• Bulletin of the Korean Chemical Society
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• v.19 no.11
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• pp.1175-1179
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• 1998

The aerobic reaction of 2-(acetylpyridine)-S-methyldithiocarbazate (acpy-mdtcH) and 2-(acetylpyridine)-N-phenylthiosemicarbazate(acpy-phTscH) with manganese(Ⅱ) acetate affords Mn(acpy-mdtc)2 and Mn(acpyphTsc)2, respectively. The spectroscopic data and X-ray structure of Mn(acpy-mdtc)2 are reported. Crystal data for Mn(acpy-mdtc)2; C18H20N6S4Mn, mol wt 503.58, monoclinic crystal system(P21/c) a=12.240(5) Å, b= 10.918(l) Å, c=17.651(3) Å, β=105.93(2), and V=2268(l) Å3, Z=4, 5071 data collected with 0°< 2θ < 52.64°, 2995 data with I > 3σ(I), R= 0.046, Rw= 0.065. The ligands act as tridentate NNS donors. The two Mn-S distances are not equal, and respectively 2.512(2) Å and 2.541(2) Å. The average Mn-N (azomethine) length, 2.242(5) Å, is slightly shorter than the average Mn-N (pyridyl) length, 2.262(5) Å. The coordination environment about MN(Ⅱ) center deviates considerably from octahedral geometry. The manganese(Ⅱ)-manganese(Ⅰ) and manganese(Ⅰ)-manganese(0) reduction potentials of Mn(acpy-mdtc)2 are ∼-l.71 and ∼-l.98 V while those of Mn(acpy-phTsc)2 are ∼-l.87 and ∼-2.11 V vs. Ag/Ag+ in dimethyl sulfoxide, respectively.

• Earthquakes and Structures
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• v.25 no.4
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• pp.235-247
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• 2023

Bingöl, a city in eastern Türkiye, is located at a very close distance to the Karlıova Region which is a junction point of the North Anatolian Fault Zone and Eastern Anatolian Fault Zone. By bilateral step over of North Anatolian Fault Zone and Eastern Anatolian Fault Zone each other there occurred NorthWest-SouthEast extended right-lateral and NorthEast-SouthWest extended left-lateral fault zones. In this paper, a typical school building located in Bingöl Çeltiksuyu was selected as the case study. Information on the school building and Bingöl Earthquake (2003) have been given in the paper. This study aimed to determine the fragility curves of the school building according to HAZUS 2022, Turkish Seismic Codes 1998, 2007 and 2018. These codes have been introduced in terms of damage limits. Incremental dynamic analysis is a parametric analysis method that has recently emerged in several different forms to estimate more thoroughly structural performance under seismic loads. Fragility analysis is commonly using to estimate the damage probability of buildings. Incremental Dynamic Analysis have performed, and 1295 Incremental Dynamic Analysis output was evaluated to obtain fragility curves. 20 different ground motion records have been selected with magnitudes between 5.6M and 7.6M. Scaling factors of these ground motions were selected between 0.1g and 2g. Comparison has been made between HAZUS 2022 and Turkish Seismic Codes 1998, 2007 and 2018 in terms of damage states and how they affected fragility curves. TSC 1998 has more conservative strictions along with TSC 2018 than TSC2007 and HAZUS moderate and extensive damage limits.

• The Journal of The Korea Institute of Intelligent Transport Systems
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• v.10 no.4
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• pp.11-23
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• 2011

The objective of this paper is to develop a daily pattern clustering algorithm using historical traffic data that can reliably detect under various traffic flow conditions in urban streets. The developed algorithm in this paper is categorized into two major parts, that is to say a macroscopic and a microscopic points of view. First of all, a macroscopic analysis process deduces a daily peak/non-peak hour and emphasis analysis time zones based on the speed time-series. A microscopic analysis process clusters a daily pattern compared with a similarity between individuals or between individual and group. The name of the developed algorithm in microscopic analysis process is called "Two-step speed clustering (TSC) algorithm". TSC algorithm improves the accuracy of a daily pattern clustering based on the time-series speed variation data. The experiments of the algorithm have been conducted with point detector data, installed at a Ansan city, and verified through comparison with a clustering techniques using SPSS. Our efforts in this study are expected to contribute to developing pattern-based information processing, operations management of daily recurrent congestion, improvement of daily signal optimization based on TOD plans.

• 전기의세계
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• v.28 no.8
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• pp.8-12
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• 1979

이글은 다음과 같이 구성되어 있다. 1. 머릿말 2. 열자극전류의 기본원리 3. TSC 측정방법 4. 쌍극자분극 5. 포획, 공간전하 6. 이온 공간전하분극 7. 결론

• 전기의세계
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• v.30 no.11
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• pp.671-680
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• 1981

영구쌍극자를 함유한 판상시료 양면에 전극을 접촉한 계의 TSC에 관해서 쌍극자의 완화시간이 단일인 경우와 분포된 경우로 구분하여 설명하기로 한다.

• Proceedings of the KIEE Conference
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• 1981.07a
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• pp.103-104
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• 1981

• Proceedings of the KIEE Conference
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• 1981.07a
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• pp.112-114
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• 1981

• Proceedings of the KIEE Conference
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• 1995.07c
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• pp.1156-1158
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• 1995

Charge decay, thermally stimulated current(TSC), charging and discharging currents(I) are measured for negatively corona-charged polymers. In this study, we will make an experiment in charge decay on polymer surface, TSC, polarity effect and the others in order to analysis it's mechanism. Especially polyvinylidene fluoride(PVDF) film is the best functional material which has been so far. Therefore, It's worthy of notice to investigate it's characteristic. And then some other functional polymers will be focused on. An experimental result was missed out for the shortage of setting. So, this thesis will be explained on the theory and direction of reseach hereafter.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.40 no.8
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• pp.808-815
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• 1991

The behavior of space charge in PE/ionomer blends has been investigated using the thermally stimulated current (TSC) technique. In the blends, at least two TSC peaks over the temperature range from -50 to 100\ulcorner are observed, one at -5 ~ 10\ulcorner (a peak) and the others at above 60\ulcorner (a peak). The a peak is assigned as the orientation of dipoles from the ionomer component. Two a peaks seem to be related to the charge trapping at sites related to the crystalline phases. One a peak is associated with the ionic interfaces and the other with the ethylene chains without the ionic interfaces. The amount of charges stored in PE/Surlyn 1652 blends increases as the poling field increases over the field range of +8 ~ +30 kV/mm, whereas that in PE/Surlyn 1601 blends increases slightly at low poling fields and then decreases at high poling fields above +10 kV/mm. Exact reasons for such a dirrerence are not known at this point.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1995.11a
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• pp.163-166
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• 1995

It was investigated the properties of TSC (Thermally Stimulated Current) to understand carriers behavior from long ago. Activation Energy of their properties is very important to verify electrical characteristics. So, for many years, many researchers were worked to get the activation energy, more compeletely. But, if boundary conditions were not satisfied, the values of activation energy contained several errors. In this work, to obtain the activation energy related to charged particles, the peak temperature Tp and the slope of tangential line on any coordinates of Arrhenius plot are applied. The calculation process can be denied with by computer, and the result of observation shows that the cures of calculation data and simulation data coincide very compeletely.