Journal of Korean Society for Atmospheric Environment
/
v.11
no.1
/
pp.37-44
/
1995
Concentration of particulate nitrate classified by formation mechanism and particle diameter in ambient air was determined from Feb. to Oct. 1993. Sampling was carried out using a two-stage Andersen air sampler at the top of a five-story building located at Kon-Kuk University in seoul. Concentration of N $H_{4}$N $O_{3}$ in TSP was measured by pyrolysis of sample filters at 160.deg.C for 1hr. concentration of N $H_{4}$N $O_{3}$ was higher in winter time compared with that in summmer time. Also, concentration of N $H_{4}$N $O_{3}$ was higher in fine particles compared with that in coarse particle. The range of N $H_{4}$N $O_{3}$ concentration was between 2.9 and 9.9.mu.g/ $m^{3}$. Weight fraction of N $H_{4}$N $O_{3}$ in total particulate nitrate was 31.1 .sim. 59.5%, and weight fraction of N $H_{4}$N $O_{3}$ in TSP was 2.1 .sim. 11.2%. Concentration of NaN $O_{3}$, which originated from sea salt, was highest in spring time and lowest in summer time,and the concentration range was between 0.1 and 0.7.mu.g/ $m^{3}$. NaN $O_{3}$/TSP ratio was very low (0.1 .sim. 0.4%) indicating that the portion of NaN $O_{3}$in TSP was negligible. Concentration of particulate nitrate originated from soil was 2.4 .sim. 2.9.mu.g/ $m^{3}$. Weight fraction of that in total particulate nitrate was 14.0 .sim. 37.1%.
Journal of Korean Society for Atmospheric Environment
/
v.14
no.1
/
pp.1-10
/
1998
Relationships between TSP and PM10 concentrations were evaluated using their respective data sets collected from Taegu and Kyeungsan areas during the period of December 1993 to November 1994. The collection of data was made using the gravimetric and $\beta$-ray absorption ($\beta$-MPM) methods for 7 days of every month from three urban sites in Taegu and one suburban site in Kyeungsan. Correlation coefficients between TSP and PM10 concentrations for these four sampling sites were found in the range of 0.85 $\sim$ 0.96. Correlation analysis was also conducted for $\beta$-PM concentration data that were measured only from the residential and commercial sites. The correlation coefficients between TSP and $\beta$-PM concentrations were 0.9 in the residential site and 0.8 in the commercial site. By contrast, the correlation coefficients between PM10 $\beta$-PM concentrations were almost identical for both the residential and commercial sites with a value of 0.88. The mean ratio for PM10 to TSP concentrations for all sites was appeared to be 0.68. The analysis of seasonal trends in PM10/TSP ratios showed that the contribution of PM10 to TSP concentrations was more significant during winter (0.70 $\sim$ 0.75) than during summer (0.61 $\sim$ 0.68). The results of this study may provide empirical informations on the compatability of aerosol data measured by different sampling methods.
Journal of Korean Society for Atmospheric Environment
/
v.10
no.1
/
pp.57-63
/
1994
In order to comprehension of the behaviour of PAHs in air which is known as carcinogens and/or mutagens suspended Particulates in ambient air were collected by Anderson air sampler from 1992. 6 to 1993. 5 in Seoul. Ten species of PAHs( Phen, An, Fl, R, Py, BaAn, BaP, Chry, BeP, DiB(a, h)An, I123p) were analyzed to understand monthly variations of PAHs distribution of PAHs concentration according to particle size, and correlation between PAHs and independent charactierstics of PAHs The highest concentration of TSP was 155.58$\mu\textrm{g}$/㎥ in May and the lowest was 60$\mu\textrm{g}$/㎥ in August. Concentration of TSP was more affected by coarse particles in spring, otherwise which was more affected by fine particles in winter. According to results of anaylsis of samples that were collected by Anderson air sampler, concentration of PAHs was more high in winter than that in summer. In almost samples collected by Anderson air sampler, concentration of PAHs was more high in coarse particles than in fine particles, but BaP well known as carcinogenic matter had more high concentration in fine particles(56-97.5%) than that in coarse particles(2.5-46%). Correlation between concentrations of TSP and PAHs was more high in fine Particles than in coarse Particles. Both fine particles and coarse particles have negative correaltion with radiation.
