• Bulletin of the Korean Chemical Society
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• v.32 no.11
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• pp.3865-3872
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• 2011

A quantitative structure-property relationship (QSPR) study was performed for the prediction of the absorption maxima of azobenzene dyes. The entire set of 191 azobenzenes was divided into a training set of 150 azobenzenes and a test set of 41 azobenzenes according to Kennard and Stones algorithm. A seven-descriptor model, with squared correlation coefficient ($R^2$) of 0.8755 and standard error of estimation (s) of 14.476, was developed by applying stepwise multiple linear regression (MLR) analysis on the training set. The reliability of the proposed model was further illustrated using various evaluation techniques: leave-many-out crossvalidation procedure, randomization tests, and validation through the test set.

• Fibers and Polymers
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• v.5 no.2
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• pp.134-138
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• 2004

Dyeing properties of a series of 4-amino-4'-fluorosulfonylazobenzene disperse dyes on poly(ethylene terephthalate) (PET) were investigated. Build-up properties and color properties on PET were examined. In particular, the 4-aminoazobenzene dyes containing a nitro group instead of a fluorosulfonyl group at 4'-position were also synthesized in order to compare their dyeing properties on PET with that of 4'-fluorosulfonyl analogues.

• Journal of Fashion Business
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• v.14 no.3
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• pp.116-127
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• 2010

Metal acid dyes are usually used to dye wool fabric to achieve high concentrated color and strong color fastness. However, metal acid dyes contain lots of heavy metal. That causes not only environmental pollution but also diseases to human. In this study, wool reactive dyes instead of metal acid dyes for wool, which are environmental friendly, are compared and analyzed in the evaluation system of their harmfulness, containing heavy metals and examined exhaustion rates and dyeing characteristics.

• Textile Coloration and Finishing
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• v.18 no.5 s.90
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• pp.15-21
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• 2006

Temporarily solubilized azo disperse dyes containing ${\beta}$-sulfatoethylsufonyl group were applied to acetate fabric and the feasibility of dispersant-free dyeing was investigated. The color yields of the dyes on acetate fabric were found to be dependent on dye bath pH as well as dyeing temperature. The optimum results were obtained at pH 6 and $80^{\circ}C$. The dyes showed good exhaustion and levelling properties. Vinylsulfone derivatives of the dyes were prepared and applied to acetate with dispersant. Dyeing properties of the temporarily solubilized disperse dyes were similar to or better than those of the vinylsulfone dyes. The dyes showed moderate to good fastness properties on acetate.

• Fibers and Polymers
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• v.3 no.4
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• pp.140-146
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• 2002

Non-genotoxic diamines 2,2'-dimethyl-5,5'-dipropoxybenzidine and 5,5'-dipropoxy-benzidine were employed as potential alternatives to benzidine in the synthesis and evaluation of new direct dyes for cotton. Assessment of the resultant dyes indicated that both diamines can be used to prepare new direct dyes having colors and fastness properties that make them comparable to commercial direct dyes, and that the structures of the new direct dyes can be confirmed by negative ion electrospray mass spectrometry (ESMS). The mutagenic properties of new direct dyes were established using the standard Ames Salmonella mammalian mutagenicity assay.

• Textile Coloration and Finishing
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• v.32 no.4
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• pp.255-264
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• 2020

With the development of synthetic dyes, excellent dyeing properties and massive production became possible. On the other hand, natural dyeing technology has gradually disappeared. However, the international environmental and human safety requirements of the apparel and textile industry are increasing, and there is a growing interest in safer and more environmentally friendly products. Accordingly, the public's interest in natural dyeing is increasing. To meet these demands, it is first necessary to clarify the stages of production and distribution of natural dyes. It is necessary to evaluate whether the product is a natural dye product and study the suitability of the natural dye product through qualitative and quantitative assessment of the indicator components of the natural dye. Typical of three natural dyes did qualitative and quantitative analysis by HPLC-DAD and HPLC-MS. Products dyed using natural dye three products were analyzed, and the presence or absence of detection of each indicator components was confirmed to confirm whether the product was dyed using natural dyes.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2394-2402
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• 2018

