• 제목/요약/키워드: Tar

검색결과 476건 처리시간 0.031초

석탄 유분에 대한 물성예측식 개발 및 공정에 대한 연구 (Thermodynamic Correlations for Predicting the Properties of Coal-Tar Fractions and Process Analysys)

  • 오준성;이의수;박상진
    • Korean Chemical Engineering Research
    • /
    • 제43권4호
    • /
    • pp.458-466
    • /
    • 2005
  • 회분식 증류 공정을 모델링하기 위해서는 평형상수와 엔탈피값이 필요하며 이 값들은 열역학적인 계산 방법에 의해 계산된다. 석탄 유분인 coal tar의 경우에는 성분이 다양하고 coal tar내의 성분을 대부분 알 수 없으므로 가상성분으로 만들어 적절한 물성예측식을 사용하여 물성값을 계산해 주어야 한다. 본 연구에서는 기존의 물성예측식에 의해 계산된 값과 이미 알려진 coal tar 유분의 실제물성값의 차이를 기 개발된 물성예측식에 대해 비교하였고 물성예측식에 필요한 2개의 parameter(NBP, SG)대신 1개의 변수(NBP)를 사용하여 간단한 물성예측식을 도출하였다. 또한 이상 기체 열용량 예측식의 경우에도 같은 방법을 적용하였다. 개발된 물성 예측식 및 회분식 증류공정프로그램은 coal tar계에 적용하여 coal tar 중 유효성분 분리를 위해 효율적으로 적용할 수 있다 하겠다.

TAR cloning 법에 의한 인간 및 마우스의 상동성 HPRT 유전자의 분리 (Isolation of Human and Mouse Orthologue HPRT Genes by Transformation-Associated Recombination (TAR) cloning)

  • 도은주;김재우;정정남;박인호;임선희
    • 생명과학회지
    • /
    • 제16권6호
    • /
    • pp.1036-1043
    • /
    • 2006
  • TAR (Transformation-Associated Recombination) cloning법은 복잡한 고등생물의 게놈으로부터 유전자나 특정 염색체 부위를 선별적 분리를 가능하게 한다. 이 방법은 목적으로 하는 염색체 부위의 주변에 존재하는 비교적 짧은 게놈 염기서열에 대한 정보를 필요로 한다. 이 기술은 출아효모의 spheroplasts 형질전환 동안 목적 유전자를 포함한 게놈 DNA와 그 유전자의 5' 또는 3' 말단 서열 (hook)을 포함하고 있는 TAR vector 사이에 일어나는 상동성 재조합에 의해 이루어진다. 본 연구에서는 TAR cloning 법을 상동성 유전자의 분리에 사용할 수 있는가를 조사하기 위해, 연간과 마우스 게놈의 HPRT 유전자를 선택하였다. 그 결과, 인간과 마우스의 게놈으로부터의 HPRT 유전자의 분리 빈도는 TAR vector로서 hHPRT hook 혹은 mHPRT hook을 사용한 경우에 거의 동일하게 나타났다. 또한 mHPRT 유전자의 gap 부분의 염기서열을 결정하여, 이 부분에 염기서열의 불안정의 요인이 되는 비정상적 특성을 발견하였다. 결론적으로 TAR cloning법을 이용하여 다른 이종 간의 게놈으로부터 상동성 유전자 즉 orthologue의 분리가 가능하였다. 더욱이 TAR cloning 시스템을 이용하여 고등동물 게놈 상에 남아있는 gap 부분을 메움으로서 고등동물의 모든 유전자들의 확인이 가속화될 수 있을 것으로 사료된다.

국내 시판중인 소아용 의약품에 함유된 타르색소의 표기실태 조사 연구 (Investigation on the Current Labelling Trend of Tar Color Additives in Infant's Drugs Marketed in Korea)

  • 김광준;방준석;이원재
    • 한국임상약학회지
    • /
    • 제23권3호
    • /
    • pp.248-255
    • /
    • 2013
  • Objective: This paper was aimed to investigate the current labelling trend of tar color additives in infant's drugs used in Korea and other countries. Method: The current labelling system of the tar color additives in infant's drugs was investigated using inserted papers for drug information of infant's drugs as well as three drug information internet sites popular in Korea including internet sites of foreign countries of USA, UK, Japan, and China for infant's drug information. Results: Among 325 drugs registered as syrup form for infant's drugs (sources, http://www.health.kr), 4 drugs indicated tar color related information on the internet and only 2 drugs indicated tar color additives' name. And from the investigated results of 76 inserted papers for infant's drug information, among 31 drugs containing tar dyes, in only 19 drugs the tar color additives' names were notated. Among 6 drugs which do not contain tar dyes, only 1 drug was notated as 'Dye-Free'. Conclusion: For advanced labelling system in Korea, we proposed the below guidelines. [1] The name of tar color additives used in infant's drugs should be notated even in drug information on internet sites. [2] All drug ingredients used in infant's drugs need to be separately notated as active and inactive species on both internet sites and inserted papers. [3] 'Dye-Free' notation should be mandatory for infant's drugs which do not contain tar color additives in drug information on the internet sites as well as inserted papers.

