• Journal of Korean Society of Environmental Engineers
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• v.36 no.12
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• pp.851-857
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• 2014

Treatability of heavy metals in marine sediments contaminated with mainly organic matter was investigated on the basis of washing technology using oxidizers and surfactants. Sediment samples were collected at N area which expected for remediation project of contaminated marine sediment. For additives, hydrogen peroxide ($H_2O_2$) and Tween-80 were used at oxidizer and nonionic surfactant, respectively. In experiments, sediments was mixed with sea water at the ratio of 1 : 3 than $H_2O_2$ (1 M, 3 M, 4 M, 5 M) and Tween-80 (0.05%) were added. Samples were gathered at following reaction time (10, 20, 30, 40, 50, 60, 70, 80 min and 24 h). Total Organic Carbon (TOC) was 55.2% at the conditions of 5 M $H_2O_2+0.05%$ Tween-80 24 h. Hence total heavy metals were Cu 29.5%, Zn 42.3%, Cd 73.0% and bioavailable heavy metals were Cu 60.0%, Zn 77.7%, Cd 90.2% at the conditions of 5 M $H_2O_2+0.05%$ Tween-80 10 min. The correlations for between bioavailable metals (Cu, Zn, Cd) and TOC were significant (Cu, Zn, Cd; $r^2=0.94$, 0.85, 0.69, respectively).

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• v.29 no.1
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• pp.293-298
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• 2005

Lab scale experimental study was carried out for SBR process, to investigate the effects of influent ship sewage organic compound removal and Bacillus sp. state on design parameters. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. The performance load of SBR process was shown to be 0.095kg ${\cdot}$ TOC/$m^{3}$ ${\cdot}$ day. The pH was decreased from 8.1 to 7.0 within 30 min and increased to 7.3 at the end of anoxic stage, and these phenomena were explained. The sluge produced in the SBR process is characterized by low generation rate (about 0.36kg ${\cdot}$ MLSS/kg ${\cdot}$ TOC) and excellent settleability. The number of Bacillus sp. in the SBR was 24.2%, indicating that Bacillus sp. was a predominant species in the reactor.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.209-209
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• 2020

환경부 자료에 따르면 1990년대부터 2000년대 후반까지 국내의 도시면적은 696,239㎢ 증가했다. 도시지역에서의 불투수면적이 차지하는 비율은 25% ~ 80%로 적지 않은 비율을 차지한다. 따라서 도시면적이 증가하면 이는 불투수면적의 증가로 이어지며 이로인한 지표유출로 오염물질의 유입이 늘어나게 되면, 수질오염중 비점오염원이 차지하는 비중의 증가한다. 비점오염원으로 인해 발생하는 환경문제를 해결하기 위해 LID(Low Impact Develpment)시설에 대한 연구가 많이 진행되었다. 본 연구에서는 7년간의 선행 연구결과를 바탕으로 LID 시설별 오염물질 저감효율을 비교분석하였다. 용인 삼계리에 위치한 식생수로 오염지표들의 유입, 유출EMC를 토대로 제거 효율에 대한 평가를 해보면 TSS는 46%, BOD는 48%, COD는 56%. TN은 42% 그리고 TP는 58%가 나왔다. 용인 해곡동에 위치한 식생여과대의 경우 TSS는 83%, BOD는 45%, COD는 43%, TN은 39%, 그리고 TP는 62%가 나왔다. 마지막으로 전주에 위치한 식생체류지의 경우 TSS는 100%, BOD는 75%, TOC는 62%, TN은 67% 그리고 TP는 83%가 나왔다. 이들 자료를 바탕으로 효율성 평가를 해보면 먼저 식생수로의 경우 TP 저감 효율이 58%로 가장 높았으며 TN 저감 효율이 42%로 가장 낮았다. 식생여과대의 경우 TSS 저감 효율이 83%로 가장 높았으며 TN 저감 효율이 39%로 가장 낮았다. 마지막으로 식생체류지의 경우 TSS 저감 효율이 100%에 가까운 양질의 제거효율을 보여주었으며, TOC의 경우 67%로 제일 낮은 제거효율을 보였다. 위 결과를 토대로 판단을 해보면 식생체류지가 전반적으로 좋은 지표를 보였으며 대부분의 상황에 양호한 제거효율을 기대할 수 있다고 생각된다. 식생 LID시설은 자연친화적이며 강우유출과 오염물질을 제거할 수 있다는 장점이 있는 반면, 장치형 LID시설에 비해 넓은 부지면적을 필요로 하므로 설치 지역의 특성에 맞게 LID 시설을 시공하는것이 적절하다고 판단된다. 해당 연구결과는 향후 식생형 LID시설을 설계하는데 있어서 기초자료로 반영될 것으로 기대된다.

