• Journal of Environmental Health Sciences
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• v.24 no.2
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• pp.134-144
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• 1998

A comprehensive air quality monitoring was carried out to investigate the criteria concentration of air pollutant in indoor of subway stations of Seoul City. The samples were collected twice per year (the first and the second half of the year) at each sampling point from February to September in 1997. Sampling point of subway stations was ticket office and platform. The measurement of indoor air pollutants such as sulfur dioxide(SO$_2$), nitrogen dioxide(NO$_2$), carbon monoxide(CO), carbon dioxide(CO$_2$), total suspended particulate(TSP) was performed to determine the indoor air quality. Heavy metals(Pb, Cd, Cu, Cr, As, Hg) were also measured together with those air pollutants. The annual average concentration of CO$_2$ and TSP in subway stations were relatively high while those of heavy metals were within 10% of environmental recommended standard concentration in all stations. As results of regression analysis between line and line of air factors, the concentrations of CO, CO$_2$, TSP, Pb, Cd, Cr and Cu were highly correlated, but those of $SO_2, NO_2$ and Hg were not correlated. As results of regression analysis between ticket office and platform, the concentrations of heavy metals such as Cr and Cu were highly correlated. Results of oneway analysis of variance between the first and the second half of the year air factors also indicated that CO, CO$_2$, Cd, Cu, Hg were significant($\alpha$=0.01), respectively. The average contration of total suspended particulate(TSP) in subway line No. 1 was shown high concentration(200 $\mu g/m^3\cdot$ day) level.

• Journal of Environmental Science International
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• v.3 no.4
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• pp.393-402
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• 1994

It is necessary to examine the source contributions and the relationship between a receptor and sources for the resonable controlling of air pollution level of suspended particulate matters. Therefore, in this study, profiles of sources contributing to the concentration of suspended particulate matters, were developed and CMB model was applied to obtain information of source contributions and feasibility of CMB model application. According to the propose of this study, twenty-seven chemical species such as the elements, anions, and total carbon of thirty-six PMl0 and TSP data sets sampled at the Pomch'on receptor site in Pusan for a 24-hr period from May to Aug. 1992, were analyzed and three (transportation, soil, marine) different source profiles were developed through the field measurement. Applying CMB model to transportation, soil, marine, the results of source contribution by CMB model showed that the case with TSP was more suitable for CMB model than that with PMl0. And the average contribution of transportation source to TSP and PMlo concentration at Pomch'on receptor was calculated as 90.66 ㎍/m3(64%) and 23.27 ㎍/m3(39%), resfiectively, which showed that the contribution by transportation was dominant. The validation of CMB model was performed by means of the results of contributions from marine source for the wind direction sectors.

• YAKHAK HOEJI
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• v.34 no.1
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• pp.1-10
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• 1990

Total suspended particulate (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for the past two years (Mar. 1987-Feb. 1989) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulate was $229.48\;{\mu}g/m^3$. The concentrations of heavy metals were $2971.94\;ng/m^3$ for Fe, $767.75\;ng/m^3$ for Zn, $765.80\;ng/m^3$ for Pb, $218.40\;ng/m^3$ for Cu, $129.91\;ng/m^3$ for Mn, respectively. And the concentration of PAHs were $3.23\;ng/m^3$ for benzo(a)pyrene, $2.71\;ng/m^3$ for benzo(k)fluoranthene, $4.53\;ng/m^3$ for benzo(ghi)perylene, respectively. The mass-size distribution of TSP was lowest in the particle size range $1.1-3.3\;{\mu}m$ increased as the particle size increased or decreased. But PAHs, Pb and Zn abounded in particles below $2.0\;{\mu}m$, while Fe and Mn abouned in particles above $2.0\;{\mu}m$. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic origin like TSP, PAH and heavy metals in the fine particles were highest in winter and lowest in summer. PAH and Ph analyzed showed significant correlations with each other and with TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.

