• Title/Summary/Keyword: TWA

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A Study on Variation of Landfill Gases in Completed Refuse Landfill Site after the Stabilization (사용종료 매립지의 지반안정화 후 매립가스의 변화)

  • Lee, Min-Hee;Ju, So-Young;Park, Jun-Kyu;Yeon, Ik-Jun;Kim, Kwang-Yul
    • Journal of the Korean GEO-environmental Society
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    • v.5 no.1
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    • pp.27-34
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    • 2004
  • The reclaimed waste layer in a completed refuse small landfill site was stabilized by JSP(Jumbo Special Pattern System) method. There were some variations of landfill gases(LFGs) after the stabilization. This study investigated the landfill gases emitted from a open dumping landfill site. We measured concentration of landfill gases before and after the construction, and 28 months later. As a result, the concentrations of $H_2S$ and $NH_3$ gases before the construction were 123.51ppm and 171.54ppm, respectively. These values were higher than TWA(Time Weighted Average) values. But the concentrations of $H_2S$ and $NH_3$ gases after the construction were 55.59ppm and 20.51ppm, and they also decreased 9.04ppm and 11.82ppm in 28 months. $CH_4$ and other landfill gases after the construction were little or a little detected in the landfill site. Hence we found out that concentrations or classes of landfill gases causing some problems extremely decreased by way of the stabilization.

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Working Environment and Risk Assessment of Gasoline in Workplace (Gasoline 취급 사업장의 작업환경 측정 및 위해성 평가)

  • Kim, Hyeon-Yeong
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.1-7
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    • 2014
  • To protect the workers' health, we evaluated the hazards of gasoline which the large amounts of use and lack of information, and perform the risk assessment through the measurement of working environment. It is estimated the reproductive toxicity, and has germ cell mutagenicity class 1B, also IARC 2B, ACGIH A3 with carcinogenicity. With working environment, it is measured as below the TLV-TWA $900mg/m^3$. It is also calculated $0.3mg/m^3$ as carcinogenicity RfC (worker), $2.7mg/m^3$ as chronic inhalation toxicity RfC (worker), $2.7mg/m^3$ as developmental toxicity RfC (worker). From all of these results, it is calculated that the risks are 459, 51 and 51 as carcinogenicity, chronic inhalation toxicity and developmental toxicity, respectively. It is concluded that the risk of gasoline is evaluated over 1.

Recommendation of an Occupational Exposure Limit and Legal Control Following an Acute Hepatotoxicity Incident from HCFC-123 (HCFC-123의 급성 독성간질환 발생 사례에 따른 노출기준 및 법 관리 필요성 권고)

  • Lee, Kwon Seob;Jo, Ji hoon;Choi, Bo Kyung;Lee, Hye Lim;Byeon, Sang Hoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.1
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    • pp.80-90
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    • 2018
  • Objectives: This study was performed to propose a domestic occupational exposure limit(OEL) following a health hazard assessment, calculation of a non-carcinogenicity reference concentration worker($RfC_{worker}$) value, and examination of international agencies' exposure limits. It also recommends legal management within the Occupational Safety and Health Act for HCFC-123, which caused an acute hepatotoxicity incident. Methods: An acute hepatotoxicity incident due to the fire extinguishing agent HCFC-123 was investigated. Toxicological hazard and health hazard classifications were examined and a non-carcinogenicity $RfC_{worker}$ value was calculated for HCFC-123. An OEL and the necessity of legal management were recommended as well. Results and Conclusions: An OEL for HCFC-123 of 10 ppm($62.5mg/m^3$), which considered the $RfC_{worker}$ value, 5.56 ppm, produced in dose-response assessment and the exposure level of 19.1-20.9 ppm measured as an eight-hour TWA(time-weighted average) in the incident place, is recommended. HCFC-123 is urged to be included as a chemical requiring legal management in the Occupational Safety and Health Regulations. In addition, it is recommended that a peak exposure of ACGIH be adopted in the Notice of the Ministry of Employment and Labor.