TAR-GARCH 모형을 이용한 국내 주가 자료 분석 (TAR-GARCH processes as Alternative Models for Korea Stock Prices Data)

  • 황선영;김은주
    • 응용통계연구
    • /
    • 제13권2호
    • /
    • pp.437-445
    • /
    • 2000
  • 국내 주가시계열을 분석하기 위해 기존의 비선형시계열모형인 분계점을 가진 자기외귀모형(TAR)과 일반화 이분산자기회귀모형(GARCH)을 비교 분석한 후, 이 두가지 모형을 결합시킨 새로운 모형 TAT-GARCH모형을 제안하였다. 이 모형은 그 자체로도 이론적인 관삼의 대상이 되어 연관된 모수추정 기법을 제시하였고 국내 개별 주가시계열 자료의 분석에 있어서 제안된 모형이 기존의 모형들 보다 상대적으로 더 좋은 예측치를 제공할 수 있음을 특정 9개 회사의 주가분석을 통해 알아보았다.

  • PDF

국내외 제품담배의 tar, nicotine 및 vapour phase 이행량 비교

  • 김정열;신창호;김종열
    • 한국연초학회지
    • /
    • 제20권2호
    • /
    • pp.225-230
    • /
    • 1998
  • A comparative study of major brands of domestic and imported cigarettes saled in market has been conducted. The total amounts of total particulate matter(TPM), tar and nicotine delivered from cigarettes, as well as the amounts of tar, nicotine in puff by puff were determined in the mainstream smoke of 6 brands. In addition, the relative amounts of vapour phase in 3rd puff smoke were determined. Results showed that the amounts of TPM and tar delivered from domestic brands were similar to the imported brands and the amounts of total nicotine delivered from domestic brands were higher than those of imported brands. As the domestic cigarettes nicotine/tar(N/T X 100) ratio was 9.5-10.3, the imported one's was 5.6-8.1. However, the amounts of tar and nicotine in puff by puff for the domestic brands were lower than those of the imported cigarettes and the relative amounts of vapour phase in 3rd puff smoke for the domestic cigarettes were lower than those of the imported cigarettes.

  • PDF

Microwave-enhanced gasification of sewage sludge waste

  • Chun, Young Nam;Song, Hee Gaen
    • Environmental Engineering Research
    • /
    • 제24권4호
    • /
    • pp.591-599
    • /
    • 2019
  • To convert sewage sludge to energy, drying-gasification characteristics during microwave heating were studied. During the gasification of carbon dioxide, the main products were gas, followed by char, and tar in terms of the amount. The main components of the producer gas were carbon monoxide and hydrogen including a small amount of methane and light hydrocarbons. They showed a sufficient heating value as a fuel. The generated tar is gravimetric tar, which is total tar. As light tars, benzene (light aromatic tar) was a major light tar. Naphthalene, anthracene, and pyrene (light polycyclic aromatic hydrocarbon tars) were also generated, but in relatively small amounts. Ammonia and hydrogen cyanide (precursor for NOx) were generated from thermal decomposition of tar containing protein and nitrogen in sewage sludge. In the case of sludge char, its average pore diameter was small, but specific area, pore volume, and adsorption amounts were relatively large, resulting in superior adsorption characteristics.

온도와 부하의 비선형성을 이용한 단기부하예측에서의 TAR(Threshold Autoregressive) 모델 (TAR(Threshold Autoregressive) Model for Short-Term Load Forecasting Using Nonlinearity of Temperature and Load)

  • 이경훈;이윤호;김진오
    • 대한전기학회논문지:전력기술부문A
    • /
    • 제50권9호
    • /
    • pp.399-399
    • /
    • 2001
  • This paper proposes TAR(Threshold Autoregressive) model for short-term load forecasting including temperature variable. In the scatter diagram of daily peak load versus daily high or low temperature, we can find out that the load-temperature relationship has a negative slope in the lower regime and a positive slope in the upper regime due to the heating and cooling load, respectively. TAR model is adequate for analyzing these phenomena since TAR model is a piecewise linear autoregressive model. In this paper, we estimated and forecasted one day-ahead daily peak load by applying TAR model using this load-temperature characteristic in these regimes. The results are compared with those of linear and quadratic regression models.