This study was performed to research the characteristics of suspended particulate for Yellow Sand of January, 1999 in Busan. Yellow Sand frequency during 13 years(1988~2000) in Busan showed maximum in April(57%), next to March(21%), May(16%). According to result of 850hPa weather map and backward isentropic trajectory, this event originated from the Gobi Desert and the Loess Plateau of China. And three mode was found in time series of TSP and PM10 concentration, primary peak showed the maximum hourly concentration at ali station. Gamjeondong as industrial site showed the highest TSP concentration and also had the longest high concentration($geq700\mu\textrm{g}/m^3$). In PM10, concentration of primary peak showed maximum value at Yeonsandong, maximum concentration of secondary and third peak was Deokcheondong. Lasted time from primary peak to secondary peak was about 30 hours, between secondary peak and third peak was 18 hours in Busan, The traveling time between occurrence of Yellow Sand the finding of it was 8~9 hours in Busan and 4~5 hours in central area.
This study was carried out to investigate total suspended particulates (TSP) in Iksan area collected by nine stages Anderson air sampler and High volume air sampler from Jul. 1996 to Jul. 1998.The results are as follows1. The average of TSP concentration to be collected by Anderson air sampler and High volume air sampler in Iksan city are $59{\mu}g/m^3$, $67{\mu}g/m^3$. It was below the level of environmental standard. 2. The average of TSP concentration by measured method are HVAS > AS > Gov. 3. The average of TSP concentration on seasonal change are higher spring than winter. It were $65.5{\mu}g/m^3$ of Spring, $57{\mu}g/m^3$ of Summer, $52.5{\mu}g/m^3$ of Fall, $61{\mu}g/m^3$ of Winter. 4. Particle size 3istribution of atmospheric particulate was divided into two groups, coarse group was made by particles larger than $1.1-2.1{\mu}m$ in diameter and fine groups smaller than $1.1-2.1{\mu}m$ in diameter. about 50% of total suspended particle measured by Anderson air sampler during the sampling period was coarse particle.
Journal of Korean Society for Atmospheric Environment
/
v.7
no.1
/
pp.17-22
/
1991
Total suspended particulates (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for one year (Mar. 1987 $\sim$ Feb. 1988) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulates was 200.44 $\mug/m^3$. The concentrations of heavy metals were 2433.80 for Fe, 629.49 for Zn, 600.71 for Pb, 143.87 for Cu, and 107.21 $ng/m^3$ for Mn, respectively. The concentrations of PAHs were 3.83 for benzo(a) pyrene, 2.95 for benzo(k)fluoranthene, and 4.42 $ng/m^3$ for benzo(ghi)perylene, respectively. PAHs, Pb and Zn abounded in particles below 2.0 $\mu$m, while Fe and Mn aboounded in particles above 2.0 $\mu$m. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic pollutants like TSP, PAHs and heavy metals in the fine particles were highest in winter and lowest in summer. PAHs and Pb analyzed showed significant correlations between each other and between TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.
This study was carried out to investigate the concentrations of TSP, Pb, Zn and Fe in ambient air adjacent to the heavy traffic road side in Seoul from October 1 to October 31, 1997. The results were as follows 1. The concentrations of TSP were 260 $\mu g/m^3$, 184 $\mu g/m^3$, 147 $\mu g/m^3$ in Chongro, Chungkechun and Kangnam-terminal, respectively. The concentration of TSP was correlated with the traffic volume of the sampling sites (r=0.77). 2. The concentrations of Pb were 638 ng/m$^3$, 335 ng/m$^3$, 233 ng/m$^3$ in Chungkechun, Kangnam-terminal and Chongro, respectively. The concentration of Pb was correlated with the Truck (over 1.4 ton) volume of the sampling sites (r=0.71). The Pb contents among these sites were significantly different (p < 0.05). 3. The concentrations of Zn were 535 ng/m$^3$, 461 ng/m$^3$, 439 ng/m$^3$ in Chongro, Kangnam-terminal and Chungkechun, respectively. The concentration of Zn was badly correlated with the traffic volume of the sampling sites (r=0.23). 4. The concentrations of Fe were 5.32 $\mu g/m^3$, 4.51 $\mu g/m^3$ and 3.18 $\mu g/m^3$ in Chongro, Kangnam-terminal and Chungkechun, respectively. The concentration of Fe was correlated with the traffic volume of the sampling sites (r=0.83). The Fe contents among these sites were significantly different (p < 0.05). 5. The concentrations of TSP, Pb, Zn, Fe investigated didn't exceed the Korean Ambient Air Quality Standards, but more researches in relation to these will be required in considering people working in these sites suffered from cough, asthma and chronic headache.
