• Journal of Environmental Science International
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• v.3 no.4
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• pp.357-365
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• 1994

Air pollution characteristics and the influence of sea breeze on air pollution concentration were studied using the data measured at 7 air quality continuous monitoring stations in Pusan, 1993. Maximum air pollution concentration in Pusan was Gamjeondong for $SO_2$, Sinpyeongdong for TSP, Daeyeondong for $O_3, Kwangbokdong for $NO_2$, Beomcheondong for CO and all substances were under annual ambient air quality standards. Increased rate of concentration for sea breeze was 24.4% for 502, 31.5% for TSP, 8.0% fort $O_3, 26.7% for $NO_2$, 15.7% for CO. Frequencies distribution of $SO_2$, TSP, $O_3$, $NO_2$, and CO concentration for sea breeze moved toward high concentration class.

• Journal of Korean Society for Atmospheric Environment
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• v.10 no.2
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• pp.130-136
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• 1994

Concentration of volatile particulate nitrate(NH$_4$NO$_3$) in TSP in ambient air was determined from Feb. to Oct 1993. Sampling was carried out using a two-stage Andersen air sampler at the top of a five-story building located at Kon- Kuk University in Seoul Concentration of NH$_4$NO$_3$ in TSP was measured by Pyrolysis of sample filters at 16$0^{\circ}C$ for 1hr. Concentration of NH$_4$NO$_3$ was higher in winter time compared with that in summer time. Also, concentration of NH$_4$NO$_3$ was higher in fine particles compared with that in coarse particle. The range of NH$_4$NO$_3$concentration was between 2.99 and 9.86 $\mu\textrm{g}$/㎥. Weight fraction of NH$_4$NO$_3$ in total particulate nitrate was 31.1~59.5%, and weight fraction of NH$_4$NO$_3$ in YSP was 2.1~11.2%.

• Journal of Environmental Health Sciences
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• v.17 no.1
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• pp.20-31
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• 1991

• Journal of environmental and Sanitary engineering
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• v.14 no.2
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• pp.68-74
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• 1999

The atmospheric concentrations of Nitrogen Dioxide ($NO_2$) and Total Suspended Particulates (TSP) at the traffic road side were measured n Asan area, Choongchumg-namdo during May 1998 and January, 1999.The results of the study are as follows;1. The aversge value of airbone $NO_2$ and TSP levels were 28.5ppb and 5.9mg/me in Asan area. 2. The concentration distribution of NO2 and TSP is high for the season of winter. On a daily pattern, somewhat high value is appeared in the afternoon. 3. For the station, terminal, and Shinchang, the average value of $NO_2$ is 33.6ppb, 27.9ppb and 24.1ppb in sequence, and the ones of TSP is 6.3mg/m3, 6.0mg/m3 and 5.3mg/m3 in order.4. The high levels of $NO_2$ and TSP were positively related to traffic volume.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.3
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• pp.348-356
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• 2012

It is very important to investigate air pollutants and emissions emitted from open burning in order to control nonpoint sources effectively. In this study, we utilized incineration simulator proposed by U.S. EPA and investigated concentrations of TSP, PM10, PM2.5 from woods and household wastes burning to calculate emission factors and build emission inventories. The results of experiment with 15 kg of woods and 3 kg of household wastes using the incineration simulator were as follows: in case of woods burning, TSP concentration was $66.4mg/m^3$, PM10 concentration was $28.4mg/m^3$, PM2.5 concentration was $17.9mg/m^3$, respectively; in case of household wastes burning, TSP concentration was $118.4mg/m^3$, PM10 concentration was $66.8mg/m^3$, PM2.5 concentration was $55.2mg/m^3$, respectively. Concentrations from household burning, as stated above, were higher than those from woods burning. Emission factors (EFs) for woods and household wastes burning were calculated as 2.45 and 6.75 g/kg for TSP, 0.86 and 5.45 g/kg for PM10, 0.78 and 4.81 g/kg for PM2.5, respectively. EFs of TSP, PM10, PM2.5 calculated from household wastes burning were higher than those of woods burning. When we added PM emissions from woods burning and household wastes burning to Korean National Emission Inventory named as Clean Air Policy Support System (CAPSS), CAPSS annual emissions of TSP, PM10, PM2.5 were increased by 0.08~0.26% (An increase rate for TSP, PM10, PM2.5 were 0.08~0.10%, 0.16~0.20% and 0.18~0.26%, respectively). Note that we assumed that the 1% of household wastes is emitted by open burning.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.5
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• pp.469-476
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• 2000