A Study on Metal Concentrations in the Air of Metal Products Manufacturing Industry (금속제품 제조 산업장내 공기중 금속농도에 관한 연구)

  • Kang, Yong Seon;Kim, Se Dong;Ku, Tae Hyeong;Yoon, Hyeong Ryeol;Moon, Deog Hwan;Han, Yong Soo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.6 no.2
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    • pp.249-264
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    • 1996
  • This study was conducted for the purpose of obtaining the fundamental data on improvement of working environment and contributing to health improvement of workers who dealed with metal by assessing the metal concentration in air of industries located in Chang-Won Industrial Complex. Authors measured the concentration of metals(Al, Cd, Cr, Cu, Mn, Ni, Pb, Sn and Zn) is the air to 25 working processes of 73 industries by flame atomic absorption spectrometry from February to December 1994. Personal air sampler was used for air sampling with mixed cellulose-ester membrane filter. The results were as follows : 1. The geometric means(range) of metal concentration; 1) Al: $0.1505mg/m^3$ ($0.0147-18.6100mg/m^3$) 2) Cd: $0.0077mg/m^3$ ($0.0003-7.0710mg/m^3$) 3) Cr: $0.0163mg/m^3$ ($0.0013-1.1510mg/m^3$) 4) Cu: $0.0097mg/m^3$ ($0.0009-0.4950mg/m^3$) 5) Mn: $0.0412mg/m^3$ ($0.0006-4.7877mg/m^3$) 6) Ni: $0.0088mg/m^3$ ($0.0001-1.0170mg/m^3$) 7) Pb: $0.0152mg/m^3$ ($0.0015-0.4499mg/m^3$) 8) Sn: $0.0486mg/m^3$ ($0.0037-0.1500mg/m^3$) 9) Zn: $0.1911mg/m^3$ ($0.0122-8.2920mg/m^3$) 2. The geometric mean of lead exceeded TWA in assembling process of other general purpose machinery not elsewhere classified products manufacturing industries.

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Real-time Remote Monitoring System of Chemical Accident Response based on Multi-hop Communication (멀티 홉 통신을 기반한 화학 사고 대응 실시간 원격 모니터링 시스템)

  • Lee, Seung-Chul;Kim, Nam-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.11
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    • pp.1706-1712
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    • 2022
  • Recently, the safety of chemical substances has gained attention due to incidents occurring in petrochemical industrial complexes, such as gas leaks and fires. In particular, industrial complexes in Ulsan and Yeosu (South Korea) are valuable as they significantly contribute to the petrochemical industry, but accidents may occur due to chemical leakage. Therefore, in this study, sensor nodes are configured at an interval of 20 [m] based on outdoor facilities standards to respond to chemical accidents, and exposure consideration of 8 h (TWA) and 15 min (STEL) are proposed in TLVs. The proposed system pre-processes data collected in multi-hop communication at a cycle of 0.6-0.75 [s] using Python and stores it in the MySQL database through SQL and a real-time remote monitoring system that updates the stored data once every 5 s is implemented by linking MySQL and Grafana.

작업환경을 위한 TLV의 근거 - TOLUENE-2.4 OR 2,6-DIISOCYANATE (or as a MIXTURE)(1)

  • Kim, Chi-Nyeon
    • 월간산업보건
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    • s.328
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    • pp.55-59
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    • 2015
  • 톨루엔-2,4-디이소시아네이트, 톨루엔-2,6-디이소시아네이트 각각 또는 두 이성체 혼합물(TDI)에 대하여 TLV-TWA는 0.005 ppm, TLV-STEL은 0.02 ppm으로 직업적 노출기준을 권고하고 있다. 본 수치는 호흡기에 대한 영향과 과민성 반응에 대한 높은 발생 가능성을 최소화하기 위한 것이다. 산업현장에서 증기상 TDI 물질은 점막, 호흡기계에 심한 자극을 일으켜 천식과 같은 증후군 등 급성 발작을 유발한다. 고농도에 노출시 심한 기관지 경련, 폐렴, 폐부종, 두통, 불면증과 기관지염으로 이어질 수 있다. TDI에 상당 부분 노출되면 대부분의 사람들은 위와 같은 건강 영향을 경험하게 된다. 심지어 처음 노출되었을 경우에도 발생된다. TDI 노출 관련 연구자들은 일반 근로자들이 0.02 ppm 수준 정도로 가끔 노출되는 경우 건강 영향을 받지 않으나, 0.02 ppm이 무영향 수준으로 간주될 수 있는 그 어떠한 증거도 없다고 결론을 내렸다. TDI에 일단 감작되면 몇몇 근로자들은 노출 중단 후에도 몇 년 동안 건강 영향 증세가 지속된다. 따라서 감작제 표기는 호흡 노출을 통한 알레르기성 감작 증세의 명확한 증거로서 권고된다. A4(비발암성 물질) 표기는 생쥐와 흰쥐들을 대상으로 수행된 위장관 투여 연구와 흡입 연구들을 통해 얻어진 동물 노출 데이터에 근거하여 설정되었다. 불충분한 데이터로 피부 표기는 권고되지 않았다.

