• Title/Summary/Keyword: Ternary composition

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Magnetic Properties of (Co-Cr)-P-Ni Alloy Thin Film ((Co-Cr)-P-Ni 합금 박막의 자기적 특성)

  • 박창민;신경호;손홍균;이택동
    • Journal of the Korean Magnetics Society
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    • v.5 no.2
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    • pp.134-139
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    • 1995
  • We produced $(Co_{93}Cr_{7})-P-Ni$ thin films for longitudinal magnetic recording media using OC magnetron sputtering system The variation of magnetic properties of $(Co_{93}Cr_{7})-P-Ni$ pseudo-ternary system with the composition was examined. We obtained the coercivity up to 1500 Oe. The coercivity iocrease could be ascribed to in-plane anisotropy enhaocement, grain size decrease, magnetic decoupling between particles. TEM micrographs showed that the grains were well-decoupled by the addition of phosphorous.

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Microstructure and Electrical Properties of Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 Ceramics Modified with Yttria (Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3계에 Yttria 첨가시 미세구조와 전기적 물성변화에 관한 연구)

  • 김창삼;이응상
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.263-269
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    • 1987
  • It is investigated that the determination of the correlation between the change of microstructure and electrical properties. Yttria is added to the compositiojn of rhombohedral region in Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 ternary system. Average grian size, lattice parameters and distribution of yttrium are characterized by XRD, SEM and EDS. Electrical properties are determined by measurement of Curie temperature, piezoelectric properties and hysteresis loops. The results are as follows; 1. Both lattice parameters, a and ${\alpha}$, are changed by addition of yttria to the composition of rhomboheadral region in Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 ternary system and Curie temperature is proportional to the values at (90-${\alpha}$).

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Preparation and Evaluation of Novel Fenofibrate-loaded Self-Microemulsifying Drug Delivery System (SMEDDS)

  • Cho, Young-Dae;Park, Young-Joon
    • Journal of Pharmaceutical Investigation
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    • v.40 no.6
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    • pp.339-345
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    • 2010
  • Fenofibrate has been used for many years to lower cholesterol levels and its pharmacokinetic profile is well understood. However, due to its low solubility in water, it has low bioavailability after oral administration. In order to improve the dissolution rate, fenofibrate was formulated into a self-microemulsifying drug delivery systems (SMEDDS). We used pseudo-ternary phase diagrams to evaluate the area of microemulsification, and an in vitro dissolution test was used to investigate the dissolution rate of fenofibrate. The optimized formulation for in vitro dissolution assessment consisted of Lauroglycol FCC (60%), Solutol HS 15 (27%), and Transcutol-P (13%). The mean droplet size of the oil phase in the microemulsion formed from the SMEDDS was about 130 nm. The dissolution rate of fenofibrate from SMEDDS was significantly higher than that of the reference tablet. Our studies suggested that the fenofibrate containing SMEDDS composition can effectively increase the solubility and oral bioavailability of poorly water-soluble drugs.

THERMALLY INDUCED PHASE SEPARATION IN TERNARY POLYMER SOLUTION

  • Jung, Bum-Suk;Kang, Yong-Soo;Jones, Richard-A.L.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.79-82
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    • 1999
  • Using Small Angle Light Scattering (SALS), the effect of quench depth on the kinetics of phase separation for ternary solution blends was investigated. The system was composed of two polymers (polystyrene and polybutadiene) and a solvent (toluene). The analyses of the early stage of phase separation were based of the Cahn-Hilliard theory [1,5]. Apparent diffusion coefficients and the fastest mode of fluctuations were evaluated, when quench depth of the system were varied near the critical composition of polymer. In the late stage of phase separation, the domain growth showed a power law with the 1/3 exponent, i.e. $q_m(t)~t^{-1/3}$. For comparison between real images and scattering profiles with time, the image of phase domains with time were obtained by using Laser Confocal Scanning Microscopy (LSCM).

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Structural Analysis of Simulated Fission-Produced Noble Metal Alloys and Their Superconductivities

  • Park, Yong Jun;Lee, Gwang Yong;Lee, Jong Gyu;Heo, Yong Deuk;Kim, Won Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.12
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    • pp.1187-1192
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    • 2000
  • Ternary (Mo-Ru-Pd) and binary (Mo-Ru, Mo-Pd) alloys have been prepared using an Ar arc melting furnace. Mo and the noble metals, Ru and Pd, are the constituents of metallic insoluble residues, which were found in the early days of post-irradiation studies on uranium oxide fuels. In the present study, the structure of the alloys was evaluated using a powder X-ray diffractometer. Unit cell parameters were determined by least squares refinements of powder X-ray diffraction data. Scanning electron microscopic analyses of the surface of the alloys indicated that surface morphology was dependent on the crystallographic structure as well as its composition. Measurements of the magnetic susceptibility of the alloys showed evidence of superconducting transition from 3 to 9.2 K. Among the ternary and binary alloys, the ${\sigma}-phase$ showed the highest superconducting transition temperature,~9.2 K.

A Study on the MESG of Flammable Ternary Gas Mixtures (3성분계 인화성 혼합가스의 MESG에 관한 연구)

  • Hwang, Kyungyong;Byeon, Junghwan;Rhee, Kyunam;Lee, Taeck-Kie
    • Journal of the Korean Institute of Gas
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    • v.20 no.3
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    • pp.30-37
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    • 2016
  • Electrical apparatuses for use in the presence of flammable gas atmospheres have to be specially designed to prevent them from igniting the explosive gas. Flameproof design implies that electrical components producing electrical sparks are contained in enclosures and withstand the maximum pressure of internal gas or vapours. In addition, any gaps in the enclosure wall have to designed in such a way that they will not transmit a gas explosion inside the enclosure to an explosive gas or vapours atmosphere outside it. In this study, we explained some of the most important physical mechanism of MESG(Maximum Experimental Safe Gap) that the jet of combustion products ejected through the flame gap to the external surroundings do not have an energy and temperature large enough to initiate an ignition of external gas or vapours. We measured the MESG and maximum explosion pressure of ternary gas mixtures(propane-acetylene-air) by the test method and procedure of IEC 60079-20-1:2010. As a result, the composition of propane gas that has lower explosive power than acetylene gas in the ternary gas mixtures makes greater effects on MESG and explosion pressure.