Journal of Korean Society for Atmospheric Environment
/
v.4
no.1
/
pp.79-83
/
1988
To improve working environment for the toll workers who were working at Kyungbu expressway in outskirts of Seoul and Suwon, the status of air pollution surrounding toll booth were measured from March 28 through June 14, 1986. The results were as follows: 1. The amount of TSP (total suspended particle) surrounding toll booth was directly proportional to the traffic load. The ratio of traffic load at Seoul and Suwon toll was 3.2:1 and of TSP was 2.6:1. 2. The proportion of particle larger than 5$\mum$ was 24.8 $\sim$ 34.9% of TSP at Seoul toll and 19.2 $\sim$ 32.7% at Suwon. The proportion of particle less than 2$\mum$ was 38.7 $\sim$ 51.8% of TSP at Seoul toll and 34.8 $\sim$ 54.8% at Suwon. 3. The concentration of respirable particle les than 7$\mum$ measured by personal air sampler was higher in Seoul toll booth than that of Suwon and it seems to be influenced by the exhausion of diesel engine. Especially the concentration of respirable particle of reformed toll booth with air curtain was 20% lower than unreformed one. 4. Concentration of Pb among suspended particles around Seoul toll was 5 times higher than Pb of Suwon toll. So it is considered that there were other possible pollution source of Pb beyond heavy traffic in Seoul toll area. The amount of Pb inside toll booth was extremely small but the concentration of benzo(a)pyrene showed a trend of increase according to traffic stagnation. 5. The concentration of $SO_2$ arround toll showed no difference between weekday and weekend and also showed no relation with traffic load. But the concentration of $NO_2$ was affected by traffic load.
The airborne concentrations of Sulfur Dioxide and Total Suspended Particulates were investigated in 4 subway lines in Seoul at early summer, 1990 and early summer, 1991. The results of the study were as follows: 1. The airborne concentrations of SO$_2$ and TSP were 0.022 ppm, 445.7 $\mu$g/m$^3$ respectively. And percents of over annual air quality standard of WHO was that SO$_2$ and TSP were 41.7%, 100% respectively. 2. Airborne SO$_2$ concentrations by subway lines were that line 1 was 0.025 ppm, line 2 was 0.023 ppm, line 3 was 0.020 ppm, and line 4 was 0.017 ppm. And TSP concentrations by subway lines were that line 2 was 533.8 $\mu$g/m$^3$, line 1 was 516.5 $\mu$g/m$^3$, line 4 was 371.6 $\mu$g/m$^3$, and line 3 was 369.3 $\mu$g/m$^3$ 3. Annual variation of concentration of TSP was not significant statistically (t=0.327), and that of SO$_2$, in 1990 was slightly higher than that in 1991 (t=1.433, p<0.1). 4. Coefficients of correlation between TSP and SO$_2$ by years were that early summer, 1990 was r=0.277 (p>0.1), and early summer, 1991 was r=0.32 (p>0.1).
This study was aimed to investigate the influence on the vicinity by air pollutant generated from facility of the district heating located in local small town. We selected the seven areas arround the surroundings of facility of the district heating, compared the air quality evaluated before and after operations of the facility, and estimated the diffusion of air pollutant exhausted from the facility using a ISC model. The result was that the concentration of TSP before and after operations of the facility was 89${\sim}$94${\mu}$g/m$^3$,and 72${\sim}$81${\mu}$g/m$^3$, respectively and the latter showed a decline in concentration. Also, there was no relationship between straight distance from the facility of the district heating and the concentration of TSP. This result was applicable to cases of PM-10 and SO$_2$. We also investigated the influence on the air around the neighbored area by air pollutant produced from facility of the district heating using ISCLT3 model. The adding-concentrations of TSP, SO$_2$,NO$_2$, and CO were 0.0019${\sim}$0.00183${\mu}$g/m$^3$, 0.0029${\sim}$0.5648ppb, 0.2924${\sim}$l.9837ppb,and 0.0087${\sim}$0.0590ppb, respectively. It is predicted that each concentration is added to pollutant exhausted from facility of the district heating and is about 1/100${\sim}$1/180,000 of present air quality. This has a tiny influence on general air quality. According to this analysis, the concentration of air pollutant is less effected to pollutants expected by the facility of the district heating than other pollutants emitted from mobil source or industrial complex, and etc.
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