• Journal of Korean Society for Atmospheric Environment
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• v.8 no.1
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• pp.20-28
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• 1992

The x-ray fluorescence(XRF) is one of the most convenient and widely used techniques for analyzing trace elements in ambient particulate matters. The objects of the study were to estimate the optimum exposure time using the XRF, to investigate the distributions of heavy metal levels in particulate matters, and finally to study seasonal variation for the concentrations of total suspended particulate matters(TSP) and size fractionated particulate matters. The suspended particulate matters had been collected by a cascade impactor having 9 size fragnated stages for 3 years(Dec. 1988 to Nov. 1991) in Kyung Hee University-Suwon Campus. The particulate matters were then collected on each stage by membrane filters. The weight concentrations were determined by the XRF system. Thus, seasonal variations and relationship between concentration and particle size could be investigated. Resulting distribution was bimodal with the coarse and the fine particle groups minimum occurring around 2.1 to 3.3 $\mu$m as an aerodynamic diameter. To determine optimum exposure time of the XRF for various trace inorganic elements, membrane filters and the NIST standard filters were extensively studied. Using a statistical technique, optimum exposure time was estimated for each trace element and overall elements. The time was then determined as 20 seconds for the XRF system. The concentration of TSP was 123.9$\mum/m^3$ on an arithmatic average. The levels of each inorganic metal were Si 2420.0ng/$m^3$, Fe 977.1ng/$m^3$, and so on. The Pb. Zn, and Cu abounded in the fine mode group, while Ca, Fe, Si, Al, and K in the coarse group. Marked seasonal variation of TSP and metal concentrations was observed. The concentration of heavy metals in the fine mode was highest in winter : on the other hand, that in the coarse mode was highest in spring.

• Journal of Environmental Science International
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• v.5 no.2
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• pp.113-130
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• 1996

Diurnal variations of air quality for each season over Taeau city were analyzed using the characteristic features of the various synoptic wind fields. The air quality data which were monitored by four stations are the hourly averaged sulfur dioxide($SO_2$), total suspended particulate(TSP) and oxidants ($O_3$) during the period of 1989 to 1992. The various synoptic wind fields obtained from the 850 hPa geopotential height were divided in to four geostrophic wind directions and two geostrophic wind speeds for each seasons. The synoptic weather conditions were again subdivided info two categories using the lotal cloud amounts, The results shows that diurnal and seasonal variations of the air quality over Taegu city, such as sulfur dioxide, total suspended particulate and oxidants reseal the various characteristics under the same synoptic weather conditions.

• Journal of environmental and Sanitary engineering
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• v.14 no.4
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• pp.158-164
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• 1999

This study was carried out to investigate total suspended particulates (TSP) in Iksan area collected by nine stages Anderson air sampler and High volume air sampler from Jul. 1996 to Jul. 1998.The results are as follows1. The average of TSP concentration to be collected by Anderson air sampler and High volume air sampler in Iksan city are $59{\mu}g/m^3$, $67{\mu}g/m^3$. It was below the level of environmental standard. 2. The average of TSP concentration by measured method are HVAS > AS > Gov. 3. The average of TSP concentration on seasonal change are higher spring than winter. It were $65.5{\mu}g/m^3$ of Spring, $57{\mu}g/m^3$ of Summer, $52.5{\mu}g/m^3$ of Fall, $61{\mu}g/m^3$ of Winter. 4. Particle size 3istribution of atmospheric particulate was divided into two groups, coarse group was made by particles larger than $1.1-2.1{\mu}m$ in diameter and fine groups smaller than $1.1-2.1{\mu}m$ in diameter. about 50% of total suspended particle measured by Anderson air sampler during the sampling period was coarse particle.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.5
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• pp.469-476
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• 2000

