• Journal of Environmental Health Sciences
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• v.24 no.2
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• pp.134-144
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• 1998

A comprehensive air quality monitoring was carried out to investigate the criteria concentration of air pollutant in indoor of subway stations of Seoul City. The samples were collected twice per year (the first and the second half of the year) at each sampling point from February to September in 1997. Sampling point of subway stations was ticket office and platform. The measurement of indoor air pollutants such as sulfur dioxide(SO$_2$), nitrogen dioxide(NO$_2$), carbon monoxide(CO), carbon dioxide(CO$_2$), total suspended particulate(TSP) was performed to determine the indoor air quality. Heavy metals(Pb, Cd, Cu, Cr, As, Hg) were also measured together with those air pollutants. The annual average concentration of CO$_2$ and TSP in subway stations were relatively high while those of heavy metals were within 10% of environmental recommended standard concentration in all stations. As results of regression analysis between line and line of air factors, the concentrations of CO, CO$_2$, TSP, Pb, Cd, Cr and Cu were highly correlated, but those of $SO_2, NO_2$ and Hg were not correlated. As results of regression analysis between ticket office and platform, the concentrations of heavy metals such as Cr and Cu were highly correlated. Results of oneway analysis of variance between the first and the second half of the year air factors also indicated that CO, CO$_2$, Cd, Cu, Hg were significant($\alpha$=0.01), respectively. The average contration of total suspended particulate(TSP) in subway line No. 1 was shown high concentration(200 $\mu g/m^3\cdot$ day) level.

• Journal of Environmental Health Sciences
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• v.26 no.2
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• pp.80-90
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• 2000

To determine the effect of air pollutants in Taejon City, we used medical insurance claim data for asthma and the data monitored from telemetry system of Ministry of Environment for air pollutants and meteorological factors. From November 1st, 1997 to October 31th, 1998, 95,629 asthma patients were covered by medical insurance at Taejon City. Subjects were composed of 49,563 males (51.8%) and 46.336 females(48.2%), and among the subjects, the proportion under 15 years old was 62.8% of the total. During the study period, daily mean concentrations of each air pollutants-So2, No2, CO, O3 and TSP-were 9.8 ppb, 17.6 ppm, 1.414 pp, 17.3 ppb and 60.6 $\mu\textrm{g}$/㎥, respectively, which were lower than each of the environmental recommended exposure levels, Through the simple correlation analysis between each air pollutants and meteorological factors, O3 was positively correlated with temperature, but negatively with relative humidity. TSP, SO2, NO2, CO were negatively correlated with meteorological factors, and these air pollutants except O3 were positively correlated with each other, O3 was correlated with TSP positively but the others negatively. Estimating relative risks of each air pollutant with the baseline general additive model, daily mean concentrations of TSP(Lag 0, 1, 4, 5day) were significantly associated with the increase of the asthma admission. Two age subgroups, under 15 and 15~54 have shown various association of all air pollutants concentration with the asthma admission. However, in case of over 54 age subgroup, only TSP(Lag 0 day) among all air pollutants was associated with the asthma admission. Each of ambient outdoor pollutant concentrations in Taejon City are significantly associated with the admission of asthma patients even though all concentrations in Taejon City are significantly associated with the admission of asthma patients even though all concentrations were much lower than the environmental recommended exposure levels. Therefore, continuous effort lowering air pollutant concentration and introducing an active environmental conservation policy should be implanted for preventing hazardous health effects. Considering major proportion of asthma admissions, high susceptibility and less confounding factors among the age subgroup under 15 will be a useful target population for assessing such health effect monitoring.

• Asian Journal of Atmospheric Environment
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• v.10 no.2
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• pp.90-98
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• 2016

Total suspended particulates (TSP) in the atmosphere were collected for 2 weeks during winter in Muroran, Hokkaido, Japan, a typical iron-manufacturing city. The concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in TSP were determined by high-performance liquid chromatography (HPLC) using fluorescence and chemiluminescence detectors, respectively. No relationship was observed between the atmospheric PAH and NPAH concentration, or the atmospheric PAH and TSP concentration. However, there was a tendency that the atmospheric PAH concentration was higher when the wind blew from the coke-oven plant. Furthermore, the concentration ratios of 1-nitropyrene to pyrene, which is a suitable indicator of the contribution made by automobiles and coal combustion systems to urban air particulates, were smaller in Muroran and the values were close to those observed in particulates from coal combustion systems. Therefore, these results show that the PAH and NPAH compositions for Muroran are characteristic of an iron-manufacturing city.