온도와 부하의 비선형성을 이용한 단기부하예측에서의 TAR(Threshold Autoregressive) 모델 (TAR(Threshold Autoregressive) Model for Short-Term Load Forecasting Using Nonlinearity of Temperature and Load)

  • 이경훈;이윤호;김진오
    • 대한전기학회논문지:전력기술부문A
    • /
    • 제50권9호
    • /
    • pp.309-405
    • /
    • 2001
  • This paper proposes TAR(Threshold Autoregressive) model for short-term load forecasting including temperature variable. In the scatter diagram of daily peak load versus daily high or low temperature, we can find out that the load-temperature relationship has a negative slope in the lower regime and a positive slope in the upper regime due to the heating and cooling load, respectively. TAR model is adequate for analyzing these phenomena since TAR model is a piecewise linear autoregressive model. In this paper, we estimated and forecasted one day-ahead daily peak load by applying TAR model using this load-temperature characteristic in these regimes. The results are compared with those of linear and quadratic regression models.

  • PDF

Transformation-associated recombination cloning에 의한 유전자 분리에 사용되는 target hook에 대한 GC content의 영향 (Effect of GC Content on Target Hook Required for Gene Isolation by Transformation-Associated Recombination Cloning)

  • 김중현;신영선;윤영호;장형진;김은아;김광섭;정정남;박인호;임선희
    • 미생물학회지
    • /
    • 제39권3호
    • /
    • pp.128-134
    • /
    • 2003
  • Transformation-associated recombination (TAR) 클로닝법은 목적 유전자를 포함한 게놈 DNA와 그 유전자의 5' 또는 3' 말단 서열을 포함하고 있는 선형의 TAR vector를 동시에 출아효모의 spheroplast내로 co-penetration 시켜 상동부위에서 일어나는 재조합에 의해 환형의 Yeast Artification Chromosome(YAC)으로 분리되는 방법이다. 일반적으로 TAR 클로닝법에 의한 목적의 single-copy 유전자 분리 빈도는 전체 형질전환체의 0.01~1% 정도이다. 이러한 TAR 클로닝법을 개선하기 위하여 Tg.AC transgenic mouse를 모델계로 사용하여 유전자 분리에 대한 target hook 내의 GC content 가 미치는 영향을 조사하였다. 이러한 목적으로 한쪽에는 다양한 GC content(18~45%)를 지닌 transgene 특이적 hook을 포함하고 다른 한쪽은 B1 반복서열을 가지는 radial TAR vector를 사용하여 transgene 분리 빈도를 측정하였다. 그 결과 target hook의 GC content는 23% 이하의 경우, ~40%인 경우에 비해 두 배 정도 클로닝 빈도가 감소하였다. 따라서 TAR vector를 제작할 때, 유전자 분리에 이용되는 target hook의 GC content는 약 40% 일때 가장 적정한 것으로 나타났다. 또한 높은 target hook 내의 GC content(65%)위치분포에 의한 차이는 클로닝 빈도에 큰 영향을 미치지 않는 것으로 나타났다.

국내 원료잎담배의 착엽위치 및 가공등급에 따른 연기성분 변화 (Changes of Smoke Components with Stalk Position and Grade of Korean Leaf Tobacco)

  • 황건중;이문수
    • 한국연초학회지
    • /
    • 제24권1호
    • /
    • pp.38-45
    • /
    • 2002
  • This study was conducted to determine the smoke component concentration and the smoke distribution in the cambridge filter pad and cigarette filter with stalk position and grade of Korean leaf tobaccos. 12 grades of flue-cured and burley leaf tobaccos which were taken from the Kim-cheon and Ock-cheon leaf tobacco processing factory were used for this study. Six kinds of smoke components such as tar, nicotine, water, carbon monoxide(CO), carbon dioxide($CO_2$) puff No. collected in the cambridge filter pad and cigarette filter were analyzed. Also, nicotine/tar, CO/tar ratio were calculated from the analytical data. Puff no., CO, and $CO_2$ concentration of flue-cured and burley tobacco leaves at high stalk position were higher than those of low stalk position, and these components were increased in high grade of leaf tobacco. Compared with flue-cured tobacco, burley tobacco showed a little values of puff no., nicotine, and tar concentration. The pH range of burley tobaccos was broader than that of flue-cured tobaccos, and the ammonia concentration of burley tobaccos was significantly higher than that of flue-cured tobaccos. The pH value and ammonia concentration of burley tobaccos were decreased as stalk position of leaf tobaccos decreased. The distribution of smoke components collected in the cambridge filter pad and cigarette filter was different with a different grade and stalk position of tobacco leaves. In high stalk position of tobacco leaves, the portion of smoke components collected in the cambridge filter pad was also increased. The average nicotine, water, and tar removal efficiency by a cigarette filter in a flue-cured tobacco were 37%, 64%, and 48%, respectively. Compared with flue-cured tobaccos, smoke components of burley tobaccos had high nicotine and low water removal efficiency by a cigarette filter. The average ratio of nicotine/tar and CO/tar of flue-cured tobaccos and burley tobaccos were 0.097, 1.22, 0.094, and 0.97, in order. Nicotine/tar ratio was decreased and CO/tar ratio was increased in low stalk position.