• Title/Summary/Keyword: Th/Ts ratio

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Regeneration of TS-1 Catalyst During Phenol Hydroxylation(Calcination temperature dependence) (페놀의 수산화 반응에 사용한 TS-1 촉매의 효과적인 재생 방법(소성 온도 의존성))

  • Kwon, Song Yi;Yoon, Songhun;Um, Kyung Sub;Lee, Jae Wook;Lee, Chul Wee
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.679-683
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    • 2010
  • In this study, calcination temperature dependence of TS-1 catalyst was investigated in the hydroxylation of phenol with hydrogen peroxide during the regeneration of catalyst. Catalyst was regenerated 5 times by calcining at $550^{\circ}C$ and $700^{\circ}C$, respectively. When the catalyst was regenerated at $550^{\circ}C$ after 5th regeneration phenol conversion was decreased from 22.9% to 15.1% and at $700^{\circ}C$ after 5th regeneration phenol conversion was decreased from 22.9% to 18.8%. For formation ratio of catechol/hydroquinone was increased from 1.28 to 1.45 after 5th regeneration at $550^{\circ}C$, and from 1.28 to 1.20 after 5th regeneration at $700^{\circ}C$. The main reasons for deactivation of the catalyst were suggested by analyzing chemical/physical properties with XRD, UV-vis spectra, $N_2$ adsorption/desorption and TGA, and evaluating the catalytic activity such as phenol conversion and product selectivity.

Relationship Among Growth Characteristics , Quality, and Chemical Components in Flue-cured Tobacco (황색종 담배에서 생육형질, 품질 및 화학성분과의 관계)

  • Jeong, Ki-Taeg;Ban, You-Seon;Lee, Jeong-Duk
    • Journal of the Korean Society of Tobacco Science
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    • v.10 no.1
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    • pp.11-19
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    • 1988
  • This study was conducted to relate among growth characteristics, quality, and chemical components for flue-cored tobacco. The results are summarized as follows : 1. Starch content in harvested green leaf was correlated negatively with leaf length, leaf width, leaf area, and leaf weight of harvested green leaf, respectively, while positively with total sugar content in cured leaf, and the ratio of leaf length to leaf width of harvested green leaf. 2. Organic matter and total nitrogen contents in the soil were correlated positively with nicotine content in cured leaf, respectively, and total nitrogen in the soil negatively with total sugar content in cured leaf. 3, Amount of fertilizer, application date of MH, priod of harvesting, and yield were correlated positively with nicotine content in cured leaf, respectively , while negatively with total sugar content. Application amount of MH was correlated positively with total sugar content, but negatively with nicotine content in cured leaf. Also amount of compost was correlated negatively with nicotine content in cured leaf. 4. The ratio of total sugar to nicotine (TS/N) per plant was correlated positively with price (Won/kg) and specific leaf area, but negatively with leaf length. leaf width, leaf area, harvested leaves, and leaf weight in cured leaves, respectively. Yield was correlated negatively with TS/N per plant. 5. TS/N of the best quality tobacco per plant was 12.0. Those of the best quality tobacco in each stalk position were 42.1 for first~third leaf, 28.4 for 4th~6th leaf , 23.7 for 7th~9th leaf, 7.7 for l0th~12th leaf , and 7.8 for over 13th leaf from bottom, respectively. 6, When TS/N was 12.0, optimum values of growth characteristics per plant were 100.5 $\pm$ 10.3g for leaf dry weight, 755.1$\pm$53.2cm for leaf length, 294.4$\pm$25.1cm for leaf width, 8, 892$\pm$111cm2 for leaf area, 16.0$\pm$0.6 leaves for harvested leaves, and 7.32$\pm$0.44mg/cm2 for specific leaf area, respectively. 7. When TS/N was 12.0, optimum values of chemical components per plant were 1.92$\pm$0.28% for nicotine content, and 20.4$\pm$ 1.4 % for total sugar content, and that of yield was 238.3$\pm$ 9.8kg/10a.

