• Title/Summary/Keyword: Ternary composition

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Thermodynamic Study of Liquid Pb-Bi, Pb-Na, Bi-Na Binaries and Pb-Bi-Na Ternary Solutions (熔融 Pb-Bi, Pb-Na, Bi-Na 및 Pb-Bi-Na 系의 物理化學的硏究)

  • Koh, Chang-Shik
    • Journal of the Korean Chemical Society
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    • v.6 no.2
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    • pp.133-142
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    • 1962
  • This study was carried out to investigate the lead-bismuth-sodium ternary system which a basis of the Dittmer method as a part of "the fundamental study of pyrometallurgical debismuthizing of lead". Thermodynamic properties of each liquid Pb-Bi, Pb-Na binaries as well as liquid Pb-Bi-Na ternary solution were measured by e.m.f. of these concentration cells, and those of each component were also determined. Furthermore, iso-activity lines including Pb rich side composition of Pb-Bi-Na ternary solution were determined. The relationship between those thermodynamic characteristics and tendency of intermetallic compound formation was discussed through the above experiments.

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Fracture Toughness of the Thermoplastic Vulcanizates from EPDM/PP/Ionomer Ternary Blends (EPDM/PP/Ionomer 삼원 블렌드로 된 열가소성 가황체의 파괴 인성)

  • Kim, K.;Cho, W.J.;Ha, C.S.;Go, J.H.
    • Elastomers and Composites
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    • v.31 no.5
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    • pp.341-346
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    • 1996
  • The fracture mechanics investigation of the thermoplastic vulcanizates(TPV) from EPDM and PP/Ionomer ternary blends was performed in terms of the J-integral by measuring fracture energy via the locus method. The TPV from ternary blends consisting of EPDM, PP and ionomer were prepared in a laboratory integral mixer by blending and vulcanizing simultaneously. Vulcanization was performed with dicumyl peroxide (DCP) and the composition of EPDM and PP was fixed at 50/50 by weight. Two kinds of poly(ethylene-co-methacrylic acid) (EMA) lonomers were used. The J-integral values at crack initiation, Jc, of the dynamically vulcanized EPDM and PP/EMA Ionomer ternary blends were affected by the cation types $(Na^+\;or\;Zn^{2+})$ and contents(5-20wt%) of the added EMA Ionomers. The ternary blend containing 20wt% zinc-neutralized EMA Ionomer and 1.0phr DCP showed the highest Jc values of the blends.

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Phase Orientation of TiC-$TiB_2$-SiC Ternary Eutectic Composite Prepared by an FZ Method

  • Tu, Rong;Li, Wenjun;Goto, Takashi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.859-860
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    • 2006
  • TiC-$TiB_2$-SiC system was a ternary eutectic, whose eutectic composition was 34TiC-$22TiB_2$-44SiC (mol%). TiC-$TiB_2$-SiC ternary eutectic composite were synthesized by a floating zone method using TiC, $TiB_2$ and SiC powders as starting materials. The TiC-$TiB_2$-SiC eutectic composite showed a lamellar texture. TiC(022), $TiB_2(010)$ and SiC(111) of the eutectic composite were perpendicular to the growth direction. TiC-$TiB_2$-SiC ternary eutectic composite had specific relationship among the crystal planes: TiC[011]//$TiB_2[010]$//SiC[112], TiC(200)//$TiB_2$(001)//SiC(402) and $TiC(1\bar{1}1)$//$TiB_2(101)$//SiC(220).

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A Fundamental Study on the Pyrometallurgical Debismuthizing of Lead (粗鉛의 乾式 脫蒼鉛에 관한 基礎的 硏究)

  • Koh, Chang-Shik
    • Journal of the Korean Chemical Society
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    • v.6 no.2
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    • pp.143-147
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    • 1962
  • As a part of "the Fundamental Study of Pyrometallurgical Debismuthizing of Lead", the author has studied liquid Pb-Bi, Pb-Na, Bi-Na binaries and Pb-Bi-Na ternary including Pb rich side composition which forms a basis of the Dittmer method. In this study, debismuthizing mechanism of the Dittmer method pertaining to the lead rich corner of the system studied was classified by the results of thermal analysis, solubility determination of Bi and Na in liquid Pb and debismuthizing test by adding metallic sodium. For instance eutectic trough in lead rich corner of Pb-Bi-Na ternary relating to the Dittmer method was determined.

