• Title/Summary/Keyword: TOC (Total Organic Carbon)

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A Study on the Determination Method of TOC Effluent Limitation for Public Sewage Treatment Plants (하수처리시설의 방류수 수질기준 설정방법 고찰 - TOC를 중심으로 -)

  • Jeong, Dong-Hwan;Cho, Yangseok;Ahn, Kyunghee;Chung, Hyen-Mi;Park, Hoowon;Shin, Hyunsang;Hur, Jin;Han, Daeho
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.3
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    • pp.241-251
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    • 2016
  • As the Enforcement Ordinance of Environmental Policy Act was revised in 2013, total organic carbon(TOC) was added as an indicative parameter for organic matter in Water and Aquatic Ecosystem Environmental Criteria. Under these imminent circumstances, a regulatory standard is needed to achieve the proposed TOC limitation control water quality from the public sewage treatment plants(PSTWs). This study purposes to present the determination method for TOC effluent limitation at the PSTWs. Therefore we investigate the TOC effluent limitation of foreign countries such as EU, Germany and USA, and analyse the effluent water qualities of PSTWs. In using these TOC data, we review apprehensively the statistics-based, the technology-based, and the region(water quality)-based determination method of TOC effluent limitation for PSTWs.

The Bildegradability of Carrageenan-based Film by Microorganisms (Carrageenan 필름의 미생물에 의한 생분해도 측정)

  • Kang, Seong Gook;Jung, Soon-Teck;Park, Hyun Jin;Rhim, Jong Whan
    • Microbiology and Biotechnology Letters
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    • v.23 no.6
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    • pp.702-709
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    • 1995
  • Degradation Of $\kappa $-carrageenan-based film by microorganisms screened from carrageenan source and activated sludge of a carrageenan producing factory was investigated by measuring changes of pH, viscosity, total sugar and total organic carbon (TOC) of the medium containing $\kappa $-carrageenan as a carbon source. Initially fifteen strains of microorganism were isolated from carrageenan source and activated sludge and then three organisms among them were selected based on the ability of growing in the medium including 0.3% $\kappa $-carrageenan as a sole carbon source. They were identified as Escherichia coli, Saccharomyces cerevisiae and Aspergillus niger. As indices of biodegradability Of $\kappa $-carrageenan based film, the changes of pH, viscosity, total sugar, and TOC of the carrageenan film-based medium were tested by the cultivation of single or mixed strains of the identified organisms. Mixed culture showed the highest biodegradability, which resulted in the changes of pH from 6.5 to 3.0, viscosity from 164 cps to 15.6 cps, total sugar content from 2.35 g/l to 0.53 g/l and TOC from 5721 ppm to 232 ppm after 30 days of cultivation. The biodegradability determined as the reduction rate of TOC by pure cultures of Asp. niger, E. coli, Sacch. cerevisiae and mixed culture of the three organisms were 94%, 86%, 80% and 96%, respectively.

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Determination of Total Organic Carbon in Water by Flame Ionization Detector (FID를 이용한 수중의 TOC 분석법)

  • 박만기;한대석;임병연
    • YAKHAK HOEJI
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    • v.22 no.3
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    • pp.157-162
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    • 1978
  • Total organic carbon(TOC) can be determined by means of combustion and flame ionization detector. The principle of string method is that a sample acidified to pH2 and transferred into combustion tube by string is oxidized with air. Another combustion tube method is that organic compounds are oxidized in the combustion tube charged with CuO and cobalt asbestos after the acidified sample is injected directly by microsyringe. Carbon dioxide evolved was reduced under specially treated nickel catalyst and hydrogen, the methane produced was detected by flame ionization detector. Linear relationship was found between concentration and the peak height by the string method. The peak area in the case of combustion tube method is in the range of 1-200ppm. The coefficient of variation by string method was 2.3% and that by combustion tube method was 1.8%. The lower detectable limit was about 10mol. Advantages of the latter are simplicity, sensitivity and reproducibility. TOC in contineous stream can also be determined automatically by means of the string method.

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Correlation analysis between TOC and organic matter indices in influent and effluent of public sewage treatment facilities (공공하수처리시설 유입수 및 방류수에서 TOC와 유기물질 관리지표간의 상관성 분석)

  • Son, Dong-Jin;Jeong, Dong-Hwan;Park, Kyoo-Hong
    • Journal of Convergence for Information Technology
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    • v.11 no.4
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    • pp.122-129
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    • 2021
  • As the total organic carbon (TOC) becomes a new water quality standard as an organic matter (OM) index for public sewage treatment facilities (PSTFs) in Korea from 2021, a comparison study needs to be conducted by examining the correlation between TOC and the existing OM indices (DOC, BOD5, CODMn, CODCr). 500 PSTFs were categorized by process configuration and capacity, and correlation between OM indices in influent and effluent was analyzed. The CODMn/TOC showed higher correlation than other OM indices. This results can be used to basic data for various research associated with TOC.

Application of Discrete Wavelet Transform for Detection of Long- and Short-Term Components in Real-Time TOC Data (실시간 TOC 자료의 장.단기 성분의 검출을 위한 이산형 웨이블렛 변환의 적용)

  • Jin, Young-Hoon;Park, Sung-Chun
    • Journal of Environmental Science International
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    • v.15 no.9
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    • pp.865-870
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    • 2006
  • Recently, Total Organic Carbon (TOC) which can be measured instantly can be used as an organic pollutant index instead of BOD or COD due to the diversity of pollutants and non-degradable problem. The primary purpose of the present study is to reveal the properties of time series data for TOC which have been measured by real-time monitoring in Juam Lake and, in particularly, to understand the long- and short-term characteristics with the extraction of the respective components based on the different return periods. For the purpose, we proposed Discrete Wavelet Transform (DWT) as the methodology. The results from the DWT showed that the different components according to the respective periodicities could be extracted from the time series data for TOC and the variation of each component with respect to time could emerge from the return periods and the respective energy ratios of the decomposed components against the raw data.

