• Title/Summary/Keyword: Temperature reduction

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Various Temperatures Affecting Characteristics of Pt/C Cathode Catalysts for Polymer Electrolyte Membrane Fuel Cells (Polymer Electrolyte Membrane Fuel Cells용 Pt/C 캐소드 전극촉매 특성에 미치는 반응 온도)

  • Yoo, Sung-Yeol;Kang, Suk-Min;Lee, Jin-A;Rhee, Choong-Kyun;Ryu, Ho-Jin
    • Korean Journal of Materials Research
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    • v.21 no.3
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    • pp.180-185
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    • 2011
  • This study is aimed to increase the activity of cathodic catalysts for PEMFCs(Polymer Electrolyte Membrane Fuel Cells). we investigated the temperature effect of 20wt% Pt/C catalysts at five different temperatures. The catalysts were synthesized by using chemical reduction method. Before adding the formaldehyde as reducing agent, process was undergone for 2 hours at the room temperature (RT), $40^{\circ}C$, $60^{\circ}C$, $80^{\circ}C$ and $100^{\circ}C$, respectively. The performances of synthesize catalysts are compared. The electrochemical oxygen reduction reaction (ORR) was studied on 20wt% Pt/C catalysts by using a glassy carbon electrode through cyclic voltammetric curves (CV) in a 1M H2SO4 solution. The ORR specific activities of 20wt% Pt/C catalysts increased to give a relative ORR catalytic activity ordering of $80^{\circ}C$ > $100^{\circ}C$ > $60^{\circ}C$ > $40^{\circ}C$ > RT. Electrochemical active surface area (EAS) was calculated with cyclic voltammetry analysis. Prepared Pt/C (at $80^{\circ}C$, $100^{\circ}C$) catalysts has higher ESA than other catalysts. Physical characterization was made by using X-ray diffraction (XRD) and transmission electron microscope (TEM). The TEM images of the carbon supported platinum electrocatalysts ($80^{\circ}C$, $100^{\circ}C$) showed homogenous particle distribution with particle size of about 2~3.5 nm. We found that a higher reaction temperature resulted in more uniform particle distribution than lower reaction temperature and then the XRD results showed that the crystalline structure of the synthesized catalysts are seen FCC structure.

Study on the Improvement of Dyeability of Commercial Indigo Leaf Powder for the Purpose of Utilizing It in Indigo Dyeing (시판 쪽잎 분말의 쪽 염료에의 활용을 위한 염색성 향상 연구)

  • Yoo, Wansong;Ahn, Cheunsoon;Narantuya, Lkhagva;Li, Longchun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.38 no.4
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    • pp.540-556
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    • 2014
  • This research investigated the effective conditions to dye cotton with commercial indigo leaf powder. We tested dyeing conditions of: pH of dyebath (6.5, 9-12), heating ($20^{\circ}C$, $50^{\circ}C$, $70^{\circ}C$, $90^{\circ}C$), ageing (0, 0.5, 1, 4, 24 hours), reduction time (0, 30, 60 min), and dyeing temperature ($2^{\circ}C$, $10^{\circ}C$, $20^{\circ}C$, $50^{\circ}C$, $70^{\circ}C$, $80^{\circ}C$), dyeing was conducted for 20 minutes. The highest K/S value was obtained when cotton was dyed using pH 11 dyebath, heated at $50^{\circ}C$ for 30 minutes, aged for 24 hours at room temperature ($20^{\circ}C$), reduction carried out for 30 minutes, and dyed at $50^{\circ}C$. It is proposed that the K/S value is primarily influenced by the dyebath pH and dyeing temperature, followed by the presence or absence of ageing time and reduction time. The color of cotton with high K/S values was B type by Munsell hue value, which was similar to the color obtained in previous studies by freshly made indigo leaf powder and indigo leaf juice. The results indicate that the dyeing conditions established in this research are suitable to maximize the dyeability of commercial indigo leaf powder and that the indigo leaf powder can be used as a substitute for fresh indigo leaf juice.

Effects of stress induced by changes of water temperature on the non-specific defense mechanism in cultured olive flounder, Paralichthys olivaceus (수온 변동 자극이 양식 넙치, Paralichthys olivaceus의 비특이적 생체 방어에 미치는 영향)

