • Yang, Hoon;Bang, Jeong-Hwan;Chang, Hong-Soon;Nah, Chang-Woon;Park, Dae-Hee
    • Journal of Electrical Engineering and Technology
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    • v.3 no.1
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    • pp.115-120
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    • 2008
  • Use of the carbon nanotube is superior to general powder state materials of mechanical and electrical properties. Because its ratio of diameter and length (aspect ratio) is very large, it has been known as a type of ideal nano-reinforcement material. Based on this advantage, the existing carbon black of semiconductive shield materials used in power cables can acquire excellent properties by using a small amount of carbon nanotubes. Thus, we investigated the thermal properties of the carbon nanotube, such as thermal conductivity, specific heat, and DSC (Differential Scanning Calorimetry). We found that a high thermal resistance level is demonstrated by using a small amount of carbon nanotubes. As a result, this tendency confirms high cross-linking density in a new network in which the carbon nanotube between carbon black constitute molecules shows a bond by similar constructive properties.

Performance evaluation of natural fiber reinforced high volume fly ash foam concrete cladding

  • Raj, Amritha;Sathyan, Dhanya;Mini, K.M.
    • Advances in concrete construction
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    • v.11 no.2
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    • pp.151-161
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    • 2021
  • The major shortcoming of concrete in most of the applications is its high self-weight and thermal conductivity. The emerging trend to overcome these shortcomings is the use of foam-concrete, which is a lightweight concrete consisting of cement, filler, water and a foaming agent. This study aims at the development of a cost-effective high-volume fly-ash foam-concrete insulation wall cladding for existing buildings using natural fiber like rice straw in different proportions. The paper reports the results of systematic studies on various mechanical, acoustic, thermal and durability properties of foam-concrete with and without replacement of cement by fly-ash. Fly-ash replaces 60 percent by weight of cement in foam-concrete. The water-solid ratio of 0.3, the filler ratio of 1:1 by weight, and the density of 1100 kg/㎥ (approx.) are fixed for all the mixes. Rice straw at 1%, 3% and 5% by weight of cement was added to improve the thermal and acoustic efficiency. From the investigations, it was inferred that the strength properties were increased with fly-ash replacement up to 1% rice straw addition. In furtherance, addition of rice straw and fly-ash resulted in improved acoustic and thermal properties.

Thermal Conductivity of Carbon-Phenolic 8-Harness Satin Weave Composite (탄소/페놀릭 8-매 주자직 복합재료의 열전도도)

  • Woo, Kyeong-Sik;Goo, Nam-Seo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.9
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    • pp.18-25
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    • 2003
  • In this paper, thermal conductivities of carbon-phenolic 8-harness satin weave composite, ACP302, were measured and predicted. In the analysis, the satin weave unit cell was identified and modeled discretely by 3-dimensional finite elements, considering the interlaced fiber tow architecture microscopically. At the unit cell boundary, the corresponding periodic boundary conditions were applied. The results were analyzed to investigate the effect of microstructural parameters such as stacking phase shifts, waviness ratio, and fiber volume fraction. The conductivities were also obtained by experiments and compared with the numerical results.

Analysis of electrical, thermal characteristic of Nano/Micro Epoxy composite (나노/마이크로 에폭시 복합체의 전기적, 열적특성 분석)

  • Jung, Eui-Hwan;Yoon, Jae-Hun;Lim, Kee-Joe;Jeong, Su-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.99-99
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    • 2010
  • Polymer nanocomposite has been attracting much attention as a new insulation material, since homogeneous dispersion of nm-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy based nanocomposites were made and AC breakdown strength of Nano-TiO2 and micro-silica filler mixture of epoxy based composites were studied by sphere to sphere electrode. Moreover, nano- and micro-filler combinations were adopted as an approach toward practical application of nanocomposite insulation materials. Nano-TiO2 particle size is about 10nm and composites ratio was resin (100) : hardener (82) : accelerator (1.5). AC breakdown test was performed at room temperature (25 [$^{\circ}C$], 80 [$^{\circ}C$] and 100 [$^{\circ}C$] in the vicinity of Tg (90[$^{\circ}C$]). And thermal conductivity were measured by ASTM-D5470.

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Fabrication of Porous Al2O3 Ceramics Using Thermoplastic Polymer (열가소성 고분자를 이용한 다공질 알루미나의 제조)

  • 이상진;김해두
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.513-517
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    • 2004
  • Porous alumina ceramics with aligned plate-shaped pores were fabricated by using thermoplastic microsphere in order to show the anisotropy in thermal conductivity. The mixed powder of alumina and microsphere was pressed under 15 MPa till 20$0^{\circ}C$ to deform polymer into platelet-shape and sintered at 1,00$0^{\circ}C$ for 1 h. The sintered specimen with 10 wt% microsphere has 45.3% porosity and the bending strength of 44 MPa. The microstructural investigation confirmed the pore structure of platelet-shape, the thermal conductivities for vertical and parallel directions are 3.803 W/mK and 7.818 W/mK, respectively, the ratio between two directions exceeds 2.