• Journal of Sericultural and Entomological Science
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• v.40 no.2
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• pp.163-168
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• 1998

Hydrolysis rate and activation energy of Antheraea pernyi silk fiber treated with HCI were examined. Thermal decomposition temperature and surface morphology were also investigated by using differential scanning calorimeter and scanning electron microscope. As the concentration of hydrochloric acid and the treatment temperature increased, the hydrolysis occurred more rapidly. The activation energy of Antheraea pernyi, 74.0 kJ/mol, was higher than that of Bombyx mori, 58.1 kJ/mol. As the concentration of hydrochloric acid increases, the activation energy of Antheraea pernyi decreased from 74.0 kJ/mol to 62.0 kJ/mol. The shape of acid-resistance fraction of Antheraea pernyi became more distroyed and was transformed from fiber to powdered form with an increase of hydrolysis rate. The thermal decomposition temperature of Antheraea pernyi was 360.8$^{\circ}C$ until the hydrolysis rate was 81.8 wt%, but ti decreased to 347.0$^{\circ}C$ when the hydrolysis rate was 93.8 wt%.

• Journal of the Korean Solar Energy Society
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• v.25 no.4
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• pp.69-76
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• 2005

The performance of water-to-water heat pump system coupled with the ground source vertical heat exchanger is presented in this paper. The CAP program of Florida Heat Pump Co. is used to predict the heat pump performances while the EED program calculates the borehole fluid temperature. It is shown that COPH increases with decreasing the temperature of output water for the operation of heating mode and COPR increases with increasing temperature of output water for the operation of cooling mode. The value of specific heat extraction rate must be moderate to insure the reasonable installation cost of borehole system. With $1^{\circ}C$decrease of $T_{wo}$ the average COPH increase is estimated as about $0.06/^{\circ}C$(for $T_{wo}\;=\;45{\sim}60^{\circ}C$ range) while with $1^{\circ}C$ increase of $T_{wo}$ the estimation of COPR increase is about $0.13/^{\circ}C$(for $T_{wo}\;= \;5{\sim}11^{\circ}C$ range) at the specific heat extraction rate of 30W/m.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.3
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• pp.358-370
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• 1997

In the present study, investigations were carried out to obtain data on combustion characteristics of methane gas and hydrogen supplemented methane gas in a constant volume combustion chamber. The main results obtained from the study can be summarized as follows. The maximum combustion pressure increases as the initial pressure and hydrogen supplement rate increase, the total burning time is shorten by lowering the initial pressure and by increasing the hydrogen supplement rate. The maximum flame temperature and NO concentration increase by the initial pressure and hydrogen supplement rate increase. The flame propagation processes in near stoichiometric mixture are propagated with a spherical shape, but in excess rich or lean mixtures are propagated with a elliptical shape. And, they are changed an unstable elliptical shape flame with very regular cells by increasing the hydrogen supplement rate.

• Journal of Industrial Technology
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• v.17
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• pp.241-247
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• 1997

A numerical model has been proposed for a diffusion flame reactor to manufacture ultrafine $TiO_2$ powders. The model equations such as mass balance equation, the 0th, 1st, and 2nd moment equations of aerosols were considered. The phenomena such as $TiCl_4$ reaction rate, $TiO_2$ nucleation rate and the coagulation of $TiO_2$ powders were included in the aerosol dynamic equation. It is found that the $TiO_2$ particle concentration becomes higher, as the inlet $TiCl_4$ concentration and the total gas flow rate increase, and also as the flame temperature decreases. The $TiO_2$ particle size increases, as the flame temperature and the inlet $TiCl_4$ concentration increase and the total gas flow rate decreases.

• Tribology and Lubricants
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• v.30 no.3
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• pp.146-155
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• 2014

In this study, we conduct fretting corrosion tests on tin-plated brass coupons to investigate the effect of temperature on fretting corrosion for various span amplitudes. We prepare a coupled fretting corrosion specimens using a tin-plated brass coupon with a thickness of $10{\mu}m$. One specimen is a flat coupon and the other specimen is a coupon with a protuberance in 1 mm radius, which is produced using 2 mm diameter steel ball. We conduct fretting corrosion tests at $25^{\circ}C$, $50^{\circ}C$, $75^{\circ}C$, $100^{\circ}C$ by rubbing the coupled coupons together at the contact between the flat and protuberance coupons. We measure electric resistance of the contact during the fretting corrosion test period. There is increase in resistance with fretting cycles. It is found that rate of increase in electric resistance becomes faster with increase in testing temperature. Magnitude of friction coefficient increases with fretting span amplitudes. And, change in friction coefficient becomes desensitized to the increment in span amplitude. Assuming that failure cycle is the cycle with an electric resistance of $0.01{\Omega}$, we find that failure lifetime ($N_f$) decreases with increase in testing temperature. Furthermore, based on the assumption that the damage rate of the connector is inversely related to the failure cycle, we calculate the activation energy for fretting damage to be 13.6 kJ/mole by using the Arrhenius equation. We propose a method to predict failure cycle at different temperatures for span amplitudes below $30{\mu}m$. Friction coefficients generally increase with increase in span amplitude and decrease in testing temperature.