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Association of Pre- and Perinatal Risk Factors With Tourette Syndrome or Chronic Tic Disorders in a Korean School-Age Population

  • Wooseok Choi;Soon-beom Hong;Johanna Inhynag Kim;Jung Lee;Soomin Jang;Yebin D Ahn;You Bin Lim;Sumin Kim;Mee Rim Oh;Bung-Nyun Kim
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.34 no.1
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    • pp.37-44
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    • 2023
  • Objectives: Tic disorders are highly heritable; however, growing evidence suggests that environmental factors play a significant role in their pathogenesis. Studies on these factors have been inconsistent, with conflicting results. Therefore, this study aimed to examine the associations of pre- and perinatal exposure to Tourette syndrome (TS) or chronic tic disorders (CTD) in Korean school-aged children. Methods: This case-control study used data from a large prospective cohort study. The primary outcome was TS/CTD diagnosis according to the Diagnostic and Statistical Manual of Mental Disorders, 5th edition (DSM-5) criteria and Kiddie-Schedule for Affective Disorders and Schizophrenia-Present and Lifetime Version-Korean Version. Demographic, pre-, and perinatal information was obtained from the maternal questionnaires. Data between the TS/CTD and control groups were compared using the chi-squared or Student's t-test, as appropriate. Two-step logistic regression analyses were used to test the association between TS/CTD and pre- and perinatal risk factors. Results: We included of 223 children (78 with TS/CTD and 145 controls). Significant differences in the demographic data between the two groups were observed. The male sex ratio, mean parental age, parental final education level, and family history of tics were included as confounders. In the final adjusted multivariable model, TS/CTD was significantly associated with antiemetic exposure during pregnancy (odds ratio [OR]=16.61, 95% confidence interval [CI] 1.49-185.22, p=0.02) and medically assisted reproduction (OR=7.89, 95% CI 2.28-27.28, p=0.01). Conclusion: Antiemetic exposure and medically assisted reproduction are significantly associated with the risk of TS/CTD. These results should be replicated in future prospective and gene-by-environment studies.

Ethylbenzene Separation from Ethylbenzene/p-xylene Mixture with MFI-type Zeolite Membranes (MFI형 제올라이트 분리막을 이용한 에틸벤젠/파라자일렌 분리에 대한 연구)

  • Lee, Gi-Cheon;Jeon, Yukwon;Chu, Young Hwan;Choi, Seonghwan;Seo, Young-Jong;Shul, Yong-Gun
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.476-481
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    • 2013
  • Ethylbenzene (EB) which has a similar physical properties with p-xylene (pX) was separated from EB/pX mixture by using MFI-type zeolite (TS-1, ZSM-5, and Silicalite-1) coated membranes. The zeolites were synthesized by microwave method to reduce the synthesis time and uniformly formed zeolite particles were coated on the ${\alpha}$-almina tubular support with a thickness of $3-4{\mu}m$. Separation factor and permeation flux of the synthesized zeolite coated membranes were measured to survey the best performance of ethylbenzene separation from different composition of EB/pX mixtures. When the EB/pX mixture of 5:5 molar ratio applied for the separation experiment, it represented the highest separation factor. We also have studied about the effect of the atomic composition of zeolites on the separation performance within the temperature range from 160 to $220^{\circ}C$. TS-1 showed the highest permeation flux of $1,666mol/m^{2*}s^*Pa$ and Silicate-1 showed the highest separation factor of 1.73 at $200^{\circ}C$ respectively.