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Precise composition control of Sn-3.0Ag-0.5Cu lead free solder bumping made by two binary electroplating (이원계 전해도금법에 의한 Sn-3.0Ag-0.5Cu 무연솔더 범핑의 정밀 조성제어)

  • Lee Se-Hyeong;Lee Chang-U;Gang Nam-Hyeon;Kim Jun-Gi;Kim Jeong-Han
    • Proceedings of the KWS Conference
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    • 2006.05a
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    • pp.218-220
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    • 2006
  • Sn-3.0Ag-0.5Cu solder is widely used as micro-joining materials of flip chip package(FCP) because of the fact that it causes less dissolution and has good thermal fatigue property. However, compared with ternary electroplating in the manufacturing process, binary electroplating is still used in industrial field because of easy to make plating solution and composition control. The objective of this research is to fabricate Sn-3.0Ag-0.5Cu solder bumping having accurate composition. The ternary Sn-3.0Ag-0.5Cu solder bumping could be made on a Cu pad by sequent binary electroplating of Sn-Cu and Sn-Ag. Composition of the solder was estimated by EDS and ICP-OES. The thickness of the bump was measured using SEM and the microstructure of intermetallic-compounds(IMCs) was observed by SEM and EDS. From the results, contents of Ag and CU found to be at $2.7{\pm}0.3wt%\;and\;0.4{\pm}0.1wt%$, respectively.

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A Prediction Model for Condensation of Zeotropic Refrigerant Mixtures Inside a Horizontal Smooth Tube (수평평활관내의 비공비 혼합냉매의 응축에 대한 예측모델)

  • ;;小山繁
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.4
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    • pp.262-270
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    • 2001
  • This paper deals with a prediction method for the condensation of ternary refrigerant mixture inside a horizontal smooth tube. Based on some reliable assumptions, the governing equations for the local heat and mass transfer characteristics are derived, and the prediction for the condensation of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a, including R407C, is carried out. The local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, mass flux etc. are obtained for a constant wall temperature and a constant wall heat flux conditions, and the effects of the composition of HFC32/HFC125/HFC134a on heat transfer characteristics are examined. The prediction result is also compared with experimental data for condensation of ternary refrigerant mixtures. The predicted wall temperature distribution has a similar trend with experimental data but the predicted local heat transfer coefficients are 20-30% higher than the experimental data.

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III-V 삼상 화합물 반도체의 분자선 결정성장법에서의 열역학적 고찰

  • O, Won-Ung;O, Jae-Eng;Baek, Su-Hyun
    • ETRI Journal
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    • v.13 no.4
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    • pp.42-51
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    • 1991
  • MBE 성장시 기판 표면에서의 성장과정을 운동론적 지배과정과 열역학적 지배과정으로 나누어 성장모델을 제시하였으며, 화학적 평형상태에서의 열역학이 III-V compound의 성장속도와 composition 에 미치는 영향을 기존의 보고된 결과 데이터와 비교 분석하였다. 특히 miscibility gap 내에 존재하는 III-V ternary compound의 경우 박막의 성질 및 소자의 특성에 영향을 미치는 alloy clustering은 저온 성장시 surface kinetics에 의해, 고온성장시에는 열역학적 spinodal decomposition에 의해 결정됨을 알수 있었다. 열역학적 모델에서는 기판과 layer사이의 lattice mismatch와 재료의 elastic coefficient의 함수인 additive strain Gibbs free energy, 그리고 ternary solid solution의 regular behavior를 가정하여 ternary alloy의 mixing에 기인한 excess Gibbs free energy를 고려하였다.

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A Study on Composition and Firing Temperature of Bone China Body (골회자기의 소지 및 소성과정에 관한 연구)

  • 이응상;이성희
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.67-72
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    • 1989
  • In order to define the composition range of bone china body with use of calcium phosphate, kaolin, quartz and feldspar as raw materials, we varied calcium phosphate from 40 to 55wt/o and selected basic composition by the change of raw materials in ternary system. After these bodies were fired at 120$0^{\circ}C$, 123$0^{\circ}C$, 125$0^{\circ}C$ and 128$0^{\circ}C$ their properties were closely tested to determine the compositions and firing conditions of bone china body.

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