Retention Behavior of the Phenols on the Binary and Ternary Mobile Phases in Reversed-Phase Liquid Chromatography (역상 액체크로마토그래피에 있어서 이성분과 삼성분 이동상에 대한 페놀류의 머무름 거동)

  • Dae Sub Oh;Sun Haing Lee;Soo Han Kim;Sang Tae Kim
    • Journal of the Korean Chemical Society
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    • v.30 no.4
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    • pp.352-358
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    • 1986
  • An extensive experimental survey on the retention behaviors of phenols in the binary solvent system such as methanol-water, acetonitrile-water and tetrahydrofuran-water as well as the ternary solvent system such as methanol-acetonitrile-water and methanol-tetrahydrofuran-water is presented. A linear equation, which describes the capacity factor as a function of the solvent composition in the mobile phase and is able to predict the retention behaviors of phenols, was obtained. The iso-eluotropic lines for the binary and ternary solvent system are based on the equal strength of the methanol-water solvent which shows an optimum separation of the phenols used. The specific effect of each solute in the binary solvent system appeared to be larger than those in the ternary system.

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Phase Equilibrium Study on the Ternary System of SBR/EPDM/Solvent (SBR, EPDM 및 Solvent로 이루어진 삼성분계의 상 평형에 관한 연구)

  • Go, Jin-Hwan;Park, Byung-Ho
    • Elastomers and Composites
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    • v.37 no.4
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    • pp.211-216
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    • 2002
  • The polymer-polymer interaction parameter, x 23t, of the styrene-butadiene polymer (SBR) and ethylene-propylene-diene terpolymer (EPDM) was investigated by observing the phase behavior of the ternary system of SBR/EPDM/solvent. The solvent used in this study was benzene acting as a good solvent for SBR but as a poor solvent for EPDM. Ternary solutions with various concentrations and mixing ratios of the two component polymers were separated into two phases by temperature change The cloud point curves (CPC) showed that the differerence of solvent affinities toward each polymer and the repulsive interaction between two polymers considerably affect the shape of CPC near 15℃. In the temperature range of 5℃ ~ 25℃, incompatible behaviours arised from both the difference of mixing ratios and concentration were clearly observed. Also the phase separation temperature greatly influenced on the composition of each separated phase. The calculated x 23t values from Flory-Huggins theory were in the range of 0.6301 ~ 1.0775, which suggest that the SBR/EPDM systems are incompatible.

A simplified phase diagram in the ternary system $Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ ($Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ 삼성분계 상태도)

  • 이득용;김대준;장주웅;이명현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.377-383
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    • 1997
  • Yttria-stabilized TZP alloyed with pentavalent oxides $(Ta_2O_5,\;Nb_2O_5)$ were fabricated by the conventional sintering method at $1500^{\circ}C$ in air to construct the simplified ternary phase diagram. The phase stability of tetragonal -$ZrO_2$ from the quasi-binary system $ZrO_2-YTa(Nb)O_4$, which do not transform to monoclinic-$ZrO_2$ even for a wide range of grain size and annealing temperature, was investigated to determine composition region of the non-transformable $t-ZrO_2$ solid solution$(NT_{ss})$. Phase stability of $NT_{ss}$ was probably due to the enhanced stability of $_YTa(Nb)O4$ having the tetragonal fergusonite structure. It was experimentally found that mixtures having $NT_{ss}$ alloyed with $T_{ss}$ by weight%% showed both excellent phase stability of $t-ZrO_2$ and fracture toughness even though the calculated composition of the mixture /was located outside $NT_{ss}$ composition region.

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Spectrophotometric Determination of Scandium(III) with Eriochrome Cyanine R in the Presence of Cetyltrimethylammonium bromide (Cetyltrimethylammonium bromide에서 Eriochrome Cyanine R에 의한 스칸듐(III)의 분광광도법 정량)

  • Cha, Ki-Won;Park, Chan-Il;Kim, Jong-Whon
    • Analytical Science and Technology
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    • v.9 no.2
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    • pp.139-144
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    • 1996
  • The spectrophotometric determination method of scandium with eriochrome cyanine R(ECR) and the composition ratio of the complex were investigated in the presence of surfactants. The absorbance increase and red shift of maximum adsorption wavelength of Sc(III)-ECR complex were observed in cetyltrimethylammonium bromide (CTMAB), but those changes were not observed in the sodium dodecyl sulfate(SDS) and Triton X-100. A volume of 5ml of $1{\times}10^{-3}M$ ECR and 10ml of $2{\times}10^{-4}M$ CTMAB are necessary for the determination of $1{\times}10^{-7}{\sim}3.0{\times}10^{-6}M$ Sc(III) at pH 6.5. The apparent molar absorption coefficient of the Sc(III)-ECR-CTMAB, temary complex at 610nm is $5.6{\times}10^5mol^{-1}cm^{-1}L$ and its detection limit is $1.0{\times}10^{-7}M$. The binary complex composition of Sc(III)-ECR is 1:2 and the ternary complex composition of Sc(III)-ECR-CTMAB is 1:3:1.

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