  • Lee, Deok-Chan;Kim, Do-Hyung;Kim, Su-Mi;Kang, Myong-Seok;Hong, Mi-Ju;Kim, Hyun-Jeong;Park, Soo-Il
    • Journal of fish pathology
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    • v.15 no.2
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    • pp.65-75
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    • 2002
  • This study was performed to know the effects of stress induced by the daily fluctuation of water temperture from 18$^{\circ}C$ to 25$^{\circ}C$ up and down for 30 days on the defence mechanism of olive flounder. Puralichthys olivaceus. To make clear the temperature stress on the defense mechanism of the tested fish. several factors of immune response such as counting of leucocyte appearance in peripheral blood, phagocytic activity in whole blood cells, nitroblue tetrazolium(NBT) reduction, chemiluminescence(CL) response, and lysozyme activity were investigated at 28 days after giving the change of water temperature. The fish was controlled under the none feeding condition during experimental period. Mortality of the tested fish was rapidly increased up to 22% within the first one week of the experimental period without any additional stress factors. The number of neutrophil of peripheral blood in the tested group was significantly higher than the control group at the 2nd week. but the number of lymphocyte was significantly lower than the control group at the 1st and 3rd day of the experimental period. respectively. In the NBT reduction test, the activity of macrophage in the control group fish was the highest on the 7th day while that in the tested group was on the 3rd day. Also. the phagocytosis of tested group against formalin killed cells was retarded compared with the control. CL response of the tested group was significantly lower from 2nd to 5lh day of the experimental period than the control. 'The lysozyme activity of tested group was remained higher during the experimental period than the control. Even though the tested fish showed different results in some non-specific factors of immune respceses between tested and control group fish, olive flounder seems highly adaptable in repealed water temperature change in condition after one week under the given temperature fluctuation range.

Development of CO2 Emission Estimation Model by Multiple Regression Analysis (다중회귀분석을 이용한 CO2배출량 추정모형)

  • Cho, Han-Jin;Jang, Seong-Ho;Kim, Yong-Sik
    • Journal of Environmental Health Sciences
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    • v.34 no.4
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    • pp.316-326
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    • 2008
  • The Earth's temperature has risen $0.76^{\circ}C$ (degree) during last 100 years which Implies a sudden rise, compare with the 4oC (degrees) rise through out the past 20,000 years. If the volume of GHG (Greenhouse Gas) emission continues at the current level, the average temperature of the Earth will rise by $1^{\circ}C$ (degree) by 2030 with the further implication that the temperature of Earth will rise by $2{\sim}5^{\circ}C$ (degrees) every 100 years. Therefore, as we are aware that the temperature of the glacial epoch was $8{\sim}9^{\circ}C$ (degrees) lower than the present time, we can easily predict that the above temperature rises can be potentially disastrous for human life. Every country in the world recognizes theseriousness of the current climate change and adopted a convention on climate change in June 1992 in Rio. The COP1 was held in March 1995 in Berlin and the COP3 in Dec. 1997 in Kyotowhere the target (2008-2012) was determined and the advanced nations' reduction target (5.2%, average)was also agreed at this conference. Korea participated in the GHG reduction plan which required the world's nations to ratify the Kyoto Protocol. Ratification of the Kyotoprotocol and the followup requirement to introduce an international emissions trading scheme will require severe reductions in GHGs and considerable economic consequences. USA are still refusing to fully ratify the treaty as the emission reductions could severely damage the economies of these countries. In order to estimate the exact $CO_2$ emission, this study statistically analyzed $CO_2$ emission of each country based on the following variables : level of economic power and scientific development, the industrial system, productivity and energy efficiency.

Analysis of Energy Reduction of Free Cooling System with Regions of South Korea (지역별 프리쿨링 시스템의 에너지 절감 분석)

  • Yoon, Jung-In;Son, Chang-Hyo;Choi, Kwang-Hwan;Baek, Seung-Moon;Heo, Jeong-Ho;Kim, Young-Min
    • Journal of the Korean Solar Energy Society
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    • v.34 no.3
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    • pp.82-88
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    • 2014
  • Using low outdoor temperature, free cooling system is used in a data center or industrial air-conditioning for energy saving. Because use of IT equipment has increased in some office building recently, there is a growing trend towards using free cooing system. Free cooling system performance is influenced by outdoor temperature. Therefore the performance is different with regions. In this study, performance characteristic of free cooling system is analysed and energy reduction is compared with some regions. Selected regions are 4 cities; including Ulsan analyzed in preceding research, Seoul, ChunCheon and Daejeon. The Aspentech software HYSYS 8.0v was used to conduct the analysis of free cooling system based on temperature per hour of 4 cities in 2013, respectively. The main result is following as. Free cooing system in this study has energy saving effect when outdoor temperature below $7^{\circ}C$. Becuase temperature of Chuncheon is relatively low, using free cooling system can conserve most air-conditioning energy. Energy reduction amount of Seoul is 11%, Chuncheon is 17.5%, Deajeon is 15%, Ulsan is 14%. In case of large scale of air-conditioning, it is reasonable to use free cooling system although the system is used in Seoul.