This study was performed to understand the behavior and source characteristics of particulate trace metals in Daegu area. To do this, total of 84 samples had been collected from January to December 1999. TSP (total suspended particulate matter) and PM-10(particulate matter with aerodynamic diameters less 10${\mu}{\textrm}{m}$) were collected by filters on portable air sampler, and in TSP and PM-10 were analyzed by ICP(Inductively Coupled Plasma Spectrometer) after preliminary treatment. The results were follow as: first, annul means of TSP and PM-10 concentration were 123 and 69$\mu\textrm{g}$/㎤ respectively. The concentration of TSP adn PM-10 were highest in winter season compared to other seasons. Second, the concentration of Al, Fe, Mn were higher in TSP than in PM-10, indicating that these metals are generally associate with natural contributions. Third, a hierarchical clustering technique was used to group 9 metals. The results from the cluster analysis of TSP and PM-10 shows a similar clustering pattern : Fe, Al in a group and the rest of the metals such as Ni, Cr, As, Mn, Cd, Pb, Zn in the other group. One group of metal such as Fe, Al is associated with natural sources such as soil and dust. The other is closely related to urban anthropogenic sources such as fuel combustion, incineration, and refuse burning, Finally, using Al as a reference element, enrichment factors were used for identifying the major particulate contributors. The enrichment factors of Al. Fe<10 (standard value of enrichment factor) were considered to have a significant dust and soil source and termed nonenriched. Ni, Cr, As, Mn, Cd, Pb, Zn》10 is enriched and has a significant which is contributed by athropogenic sources.

• Journal of Environmental Health Sciences
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• v.29 no.1
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• pp.67-73
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• 2003

This study was carried out to characterize the behavior and sources of particulate trace metal in Daegu city. TSP (Total Suspended Particulate matter) was collected by filters on High Volume Air Sampler from the four areal (reference, residential, commercial, industrial area). The moult were analyzed by AAS after preliminary treatment. The average centration trend of trace metals contained in TSP was shown as follows : Fe > Cu > Pb > Mn > Ni > Cr > Cd. The trace metals showed the highest concentration in the industrial area. This study showed the seasonal variation of trace metals. Fe and Mn showed high concentration in spring, whereas Cr, Ni, Cd and Pb showed high concentration in winter. Also this study showed the regional variation of trace metals. The order of the average concentration of trace metals was : industrial > commercial > residential > reference area. Using Mn as a reference element, the enrichment factor analysis were used for identifying the trace element contributors. The enrichment factors of Cr, Fe < 10 were considered to have a significant dust and soil source and termed nonenriched. Pb, Cd, Cu >>10 were enriched and had a significant fraction which was contributed by anthropogenic sources.

• Journal of Preventive Medicine and Public Health
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• v.31 no.1 s.60
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• pp.82-90
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• 1998

A large number of studies have indicated associations between particulate air pollution and daily mortality. Daily measurements of total suspended particulates (TSP) by high volume air sampler were matched to daily death counts supplied by the National Statistics Office, Korea. All deaths, except deaths from accidents, occurred at Ulsan from 1 January 1991 to 31 December 1994 were considered in the poisson regression analysis. The multiple regression models were used to investigate a main effects of air particulate pollution controlling for $SO_2$ levels, air temperature, relative humidity, seasonal variation, and calendar year. The results indicated that the effects of TSP, $SO_2$, temperature, and relative humidity were not significantly associated with all cause mortality. It could, however, be emphasized that the size of the parameter estimate of TSP was very similar to that of previous studies. An increase in particulates of $100{\mu}g/m^3$ was associated with a 3% increase in mortality. This relationship was observed at TSP levels well below the current National Ambient Air Quality Standard of $150{\mu}g/m^3$ in Korea as well.

• Korean Journal of Poultry Science
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• v.20 no.1
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• pp.11-15
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• 1993

Environmental measurements were made in 10 broiler confinement houses in order to characterize dust contaminants. Particles were collected by filters on nine stages Anderson Air Sampler, The obtained results were summarized as follows ; 1. The concentrations of the total suspended particles(TSP) were 7.584 mg/$m_3$~11.589mg/$m_3$ in 10 day old broiler houses and 15.836 mg/$m_3$~22.471 mg/$m_3$ in 30 day old broiler houses. 2. The concentrations of the coarse particles were 4.974 mg/$m_3$~18.981 mg/$m_3$ in 10 broiler confinement houses. Therefore, it was found that the coarse particles contributed to TSP between 65.6% and 85.0%. 3. The dust levels were higher in 30 day old broiler houses with TSP averaging about 19.341 mg/$m_3$ than 9.491 mg/$m_3$ in 10 day old broiler houses. In view of the above results , It was concluded that domestic broiler houses need artificial ventilation system.