This study was performed to understand the behavior and source characteristics of particulate trace metals in Daegu area. To do this, total of 84 samples had been collected from January to December 1999. TSP (total suspended particulate matter) and PM-10(particulate matter with aerodynamic diameters less 10${\mu}{\textrm}{m}$) were collected by filters on portable air sampler, and in TSP and PM-10 were analyzed by ICP(Inductively Coupled Plasma Spectrometer) after preliminary treatment. The results were follow as: first, annul means of TSP and PM-10 concentration were 123 and 69$\mu\textrm{g}$/㎤ respectively. The concentration of TSP adn PM-10 were highest in winter season compared to other seasons. Second, the concentration of Al, Fe, Mn were higher in TSP than in PM-10, indicating that these metals are generally associate with natural contributions. Third, a hierarchical clustering technique was used to group 9 metals. The results from the cluster analysis of TSP and PM-10 shows a similar clustering pattern : Fe, Al in a group and the rest of the metals such as Ni, Cr, As, Mn, Cd, Pb, Zn in the other group. One group of metal such as Fe, Al is associated with natural sources such as soil and dust. The other is closely related to urban anthropogenic sources such as fuel combustion, incineration, and refuse burning, Finally, using Al as a reference element, enrichment factors were used for identifying the major particulate contributors. The enrichment factors of Al. Fe<10 (standard value of enrichment factor) were considered to have a significant dust and soil source and termed nonenriched. Ni, Cr, As, Mn, Cd, Pb, Zn》10 is enriched and has a significant which is contributed by athropogenic sources.

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1440-1448
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• 2014

Co(II)-tetrasulfonated phthalocyanine (CoTSP) is known to be aggregated to dimer at high concentration levels in water. A study on the aggregation of CoTSP using multivariate curve resolution analysis of the visible absorbance spectra over a concentration range of 30, 40 and 50 ${\mu}M$ in the presence of dimethyl sulfoxide (DMSO), dimethyl formamide (DMF), acetonitrile (AN) and ethanol (EtOH) in the concentration range of 0 to 3.57 M is conducted. A hard modeling-based multivariate curve resolution method was applied to determine the dissociation constants of the CoTSP aggregates at various temperatures ranging from 25, 45 and $65^{\circ}C$ and in the presence of various co-solvents. Dissociation constant for aggregation was increased and then decrease by temperature and concentration of phthalocyanine, respectively. Utilizing the vant Hoff relation, the enthalpy and entropy of the dissociation equilibriums were calculated. For the dissociation of both aggregates, the enthalpy and entropy changes were positive and negative, respectively. Molecular dynamics simulation of cosolvent effect on CoTSP aggregation was done to confirm spectroscopy results. Results of radial distribution function (RDF), root mean square deviation (RMSD) and distance curves confirmed more effect of polar solvent to decrease monomer formation.

• Journal of Environmental Health Sciences
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• v.22 no.4
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• pp.43-48
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• 1996

Indoor air quality(IAQ) in museum is very important for protection of cultural properties. In our study, we measured air pollutants($NO_x, NH_3, SO_2, O_3$, CO, $CO_2$, TSP), temperature and humidity to evaluate IAQ of national central museum. Indoor carbon dioxide and TSP concentrations were higher than outdoor concentrations. Temperature, huinidity and TSP had large deviation depending on air conditioning operates or not. Indoor gas phase pollutants except $CO_2$ were lower than outdoor concentrations, but $SO_2$ concentration was high in storage. $CO_2$ and TSP were influenced by the number of spectators.