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노출평가를 위한 TLV 근거 - 황산(SULFURIC ACID)(1)

  • Kim, Chi-Nyeon
    • 월간산업보건
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    • s.354
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    • pp.16-21
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    • 2017
  • 황산(sulfuric acid)에 대한 직업적 노출기준은 흉곽성 입자로 측정하여 TLV-TWA $0.2mg/m^3$으로 권고하였다. 이 기준은 기존의 호흡기 질환이 있는 개인의 폐 기능 감소 가능성을 최소화 하기 위한 것이다. 또한 이 노출기준은 황상 에어로졸에 노출된 후 동물과 사람 모두에서 발생하는 것으로 입증된 점액 섬모 간극의 변화를 최소화하는 수준이다. 강한 무기산 미스트에 함유된 형태로 작업장에서 황산에 노출되면 후두암과 관련이 있어 A2의 발암성 추정물질로 설정하였다. 납 축전지 공장 연구에 따르면 황산 에어로졸의 입자 크기는 일반적으로 $10{\mu}m$미만이었다. 따라서 흉곽성 입자 측정의 기준은 황산 에어로졸 노출로 후두암과 기도 관련 영향(즉, 기관지 정화작용 및 폐 기능 변화)에 대해 보홀할 수 있다. "피부(Skin)"와 감작제(SEN)" 경고주석을 지정하거나 TLV-STEL을 권고하기 위한 유용한 자료는 없다.

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Evaluation of Mechanical Properties in Bi-2223 Composite Superconducting Tapes (Bi-2223산화물 복합 초전도 테이프의 기계적 특성 평가)

  • 신형섭;최수용
    • Progress in Superconductivity and Cryogenics
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    • v.3 no.2
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    • pp.1-4
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    • 2001
  • For the practical use of a superconducting wire to magnet application, it is important to assess the Young modulus and other mechanical properties of HTS tapes. In order to establish a test method of mechanical properties for oxide composite superconductors. tensile tests of Bi-2223 multi- filamentary tapes were carried out at room temperature, as an activity of the International round robin test proposed by the committee of VAMAS/TWA 16-Subrgroup. The tapes consisting of mutli-filamentary showed a three stage tensile behavior. At the initial stage of the stress-streain curve. The elastic deformation existed in a quite nattrow strain region. But the plastic deformation was observed in a wide strain region due to the platic flow of the Ag alloy matrix. The results of RRT were also reported and discussed.

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Results of the First Round-Robin-Test for Evaluation of Mechanical Properties in Bi-2223 Composite Superconductors (산화물 복합초전도체(Bi-2223)의 기계적특성 평가를 위한 라운드로빈 시험 결과)

  • 신형섭
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2001.02a
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    • pp.13-16
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    • 2001
  • In the practical sense, it is important to assess the Young modulus and the degradation of $I_{c}$ due to mechanical deformation in HTS tapes for designing superconducting magnets. In order to establish a test method of mechanical properties in oxide composite superconductors, the committee of VAMAS/TWA 16-Subgroup proposed an international round robin test. The first effort has been focused on the multifilamentary Bi-2223 tapes. Eight groups participated in the RRT activity and each group carried out the tensile test by their own professional technique to three kinds of Bi-2223 tapes. The experimental details were reported and discussed for your information.

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A Statistical Assessment of Particulate Exposure Concentration for the Welders and Grinding workers (입자상 물질 폭로농도의 통계적 평가방법에 관한 고찰 -용접·연삭 작업장의 근로자를 대상으로-)

  • Yoon, Young-No;Yi, Kwan-Hyeong
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.1 no.2
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    • pp.154-163
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    • 1991
  • Particulate matter exposure leva1 of welders and grinding workers was evaluated in Banwol and Changwon industry complexes. Full period single sample and full period consecutive samples were collected with personal air samplers attached to workers. Compliance difference with 8-hour time weighted average (TWA) was compared by Korean strategy and the classification system recommended by OHSA for employee exposure to particulates. And difference of compliance was compared according to precision of measurement and analysis (total precision). Compliance rate was depended on the total precision, therefore, quality control of measurement and analysis was important.

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