• Analytical Science and Technology
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• v.13 no.5
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• pp.652-658
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• 2000

Chemical degradation of aqueous humic acid by ozonation was studied with respect to the direct reactions of ozone and the indirect reactions due to its preliminary decomposition to secondary oxidant, OH radical. This was characterized by analyzing TOC, $UV_{254}$ and ozone consumption measured in different experimental conditions in which ozone reacted in the presence of various concentrations of $H_2O_2$ and $HCO_3{^-}$ concentrations ranging from 20 to 100 mg/L. and different pH (5-9). The results suggest that the TOC removal is mainly dependent on indirect reactions of OH radical whereas $UV_{254}$ reduction is mainly dependent on direct reactions of ozone with humic acid molecules. It has been also found that ozone consumption was most likely to be affected by pH and alkalinity in the solution.

• Journal of Soil and Groundwater Environment
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• v.7 no.1
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• pp.25-31
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• 2002

This study attempts to elucidate the possibility of treating landfill leachate by steelers' dust/${H_2}{O_2}$ system in a well-mixed batch reactor. Experiments were conducted to investigate the effects of operating variables such as pH, dust and ${H_2}{O_2}$ dosages and ${H_2}{O_2}$ injection method on the treatment efficiency, Contaminant concentrations were identified by TOC (Total Organic Carbon) analyzer. Experimental observations showed the possibility of steelers' dust as a catalytic reagent in the ${H_2}{O_2}$/dust system. The batch experiments showed that the optimal $H_2O$$_2$ and dust dosage, 20g/L dust. 2,000mg/L ${H_2}{O_2}$ removed about 75% of initial TOC concentration (250mg/1) within 60 min. And the TOC removal in the ${H_2}{O_2}$/dust system effectively proceeded only within a limited pH range of 3-4. The stealers' dust-catalyzed oxidative treatment of landfill leachate was more efficient compared with the $FeSO_2$catalyzed system (Fenton oxidation) for the removal rate and the cost.

• Journal of the Korean Wood Science and Technology
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• v.47 no.6
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• pp.709-720
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• 2019

Due to global warming and abnormal climate, the incidence and scale of green tracts in rivers and water intake dam are increasing every year. Therefore, in this study, developed eco friendly positively charged Torrefied Wood Flour(TWF) coagulant by reusing wood damaged by blight as a natural material. In order to evaluate the effect of coagulant on water ecosystem, green algae contaminated water was collected and TOC showed high removal rate of 86% ~ 92% under 1% and 5% TWF C-PAM treatment condition. The $NH_3-N$ showed 53% removal efficiency. The average pH of the polluted water was 7.9 in the case of hydrogen ion concentration, and the pH of the treated water was in the range of 6.5 ~ 7.7, It was found to be suitable for water quality standards. In ecotoxicity tests, all the results of the experiment showed that both the number of green algae and that of treated water were not affected by the survival of the daphnia. Therefore, as a result of the analyzing, developed paste type TWF coagulants is considered to be able to remove algae using natural resources.