• Journal of Environmental Science International
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• v.5 no.4
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• pp.453-462
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• 1996

This study was conducted to evaluate the level of atmospheric heavy metals and the relationship of that concentration with weather conditions. This research monitored the concentration of Total Suspended Particulates (TSP) at every three hours by using High Volume Air Sampler from December 24th, of 1995 to Febuary 20th, 1996 in Kimhae area, which recently became a rapidly growing residential and industrial sitc. The items such as air-temperature, relative humidity, radition, wind speed, and wind direction were monitored by using Atmospheric Weather System at the same time. From the collected TSP, the concentration of heavy metals were analyzed by using the Atomic Absorption Spcetrophotometry. The mean concentration of TSP was 110.4 $\mu\textrm{g}$/$m^3$, and the mean concentration of lead (Pb), copper(Cu), chromium (Cr), manganese (Mn), cadmium (Cd), were 0.837 $\mu\textrm{g}$/$m^3$, 0486 $\mu\textrm{g}$/$m^3$, 0.264$\mu\textrm{g}$/$m^3$). The concentration of Pb and Mn was higher in the moring and that of Cu, Cr and Cd was higher in the afternoon and the evening. Regarding the relationship between the concentration of pollutants and weather condition, the-concentration TSP revealed positive correlation with temperature, humidity, wind speed, but negative correlation with tradition (p<0.01). The concentration of Mn revealed positive correlation with temperature and humidity, but negative correlation with wind speed (p<0.01). And the the concentration of pollutants and weather condition revealed higher correlation within the same time period. In summary, the paralleled mornitoring of air conditions and weather condition should be recommended to. get the correct informations concerning the pollution and to prevent the deterioration of air conditions.

• Journal of Preventive Medicine and Public Health
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• v.27 no.3 s.47
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• pp.505-516
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• 1994

For the purpose of preparing the fundamental data on air pollution in underground shopping center and also contributing to the health improvement of residents, the authors measured the level of $SO_2,\;NO_2,\;TSP,\;CO,\;CO_2$ and also some related factors as air temperature, air movement, relative humidity and mean radiation temperature at inside and outside of underground shopping center in Pusan from January to February and from July to August 1994. The results were as follows : 1. The mean concentration of CO within the underground shopping center was $3.1{\pm}1.3ppm$ in winter and $2.1{\pm}0.9ppm$ in summer. There was a negative correlation (p<0.01) between inner CO concentration and temperature in summer and no correlation between inner CO concentration and outer CO concentration in underground shopping center 2. The mean concentration of COE within the underground shopping center was $876{\pm}353ppm$ in winter and $757{\pm}125ppm$ in summer. There was a negative correlation (p<0.01) between inner $CO_2$ concentration and air movement in summer and positive correlation (p<0.05) between inner $CO_2$ concentration and outer $CO_2$ concentration in underground shopping center. 3. The mean concentration of $SO_2$ within a underground shopping center was $0.036{\pm}0.019ppm$ in winter and $0.040{\pm}0.013ppm$ in summer. There was a positive correlation(p<0.01) between inner $SO_2$ concentration and temperature in summer and positive correlation between inner $SO_2$ concentration and outer $SO_2$ concentration in summer and winter in underground shopping center. 4. The mean concentration of $NO_2$ within a underground shopping center was $0.052{\pm}0.038ppm$ in winter and $0.042{\pm}0.016ppm$ in summer. There was a no correlation between inner $SO_2$ concentration and thermal factors in summer and winter and low correlation between inner $SO_2$ concentration and outer $SO_2$ concentration in underground shopping center 5. The mean concentration of TSP within a underground shopping center was $430{\pm}214{\mu}g/m^3$ in winter, $366{\pm}73{\mu}g/m^3$ in summer, and very in excess of the atmospheric environmental quality standards of Korea ($150{\mu}g/m3{\downarrow}$). There was low correlation between inner TSP concentration and temperature in summer and high correlation between inner TSP concentration and outer TSP concentration in underground shopping center.