Effect of pH on the $VFA_s$ fermentation in the anaerobic treatment of food waste (pH조절이 음식폐기물의 유기산발효에 미치는 영향)

  • 조한진;성낙창;김은호;장성호;손영일;박진식
    • Journal of environmental and Sanitary engineering
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    • v.16 no.2
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    • pp.32-37
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    • 2001
  • The purpose of this study was to investigate the created liquid post-acid fermentation of usability of denitrification as exterior carbon sources by pH control. The time of acid fermentation of food waste, the slower loading capacity of organic matter, the faster decomposition rate, but the density of generation Volatile Fermentation Acids(VFAs), was weak and, $SBOD_{5}$ : ST-N rate and $SBOD_{5}/SCOD_{Cr}$ rate was low. Between TS and VS, VS was decreased to 4.5th day fast, and then was decreased slowly. 1.5 days after stating the experiments, $SCOD_{Cr}$, $SBOD_{5}$, STOC and $VFA_{s}$ was decreased of increased slowly, and then increased fast. And after showing the highest density, it was tended to decreased fast. At the time of $SBOD_{5}$ with the highest density, at $SBOD_{5}$ : ST-N ratio, $R_1$ was 303:1, $R_2$ was 319:1, $R_3$was the highest. After studying $SBOD_{5}$ : ST-N ratio and $SBOD_{5}/SCOD_{Cr}$ ratio, as a carbon source of biological denitrification it was profitable composition ratio.

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The effect of regular exercise on immune response and hormone (규칙적인 운동이 면역반응 및 호르몬에 미치는 영향)

  • Park, Sang Kyu
    • The Korean Journal of Emergency Medical Services
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    • v.5 no.1
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    • pp.15-22
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    • 2001
  • This study has measured the pulmonary function by treadmill test for 6 young women who were in twenties, and analyzed the respiratory-circulatory function and the change of hormone and immune response after performing the exercise program (60% severity) for 10 weeks. The results are as follows; 1. 10 weeks regular exercise made a decrease in weight and body fat proportion, and improved the respiratory-circular function by increasing the maximum oxygen absorption and ventilation. 2. 10 weeks regular exercise made a significant increase in count of WBC, lymphocyte, and T lymphocyte, but a significant decrease in B lymphocyte. NK cell also showed an increase in counts, but insignificant. 3. 10 weeks regular exercise made a significant increase in blood norepinephrine level. Epinephrine and cortisol also showed an increase in count, but insignificant. In summary, it suggested that 10 weeks regular exercise improves the immune function by decrease in body fat, increase in respiratory-circular function and metabolic efficiency, and also by raising Th/Ts ratio (an increase in count of WBC, lymphocyte, and T lymphocyte, but a decrease in suppressor T lymphocyte).

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Effects of Laughter Therapy on Depression, Quality of Life, Resilience and Immune Responses in Breast Cancer Survivors (웃음요법이 유방암 생존자의 우울, 삶의 질, 극복력, 면역반응에 미치는 효과)

  • Cho, Eun-A;Oh, Hyun-Ei
    • Journal of Korean Academy of Nursing
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    • v.41 no.3
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    • pp.285-293
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    • 2011
  • Purpose: In this study, the effects of laughter therapy on levels of depression, quality of life, resilience and immune responses in breast cancer survivors were examined. Methods: A quasi-experimental nonequivalent control group, pretest-posttest design was used. Participants (n=37) included breast cancer survivors who finished chemotheraphy and radiation therapy: 16 in the experiment group and 21 in the control group. Data were collected from August to November 2009. The experimental group participated in laughter therapy eight times, twice a week for 60 min per session. Questionnaires were used to me-asure pretest and posttest levels of depression, quality of life and resilience. A blood test was used to analyze changes in Total T cell, T helper, T suppressor, Th/Ts ratio, Total B cell, T cell/B cell ratio and NK cell for immune responses. Results: The results showed that laughter therapy was effective in increasing the quality of life and resilience in breast cancer survivors. but depression and immune responses did not differ significantly between the groups. Conclusion: The results of the study indicate that laughter therapy may be an effective nursing intervention to improve quality of life and resilience in breast cancer survivors.