Textile dyes are some of the pollutants which have received the most attention because of the large volume of wastewater generated by the textile industry. Removal by means of adsorption is one of the most versatile alternatives to treat these effluents. Even though different adsorbents such as activated carbons and mineral materials have been proposed, polymeric adsorbents are a viable alternative. This work reports for the first time the use of polyelectrolyte PTZ and macroelectrolyte MTZ containing tetrazole groups as adsorbents useful in the textile dyes removal present in aqueous solutions and wastewater. Because of the anionic character of the tetrazole group, MTZ exhibits selective adsorption capabilities for cationic dyes of up to $156.25mg{\cdot}g^{-1}$. The kinetic study of the process of adsorption shows that PTZ and MTZ fit a pseudo second-order model. MTZ also shows utility as a flocculant agent in the treatment of wastewater containing dyes Indigo Blue and Reactive Black. The results showed that PTZ and MTZ may be used in the treatment of wastewater in a process of coagulation-flocculation followed by the treatment by adsorption. This two-stage treatment removed up to 95% of the dye present in the wastewater. As well as removing the dyes, the values for COD, suspended solids, pH, and color of the wastewater decreased, thus significantly improving its quality.

• Textile Coloration and Finishing
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• v.3 no.2
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• pp.16-24
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• 1991

The textile fabric have the functions of sanitation, decoration, wearing style and washing in the practical use. Among various texitle fiber, silk has less utilities than synthetic fiber in practical use although silk has good benefits of the high quality. Thus no textile fiber, neither natural nor synthetic, has all the functions. In this sence, many blend yarns have been improved various functions of fabric. However, this has been disturbed with the problem of dyeing, especially in the case of blend fabric of silk. In this study, we dyed silk/PET blend fabric in one step useing one bath dyeing method by acid dyes/disperse dyes. The results of the experiments can be summarized as follows; 1) Yellow index of silk fabric treated at $130^{\circ}C$ increased about 7.8 (color difference 4.5 NBS) and whiteness decrease about 5%. 2) Both elongation and tensile strength of silk fabric treated at $130^{\circ}C$ of pH 5-6 decreased about 10% and tensile strength of silk spun yarn treated at $60^{\circ}C$ of pH 10 have little changed. 3) While silk/PET blend frbric dyeing, silk soiling of disperse dyes causes from difference of dyeing rate and degree of silk soiling with dyes. 4) Fastness and soiling of silk/PET blend fabric dyed by one bath dyeing method of acid dyes/disperse dyes was same as two bath dyeing method.

• Textile Coloration and Finishing
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• v.33 no.4
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• pp.202-209
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• 2021

Natural dyes are more expensive than synthetic dyes and the dyeing process, which is mainly immersion of dye, is complicated. For this reason, relatively small-scale production methods were predominant. However, awareness and interest in environmental sustainability is rising globally, and the use of synthetic dyes causes various environmental problems such as wastewater and CO₂ emission, so the consumption of natural dyes is increasing. In addition, interest in digital textile printing, an eco-friendly dyeing method that can produce products of various designs and uses less water, is growing. In this study, natural indigo dye (Indigofera tinctoria) was used as a raw material for Digital Textile Printing ink, and ¹⁴C (Biocarbon) present in it was measured to confirm whether it was derived from natural ingredients. The performance was confirmed by testing the pH, viscosity, electrical conductivity, surface tension, and particle size analysis of natural indigo ink. In addition, the performance of natural indigo DTP ink and printing fabric was evaluated by inspecting the change in color fastness and corresponding index substances before and after digital printing with natural indigo DTP ink on textiles. Through this, the possibility of commercialization of DTP ink and printing fabric using natural indigo was confirmed.

• Textile Coloration and Finishing
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• v.15 no.5
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• pp.340-347
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• 2003

Present situation of Korean textile products regarding European eco-label criteria was assessed by analyzing harmful substances including pH, PCP & TeCP, formaldehyde, heavy metals, cleavable arylamines, allergenic dyes, pesticides, organic carriers, TBT as well as color fastness as the minimum quality requirement. Fabric specimens were submitted from six typical textile companies for product eco-testing. In six product groups selected, arylamines, allergenic dyes, halogenated organic carriers and color fastness were found to be parameters that failed to meet the criteria. Source elucidation of harmful substances were presented with their instrumental analysis results.