• 제목/요약/키워드: Tetraphenylethylene

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Co-deposition and Tuned Blue Emission Color from New Tetraphenylethylene Derivatives

  • Kim, Soo-Kang;Park, Jong-Wook
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.526-529
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    • 2008
  • By combining tetraphenylethylene and anthracene, we synthesized 9,10-bis(4-(1,2,2-triphenylvinyl)phenyl) anthracene [BTPPA] and 1,2-di(4'-tert-butylphenyl)-1,2-bis(4'-(anthracene-9-yl)phenyl)ethene [BPBAPE]; both BTPPA and BPBAPE have similar band-gaps, however their PL spectra were shifted by about 30 nm with respect to each other. The fabricated multilayered non-doped OLED devices based on pure BTPPA or BPBAPE exhibited luminance efficiencies of 3.93 cd/A at 6.8 V and 10.33 cd/A at 8.1 V, respectively, at $10\;mA/cm^2$. As the BPBAPE content of the emitting layer increased, the luminance efficiency of the device increased; in addition, the CIE coordinates of the fabricated devices shifted gradually from deep-blue for pure BTPPA to sky-blue for pure BPBAPE.

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Aggregation-Induced Emission (AIE) 기반의 Turn-On 형광센서를 이용한 수질 속 중금속 납 이온의 효율적인 검출 (Efficient Detection of Heavy Metal Lead Ions in Aqueous Media using Aggregation-Induced Emission (AIE)-based Turn-on Fluorescence Sensor)

  • 최해민;성현정;차주연;이성호
    • 한국환경과학회지
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    • 제32권11호
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    • pp.757-765
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    • 2023
  • Lead, a heavy metal widely employed in various industries, continues to pose a threat to both human health and the environment. Therefore, the development of a sensor capable of rapidly and accurately detecting lead(II) ions in real-time at contaminated sites is crucial. In this study, we have engineered a fluorescent sensor with the ability to efficiently detect lead(II) ions under actual environmental conditions, including tap water and freshwater. The compound, tetraphenylethylene carboxylic acid derivative (TPE-COOH), exhibits high selectivity and sensitivity toward lead(II) ions in aqueous solution, where the interaction between TPE-COOH and lead(II) ions leads to its aggregation, thus triggering a fluorescence "turn-on" based on the aggregation-induced emission (AIE) mechanism. Impressively, compound TPE-COOH proficiently detects lead(II) ions within a range of 30 to 100 𝜇M in tap water and freshwater, even in the presence of various interfering substances.