• Advances in environmental research
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• v.6 no.3
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• pp.189-202
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• 2017

This study examines the concentrations of particulate-phase polycyclic aromatic hydrocarbons (PAHs) and gas-phase PAHs in sidestream cigarette smoke. Sixteen PAHs were determined for four brands of cigarettes. The volume of the experimental room is approximately $66m^3$. The air samples in the room were collected before and after smoking. The median total of particulate-phase and gas-phase PAH concentrations before smoking $3.13ng/m^3$and $48.0ng/m^3$, respectively. The median concentrations of them after smoking were $10.0ng/m^3$ and $79.6ng/m^3$. The median increases in the total of 16 PAH concentrations per cigarette during smoking were 271 ng for the particulate-phase PAHs and 1960 ng for the gas-phase PAHs. According to the relationship between particulate-phase and gas-phase PAHs after smoking, the two- to four-ring gas-phase PAHs and the higher molecular weight particulate-phase PAHs were probably formed from similar precursors. The relationship between the total suspended particulate (TSP) concentration and the increase in the total particulate-phase concentration of the 16 PAHs per cigarette during smoking were significantly positive. The increase in the total gas-phase concentration of the 16 PAHs tended to increase as the TSP concentration increased. This may indicates that decreasing the amount of TSP produced inhibit the production of PAHs during smoking.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.4
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• pp.285-295
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• 2002

In this study, several types of gravimetric methods (such as high, medium, low, and ultra low volume sampling methods) were applied to determine suspended particulate matter concentrations in both ambient and indoor environments. Comparative evaluations were undertaken with SPM data obtained using a variety of samplers (TSP, PM10, and PM4.0) at different sampling flow rates. Correlation coefficients between TSP and PM10 concentrations measured at different flow rates fell in the range of 0.73∼0.94 (n=40). In addition, correlation coefficients for PM concentrations measured by different TSP samplers were in the range of 0.90∼0.95 (n=36 or n=38), while 0.77∼0.91 (n=38) for PM10 samplers. Correlation analysis was also conducted on indoor monitoring data that were measured using ultra-low-volume samplers at both different or identical flow rates. The correlation coefficients were in the range of 0.98∼0.99 (n=38) between TSP and TSP and 0.92∼0.94 (n=38) between TSP and PM10. The mean ratio for high volume PM10 to TSP concentration that was monitored at identical flow rates in the ambient air appeared to be 0.72. The mean ratios of PM10 to TSP and PM4.0 to TSP observed with identical flow rates at indoor environments were 0.47 and 0.40. The results of this study may provide empirical information concerning the compatability of aerosol data obtained by gravimetric sampling methods at different flow rates.

• Asian Journal of Atmospheric Environment
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• v.7 no.3
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• pp.169-175
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• 2013

Measurement of the phosphorus concentration in aerosols in Beijing, which was a representative East Asian mega-city, was carried out. The optimum procedure for analyzing phosphorus in aerosols was found in this study. Recovery of phosphorus in environmental samples through the improved method was almost 100%. The concentration of phosphorus in TSP was $145{\pm}47\;ng/m^3$, with a seasonal variation showing high concentrations in winter and low concentrations in summer. The concentrations of phosphorus in $PM_{2.5}$ accounted for $35{\pm}6%$ of those in TSP, with no seasonal variations. The major source of phosphorus in aerosols in Beijing was soil dust, and additional sources of phosphorus in fine particles could be coal combustion and biomass burning.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.5
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• pp.612-624
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• 2007

The real-time monitoring of radon ($^{222}Rn$) concentrations has been carried out to evaluate its ambient background concentration levels in Gosan site, Jeju Island between January 2001 and December 2004. In addition, the atmospheric TSP aerosols have been sampled, and their ionic and metallic components were analyzed to understand the characteristics of air pollution. The mean concentration of radon was $3,121{\pm}1,627\;mBq/m^3$, and the seasonal mean concentrations for spring, summer, fall and winter seasons were 2,898, 2,398, 3,571 and $3,646\;mBq/m^3$, respectively, The hourly concentrations have shown the highest value at 7 a.m. and the lowest value at 2 p.m. From the backward trajectory analyses, the radon concentrations have increased, when the air parcels were moved from the Chinese continent to Jeju area. On the other hand, they have decreased, when the air parcels from the North Pacific Ocean. In the analytical results of ionic species and metal elements of TSP aerosols, the concentrations of $nss-{SO_4}^{2-}$ and S were higher in June and March. Meanwhile, the concentrations of other anthropogenic species as well as soil components were mostly higher in March and April. On the basis of factor analysis, the TSP aerosols at Gosan area were largely influenced by soil sources, followed by anthropogenic sources and marine sources. From the result of backward trajectory analyses, the concentrations of $nss-{SO_4}^{2-},\;{NO_3}^-$, Al and Ca were mostly higher, when the air parcels moved from Chinese continent to Jeju area. On the other hand, their concentrations were lower, when the air parcels drifted from the North Pacific Ocean.