• Journal of Photoscience
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• v.9 no.2
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• pp.299-301
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• 2002

Recent denaturation experiments of bacteriorhodopsin (bR) in the dark and under illumination at high temperatures revealed that irreversible thermal bleaching occurs above ~ 70°C and the preceding reversible structural changes in the dark above 60°C are closely related to irreversible photobleaching observed in the same temperature range (Yokoyama et al. (2002). J Biochem. 131,785). In this study, structural properties of bacteriorhodopsin (bR) at high temperatures were extensively probed by hydroxylamine reactivity with the Schiff base in the dark and hydrogen-deuterium (H-D) exchange in the peptide groups. In the Arrhenius plot from kinetics measurements of the hydroxylamine reaction, a good linear relationship between the reaction time constant and the inverse of the absolute temperature was observed below 60°C, while significant increase started above 60°C, suggesting that remarkable increase in water accessibility of the Schiff base in the temperature region. FT-IR spectroscopic studies on the H-D exchange suggested increase in the deuterium exchanges rate of the peptide hydrogen in the same temperature region.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.11
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• pp.7736-7744
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• 2015

Considering the significant waste of industrial energy, effective use of low temperature waste heat is extremely important. In this study, a heat pump cycle with double effect and double stage was realized, which escalates the hot water temperature from $50^{\circ}C$ to $70^{\circ}C$ using $160^{\circ}C$ high temperature heat source and $17^{\circ}C$ low temperature heat source. The steam generated in the first generator condenses in the first condenser generating steam in the second generator. The steam condenses in the second condenser and is provided to the second evaporator. Part of the water out of the second evaporator is supplied to the first evaporator, which evaporates using low temperature waste heat. The evaporated steam enters the first absorber and the second evaporator. The steam out of the second evaporator is absorbed into the solution at the second absorber. The hot water temperature is raised in the second condenser and in the second absorber. Proper flow rates and UA values, which satisfied temperature lift $20^{\circ}C$ and COP 1.6, were deduced through trior and error. The COP increases as the temperature of the high temperature water increases, hot water temperature decreases and flow rate increases, waste water temperature and flow rate increases, solution circulation rate decreases. On the other hand, the temperature rise of the hot water increases as the temperature of the high temperature water increases, hot water temperature increases and flow rate decreases, waste water temperature and flow rate increases, solution circulation rate increases. In addition, the COP and hot water temperature rise increase as UAs of the heat exchangers increase.

• Progress in Superconductivity and Cryogenics
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• v.17 no.3
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• pp.9-12
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• 2015

NbN thin films were deposited on thermally oxidized Si substrate at room temperature by using reactive magnetron sputtering in an $Ar-N_2$ gas mixture. Total sputtering gas pressure was fixed while varying $N_2$ flow rate from 1.4 sccm to 2.9 sccm. X-ray diffraction pattern analysis revealed dominant NbN(200) orientation in the low $N_2$ flow rate but emerging of (111) orientation with diminishing (200) orientation at higher flow rate. The dependences of the superconducting properties on the $N_2$ gas flow rate were investigated. All the NbN thin films showed a small negative temperature coefficient of resistance with resistivity ratio between 300 K and 20 K in the range from 0.98 to 0.89 as the $N_2$ flow rate is increased. Transition temperature showed non-monotonic dependence on $N_2$ flow rate reaching as high as 11.12 K determined by the mid-point temperature of the transition with transition width of 0.3 K. On the other hand, the upper critical field showed roughly linear increase with $N_2$ flow rate up to 2.7 sccm. The highest upper critical field extrapolated to 0 K was 17.4 T with corresponding coherence length of 4.3 nm. Our results are discussed with the granular nature of NbN thin films.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.27 no.5
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• pp.277-282
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• 2015

During hot and humid weather, air-conditioners consume a large amount of electricity due to the large amount of latent heat. Simultaneous usage of a dehumidifier may reduce latent heat and reduce electricity consumption. In this study, dehumidification performance was measured for a small-sized dehumidification rotor made of inorganic fiber impregnated with metallic silicate within a constant temperature and humidity chamber. Regeneration to dehumidification depends on ratio, rotor speed, room temperature, regeneration temperature, room relative humidity and frontal velocity to the rotor. Results demonstrate an optimum area ratio (1/2), rotor speed (1.0 rpm), and regeneration temperature ($100^{\circ}C$) to achieve a dehumidification rate of 0.0581 kg/s. As the area ratio increases, the optimum rotation speed and the optimum regeneration temperature also increase. Above the optimum rotor speed, incomplete regeneration reduces dehumidification. Above the optimum regeneration temperature, increased temperature variation between regeneration and dehumidification reduces dehumidification. Dehumidification rate also increases with an increase of relative humidity, dehumidification temperature and flow velocity into the rotor.

• Journal of Pharmaceutical Investigation
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• v.26 no.4
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• pp.263-271
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• 1996

Sulconazole nitrate(SCN), an imidazole derivative which has been effective in the treatment of dermatophytosis, tinea versicolor and candidiasis, was formulated as a gel containing drug, poloxamer 407, ethanol and propylene glycol. The resulting SCN gels were evaluated with respect to their viscosity, drug release rate, skin permeation rate. The apparent viscosity of SCN gel increased in proportion to poloxamer 407, drug and propylene glycol concentration. In case ethanol was added, the apparent viscosity decreased. The drug release rate of SCN gel increased in proportion to temperature and ethanol concentration. But the drug release rate decreased as the concentration of poloxamer 407 increased. The increase of drug concentration induced nonlinear increase of drug release rate. When propylene glycol was added at the level of 10%, the drug release rate increased but from 15% it decreased. The skin permeation rate decreased in high concentration of poloxamer 407. The skin permeation rate of SCN gel containing 15% ethanol increased about twice than that of gel without ethanol. The increase of drug concentration induced nonlinear increase of skin permeation rate. When propylene glycol was added at the level of 10%, the skin permeation rate increased but from 15% it decreased.