A study on correlations between tongue with skeletal pattern and intermaxillary space in Class II malocclusion adult patients (골격성 II급 성인 부정교합자에서 혀와 두개안면골격 및 악간공간과의 상관관계에 관한 연구)

  • Kang, Hyun-Hee;Park, Soo-Byung
    • The korean journal of orthodontics
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    • v.29 no.5 s.76
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    • pp.575-587
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    • 1999
  • This study was designed to evaluate the correlations between tongue with skeletal pattern and intermaxillary space in Class II malocclusion adult patients. Craniofacial skeletal pattern was analyzed on the lateral cephalometric radiograph and the subjects were devided two groups by facial ratio, the 30 subjects of hyperdivergent group and the 30 subjects of hypodivergent group. The size and posture of tongue and intermaxillary space were measured on the lateral cephalometric radiograph. These data were statistically analyzed to examine significant differences between both groups and compared the correlation between tongue with skeletal measurements and intermaxillary space in each group. The results of this study were as follows. 1. In comparison of the tongue and intermaxillary space, the measurement of TS/IS showed significantly larger in hyperdivergent group and PIH and IS showed significantly larger in hypodivergent group. There were no statistically significant differences in the measurements of the height and posture of tongue. 2. In correlation between tongue with craniofacial skeletal measurements, the length and height of tongue showed the highest correlation with AFH(anterior facial height) in both groups(p<0.01). And that measurements showed high correlation with PFH(posterior facial height) in hypodivergent group. 3. In both groups, most measurements of tongue showed high correlation with intermaxillary space and the height and space of tongue showed high correlation with AIH and PIH(p<0.01).

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Deformational Characteristics of Cohesive Soils Using Resonant Column / Torsional Shear Testing Equipment (공진주/비틂 전단(RC/TS)시험기를 이용한 점성토의 변형특성)

  • 김동수
    • Geotechnical Engineering
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    • v.11 no.1
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    • pp.113-126
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    • 1995
  • Both resonant column (RC) and torsional shear(TS) tests were performed at small to intermediate strain levels to investigate deformational characteristics of cohesive soils. The effects of variables such as strain amplitude, loading frequency, and number of loading cycles were studied. Plasticity index was found to be an important variables in evaluating these effects. Soils tested include undisturbed silts and clays and compacted subgrade soils. At small strains below the elastic threshold, shear modulus is independent of number of loading cycles and strain amplitude. Small strain material damping exists wi th ranges be tween 1.1% and 1.7% for 75 tests. The elastic threshold strain increases as confining pressure and plasticity index increases. Above the cyclic threshold strain, the modulus of cohesive soil decreases with increasing number of cycles while damping ratio is almost independent of number of load cycles. Moduli and damping ratios of cohesive soils obtanined by RC test are higher than those from 75 test because of the frequency effect. Shear modulus of cohesive soil increases linearly as a function of the logarithm of loading frequency.

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Deduction of Optimum Factors for Hydrogen Production from Organic Resources using a Continuous Reaction Process (연속반응공정을 이용한 유기성자원으로부터 수소생산을 위한 최적인자도출에 관한 연구)

  • Kim, Choong Gon;Shin, Hyun Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.2
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    • pp.22-27
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    • 2011
  • This study was performed to find out the optimum condition for hydrogen production by changing mixture ratio from 3:7(food waste water : swine wastewater) without pre-treatment of food wastewater and swine wastewater using a continuous reaction process. It was confirmed that hydrogen generation according to pH is the highest in a condition of pH 5.5, and that the optimum pH for hydrogen production in case of mixing food wastewater with swine wastewater is 5.5 through this. Hydrogen generation according to HRT showed high hydrogen generation rate in case of 4 days rather than 3 days, and this involves largely in vitality of hydrogen producing bacteria according to variation of the HRT value, so it is judged that HRT also acts as an important factor to hydrogen producing bacteria. The organic removal efficiency recorded a removal efficiency of maximum TS 52%, VS 71%, TSS 83% and VSS 89% at the 6th day of operation, and it was confirmed that organic removal efficiency is possible even through an hydrogen production process.