Behaviors of Mechanical Properties of Filament-Winding-Laminated Composites due to Environmental Aging (필라멘트 와인딩 복합재의 환경노화에 따른 기계적물성 평가)

  • Choi Nak-Sam;Yun Young-Ju;Lee Sang-Woo;Kim Duck-Jae
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.31-35
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    • 2006
  • Degradation characteristics of filament-winded composites due to accelerated environmental aging have been evaluated under high temperature, water immersion and thermal impact conditions. Two kinds of laminated composites coated by an urethane resin have been used: carbon-fiber reinforced epoxy(T700/Epon-826, CFRP) and glass-fiber reinforced phenolic (E-glass/phenolic, GFRP). For tensile strength of $0^{\circ}$ composites, CFRP did high reduction by 25% under the influence of high temperature and water while CFRP showed little degradation. However for water-immersed $90^{\circ}$ composites both CFRP and GFRP showed high reduction in tensile strength. Bending strength and modulus of $90^{\circ}$ composites were largely reduced in water-immersion as well as high temperature environment. Urethane coating on the composite surface improved the bending properties by 20%, however hardly showed such improvement for water-immersed $90^{\circ}$ composites.

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Indoor Temperature Control of a Heat Pump Based on Model Predictive Control Considering Energy Efficiency (에너지효율을 고려한 모델예측제어에 기초한 열펌프의 실내온도 제어)

  • 조항철;변경석;송재복;장효환;최영돈
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.3
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    • pp.200-208
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    • 2001
  • In indoor temperature control of a heat pump, a reduction in energy consumption is very important. However, most control schemes for heat pumps have focused only on control performance such s settling time and steady-state error. In this paper, the model predictive control (MPC) which includes the energy-related variable in this cost function is proposed. By computing the control signal minimizing this cost function, the trade-off between energy reduction and temperature control performance can be obtained. Since the MPC required the process model, the dynamic mode of a heat pump is also obtained by the system identification technique. Performance of the proposed MPC considering energy efficiency is compared with the two other control schemes. It si shown that the proposed scheme can consume less energy thant hte others in achieving similar control performance.

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A Study on the Reduction of HC and Heat Characteristics of the Dual Pipe Exhaust Manifold (이중관 배기메니폴드의 HC저감효과 및 열특성에 관한 연구)

  • 박경석;허형석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.6
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    • pp.103-111
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    • 2001
  • During cold-start period, the reduction of exhaust emissions is a challenging task. To decrease harmful gaseous substances such as HC, it is necessary to realize a fast catalyst warm-up. In this study, the performance of dual pipe exhaust system have been carried out through different test mode. From measurement of gas temperature and HC concentration, the following conclusions were derived ; 1) Compared with single pipe, dual pipe exhaust system remarkably increase temperature of exhaust gas going through M.C.C(Main Catalytic Converter). 2) W.C.C.(Warm-up Catalytic Converter) also decreases HC emission. To reduce HC emission, it is helpful to use W.C.C. as well as dual pipe exhaust system. 3) Using finite element method, it is shown that inner parts have much higher distribution of temperature than outer parts.

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Shear Spinning of Ti-6Al-4V Alloy at Hot Working Temperature (Ti-6Al-4V 합금의 열간 전단 스피닝)

  • Lee, H.S.;Song, Y.B.;Hong, S.S.
    • Transactions of Materials Processing
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    • v.20 no.6
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    • pp.432-438
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    • 2011
  • A method for estimating the shear spinnability is suggested, and it was applied to sheets of Ti-6Al-4V alloy for estimation of shear spinnability at hot working temperature. The effective working temperature was $850^{\circ}C$ or above. The hot spinning operation was carried out in two steps of shear spinning. The reduction of thickness at the first step was 50% and 45% at the second, and the overall reduction of thickness was 72.4%. The cone spinning process could produce a uniform wall thickness with only a few percent tolerance, proving itself appropriate for making cones of Ti-6Al-4V alloy with uniform wall thickness.

An Experimental Study on SOx Reduction in Diesel Engine (SOx저감을 위한 DOC에 관한 실험적 연구)

  • 오용석;박봉규
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.3
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    • pp.261-266
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    • 1998
  • Recently, air pollution is increased according to increase of vehicle. So many countries are studying about DOC for diesel emission decrease. However, there are many difficulty in applying to DOC . In this study, SOx exhaust gas equipped with DOC was studied and we obtained several test results as following. First, in diesel oxidation catalyst, additives such as Pt is very effective for 503 and sulfate. Second, the oxidative activity for 502 has decreased to add such as Pt and the decrease of 502 is effect for the reduction of PM in high temperature . And finally, in high temperature, concentration of SOx is increased and temperature is affected by process from SOB to 503, whereas engine performance and fuel consumption are not affected by equipped DOC.

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