Comparison of the Performance of Machine Learning Models for TOC Prediction Based on Input Variable Composition (입력변수 구성에 따른 총유기탄소(TOC) 예측 머신러닝 모형의 성능 비교)

  • Sohyun Lee;Jungsu Park
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.3
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    • pp.19-29
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    • 2024
  • Total organic carbon (TOC) represents the total amount of organic carbon contained in water and is a key water quality parameter used, along with biochemical oxygen demand (BOD) and chemical oxygen demand (COD), to quantify the amount of organic matter in water. In this study, a model to predict TOC was developed using XGBoost (XGB), a representative ensemble machine learning algorithm. Independent variables for model construction included water temperature, pH, electrical conductivity, dissolved oxygen concentration, BOD, COD, suspended solids, total nitrogen, total phosphorus, and discharge. To quantitatively analyze the impact of various water quality parameters used in model construction, the feature importance of input variables was calculated. Based on the results of feature importance analysis, items with low importance were sequentially excluded to observe changes in model performance. When built by sequentially excluding items with low importance, the performance of the model showed a root mean squared error-observation standard deviation ratio (RSR) range of 0.53 to 0.55. The model that applied all input variables showed the best performance with an RSR value of 0.53. To enhance the model's field applicability, models using relatively easily measurable parameters were also built, and the performance changes were analyzed. The results showed that a model constructed using only the relatively easily measurable parameters of water temperature, electrical conductivity, pH, dissolved oxygen concentration, and suspended solids had an RSR of 0.72. This indicates that stable performance can be achieved using relatively easily measurable field water quality parameters.

Holocene Variations of Organic Carbon Contents in Lake Langer of King George Island, South Shetland Islands, West Antarctica

  • Khim, Boo-Keun;Yoon, Ho-Il;Kang, Cheon-Yun;Zhao, Junlin
    • Ocean and Polar Research
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    • v.26 no.3
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    • pp.507-514
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    • 2004
  • A sediment core drilled from Lake langer on King George Island was analyzed for a variety of textural md geochemical properties along with $^{14}C$ age dates. These data were combined with published records of other cores to provide a detailed history of Holocene variation of total organic carbon (TOC) contents with respect to terrestrial paleoclimate change. The lithologic contrast of the lower diamicton and upper fine-grained sediments shows the glacier activity and subsequent lake formation. Low TOC contents fluctuated during the diamicton deposition whereas the increase of TOC began with the lake formation during the postglacial period that started about 5,000 yr B.p More notable are the distinct TOC peaks that may imply enhanced primary productivity during the warm period. The uniform and low TOC contents may reflect the limited productivity during the evolution of the lake. However, the recent TOC readvance clearly indicates gradual warming on King George Island. However, the paleoclimatic signature in the terrestrial lake environment during the Holocene seems to be subtle and less distinct, compared to the marine environment.

Effect of the Total Organic Carbon(TOC) on phosphorus removal by Stapylococcus auricularis (Stapylococcus auricularis에 의한 인 제거에서 총유기탄소의 영향)

  • 최석순
    • Journal of environmental and Sanitary engineering
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    • v.15 no.3
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    • pp.57-61
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    • 2000
  • Stapylococcus auricularis was used for the simultaneous removal of phosphorus and Total Organic Carbon(TOC) in the wastewater from sewage and various industries. In this study, the characteristics of phosphorus removal was investigated with initial ratio of TOC phosphorus in the synthetic wastewater. When the synthetic wastewater containing 15mg/L of phosphorus was treated under anaerobic and conditions, phosphorus was removed completely within 6 hours of operation. And when the initial ratio of TOC to phosphorus was 30, as high as 10 times the removal rate of phosphorus by Acinetobacter calcoaceticus was achieved. These results implied that a long adaptation time, one of the chief problems in biological phosphorus removal process was overcome.

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A Study on the Appropriateness as Organic Matters Indicator and the Distribution of Chemical Oxygen Demand and Total Organic Carbon in Masan Bay, Korea (마산만 해수 중 화학적산소요구량과 총유기탄소 분포 특성 및 유기물 지표로서의 적절성 검토)

  • PARK, MI-OK;LEE, YONG-WOO;CHO, SEONG-AH;KIM, HYE-MI;PARK, JUN-KUN;KIM, SUNG-GIL;KIM, SEONG-SOO;LEE, SUK MO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.26 no.2
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    • pp.82-95
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    • 2021
  • We investigated the temporal and spatial distribution characteristics of chemical oxygen demand (COD) and total organic carbon (TOC) in all 13 locations of Masan Bay from February to November in 2015. The COD and TOC contents were high during the June-August period when the pollution load increased. In particular, the concentrations of COD and TOC were about twice as high in the surface water as in the bottom water. In spatial distribution, the COD and TOC concentrations at the inner bay were about twice as high as those of the outer bay in Masan Bay. As a result of estimating the oxidation efficiency of COD from the surface layer of Masan Bay in 2015 based on the theoretical oxygen demand (TOD), it was at the level of about 23%. Due to the low oxidation efficiency of COD, there is a risk that the organic matter in Masan Bay will be somewhat underestimated. Therefore, for quantitative analysis of organic matter, COD and TOC analyses need to be combined.