• Journal of Environmental Health Sciences
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• v.18 no.1
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• pp.12-21
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• 1992

This study was performed to determine the concentrations of airborne TSP, Pb and street dust Pb in Kuro, Chongro, Namsan Tollgate and kwachun from August 15 to September 15, 1990.The results of this study are as follows. 1. Average airborne TSP concentrations in chongro and Kuro were 460$\mu$g/m$^{3}$ and 440$\mu$g/m$^}3}$, respectively, and exceeded the Korean air quality standards of 300$\mu$g/m$^{3}$. Average airborne TSP concentrations in Namsan Tollgate and Kwachun were 270$\mu$g/m$^{3}$ and 80$\mu$g/m$^{3}$, respectively, and didn't exceeded the Korean air quality standards of 300$\mu$g/m$^{3}$. The airborne TSP concentrations between Seoul area(Kuro, Chongro and Namsan Tollgate) and Kwachun area were significantly different (p < 0.01). 2. Average airborne Pb concentrations in Chongro, Kuro, Namsan Tollgate and Kwachun were 1.07, 0.55, 0.84 and 0.16$\mu$g/m$^{3}$, respectively. All the airborne Pb concentration at four area were below the Korean air quality standards of 1.5$\mu$g/m$^{3}$. The airborne Pb concentrations between Seoul area (Kuro, Chongro and Narnsan Tollgate) and Kwachun area were significantly different (p < 0.01). 3. Pb contents in street dusts in Kuro, Chongro, Namsan Tollgate and Kwachun were 9.30, 15.25, 18.17 and 3.16$\mu$g/g, respectively. The Pb contents in street dusts between Seoul area(Kuro, Chongro and Namsan Tollgate) and Kwachun area were significantly different (p < 0.01). 4. The airborne TSP and Pb concentrations were highly correlated(r=0.68), but the Pb concentrations in street dusts and atmosphere were poorly correlated(r=0.22).

• Journal of Environmental Science International
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• v.3 no.4
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• pp.393-402
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• 1994

It is necessary to examine the source contributions and the relationship between a receptor and sources for the resonable controlling of air pollution level of suspended particulate matters. Therefore, in this study, profiles of sources contributing to the concentration of suspended particulate matters, were developed and CMB model was applied to obtain information of source contributions and feasibility of CMB model application. According to the propose of this study, twenty-seven chemical species such as the elements, anions, and total carbon of thirty-six PMl0 and TSP data sets sampled at the Pomch'on receptor site in Pusan for a 24-hr period from May to Aug. 1992, were analyzed and three (transportation, soil, marine) different source profiles were developed through the field measurement. Applying CMB model to transportation, soil, marine, the results of source contribution by CMB model showed that the case with TSP was more suitable for CMB model than that with PMl0. And the average contribution of transportation source to TSP and PMlo concentration at Pomch'on receptor was calculated as 90.66 ㎍/m3(64%) and 23.27 ㎍/m3(39%), resfiectively, which showed that the contribution by transportation was dominant. The validation of CMB model was performed by means of the results of contributions from marine source for the wind direction sectors.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.2
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• pp.233-243
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• 2018

This study was carried out to characterize the ambient levels of PAH concentrations in Pohang city, where steel industry has been intensively developed. A large amount of PAH emissions from steel production and related industries in Pohang are concerned about the environmental health hazards of nearby residents. TSP samples were seasonally collected during 10 days at four sites in Pohang from April to December 2010. Each sample was collected for 24 hours using high-volume air sampler. All samples were extracted by $soxtec^{TM}$ before concentration of 1.0 mL. The concentrates were analyzed by GC/MS. The prevailing wind direction was southwest and west-southwest in Pohang during the measurement period. Variations of TSP concentrations appeared to be similar between four sites. The highest TSP concentration was found in fall, while the lowest in summer. The highest PAH concentration was found at an industrial site, while the lowest at a residential/commercial site. In the case of BaP, the average concentration at the industrial site was $0.63{\pm}0.66ng/m^3$, which was approximately 2 times of the residential/commercial site. The paired t-test (p<0.05) showed significant differences between industrial and residential area. Particulate PAH concentrations were higher in the winter and lower in the summer. The concentrations of BaP in winter were 2~10 times higher than those in the other three seasons. This study clearly demonstrated the impact of steel industry on the elevated levels of PAH in Pohang city.