• Journal of Environmental Impact Assessment
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• v.28 no.5
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• pp.471-482
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• 2019

Water treatment system filled with Bio-stone Ball (BSB) have been developed for the purification of polluted water in many rivers and lakes. The real-scale plants of BSB water treatment system was constructed for field application test and water purification evaluation in Maewha reservoir. The average water purification efficiencies of BSB watertreatment system shows BOD 70.3% (47.2~97.4%), COD 45.3% (26.1~64.7%), TOC 19.2% (8.5~50.0%), SS 82.8% (73.1~92.7%), Chl-a 80.4% (57.2~91.8%), TN 23.2% (6.4~39.5%), and TP 51.8% (-1.1~80.1%). BSB water treatment system shows very high at 70~80% in the water purification efficiencies of BOD, Chl-a, and SS. The average of pollution loading reduction by installation of BSB treatment system shows 39.2% for COD and 16.8% for TP. The water quality improvement rates (%) of the Maewha reservoir shows TOC 14.5%, COD 14.5%, Chl-a 12.5% and TP 25.1%. The BSB watertreatment system can be applied to many agricultural reservoirs and major rivers to deal with serious water pollution issues.

• Journal of Navigation and Port Research
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• v.29 no.5 s.101
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• pp.475-480
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• 2005

Lab scale experimental study was carried out for SBR process, to investigate the effects of influent ship sewage organic compound removal and Bacillus sp. state on design parameters. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than $92.0\%$ of chemical oxygen demand(COD) were removed. In addition, about $84.0\%$ of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged $93\%$. The performance load of SBR process was shown to be $0.095kg{\cdot}TOC/m3{\cdot}day$. The pH was decreased from 8.1 to 7.0 within 30 min and increased to 7.3 at the end of anoxic stage, and these phenomena were explained. The sludge produced in the SBR process is characterized by low generation rate (about $0.36kg{\cdot}MLSS/kg{\cdot}TOC$) and excellent settleability. The number of Bacillus sp. in the SBR was $24.2\%$, indicating that Bacillus sp. was a predominant species in the reactor.

• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.486-492
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• 2009

Wet oxidations (WO) of quinoline in aqueous solution were carried out at $225^{\circ}C$ and $250^{\circ}C$. In the WO at $250^{\circ}C$, quinoline was degraded completely within 30 min and the reduction in total organic carbon (TOC) of 63% was achieved during 120 min. However, the rate of the reduction in TOC was only 13% within 240 min during the WO at $225^{\circ}C$. Nicotinic and acetic acid were found to be main intermediates formed during the oxidation of quinoline. With the addition of the homogeneous catalyst $CuSO_4$ or more easily oxidizable phenol, WOs of quinoline were also carried out under moderate conditions at $200^{\circ}C$. The catalytic WO with $CuSO_4$ of 0.20 g/L showed the destruction rates of quinoline and TOC comparable to those in the WO at $250^{\circ}C$. The WOs of quinoline-phenol mixture exhibited induction periods to degrade quinoline and phenol during which free radicals were produced to initiate WOs. With increasing initial concentrations of phenol at a given initial concentration of quinoline, the induction periods in the destructions of quinoline and phenol became shorter and the reduction in TOC increased from 60% to 75% during 180 min of the WOs. The reduction rate of an induction period decreased as increasing the initial concentration ratio of phenol to quinoline. On the other hand, phenol degradation in the WOs of quinoline-phenol mixtures required a longer induction period and proceeded slower compared to the case of the WO of phenol.

• Analytical Science and Technology
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• v.14 no.1
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• pp.80-87
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• 2001

This research was studied the action of the coupling ozone-hydrogen peroxide on aqueous humic acid. PEROXONE process is enhanced the generation of hydroxyl radicals which is effective for degradation of organic matters. Therefore the changes of $UV_{254}$ and TOC were investigated through the change of concentrations, injection time of $H_2O_2$, initial pH of aqueous humic acid and concentrations of radical savenger as $HCO_3{^-}$ in the PEROXONE processes. And the GC/ECD was used to detect the formaldehyde formed by ozonation of humic acid. From the experimental results, concentrations and injection time of $H_2O_2$ and initial pH in solution in the PEROXONE processes were very important for enhancing the efficiency of degradation in humic acid. The results indicated that removal efficiency of TOC was the highest when concentration of $H_2O_2$ was 5mg/L, injection time of $H_2O_2$ was 5 minutes and initial pH in solution was 10.5. And presence of alkalinity in solution was reduced the efficiency of treatment. The formaldehyde were formed less PEROXONE processes than only ozone. When initial pH in solution were changed from 3.5 to 10.5, the formaldehyde were formed highest concentration at pH 5.