• The Korean Journal of Ceramics
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• v.7 no.1
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• pp.30-35
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• 2001

The contribution of the non-$180^{\circ}C$ domains to the electric-field-induced strains (EFI-strains) of PZT ceramics was evaluated by an XRD method and by an interferometric method. The XRD intensity ratio of 200 and 002 diffraction peaks of tetragonal PZT was measured under strong electric fields. The amount of the $90^{\circ}$ domain reorientation was evaluated and the strain due to the domain reorientation was calculated. It was confirmed that the EFI-strain of PZT ceramics was equal to the sum of the strain calculated from the d$_33$ constant determined by the resonance-antiresonance method and the strain due to the $90^{\circ}$ domain reorientation. The amount of the $90^{\circ}$domain reorientation has a linear relation with the c/a ratio in the "soft" PZT ceramics. A Mech-Zehnder interferometer was constructed to measure the EFI-strains vs. electric-field curves of PZT ceramics as a function of frequency. The EFI-strain vs. electric-field curve showed a hysteresis due to the effect of the non-$180^{\circ}$ domain reorientation when the applied voltage was high and its frequency was low. The apparent piezoelectric constant increased from the d$_33$ value determined by the resonance-antiresonance method with decreasing frequency. This deviation was attributed to the non-$180^{\circ}$ domain contribution.tribution.