• 한국지하수토양환경학회지:지하수토양환경
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• 제17권1호
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• pp.42-46
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• 2012

The ISO document of ISO/TC/190/SC3/WG11/N11 is a working draft of international standard (WD) dealing with analytical method for the determination of explosives and related compounds using high performance liquid chromatography. The scope of this WD covers the storage of samples, preparing test portion, extraction and instrumentation. The main purpose of this study was to improve the extraction conditions which were already adopted in the WD. For this purpose, mechanical shaking method could be corresponded up to 18 hours of ultrasonic bath extraction in the WD was tested. Methanol was also tested with the intention of being added as an extracting solvent other than acetonitrile in the WD. According to the results, 16 hours of mechanical shaking method showed statistically the same effectiveness as that of 18 hours of ultrasonic bath extraction. In case of extracting solvent, methanol also showed statistically the same extraction capability as acetonitrile for DNB, TNT, 2-A-DNT and 2,4-DNT. However, the recovery rate of TNB with methanol extraction was 40% higher than that of acetonitrile extraction. Through adding mechanical shaking method into committee draft (cf. the next stage draft of the WD during the process for making international standard), ISO standard of analyzing explosives and related compounds in soil would become more useful in dealing with huge number of field samples in the laboratory. In other aspect, adopting methanol as an alternative extracting solvent would be very effective in the terms of exchangeability with GC-ECD/MS method which is being developed by German experts.

• 한국지하수토양환경학회지:지하수토양환경
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• 제20권6호
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• pp.8-18
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• 2015

Pollutants such as heavy metals and explosives originating from the military operational ranges can be migrated to adjacent surface water body or offsite soil, and can affect to local residents and aquatic ecosystem. Therefore, Korea Ministry of the National Defense has established various guidelines for environmental management including the installation of pollutant migration prevention facilities (PMPFs) and monitoring methodologies for heavy metals in the operational range soil and effluent and sediment of PMPFs. However, current guidelines neither address the explosive compounds such as 2, 4, 6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) nor suggest detailed environmental investigation protocol. This paper introduces the new “Environmental Management Manual for Military Firing Ranges”, which includes the environmental criteria for explosives as well as the detailed investigation protocol for the affected environmental media including soil, effluent and sediment of PMPFs.

• 한국해양공학회지
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• 제37권3호
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• pp.99-110
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• 2023

When a fire accident accompanied by an explosion occurs, the surrounding firewalls are affected by impact and thermal loads. Damaged firewalls due to accidental loads may not fully perform their essential function. Therefore, this paper proposes an advanced methodology for evaluating the fire resistance performance of firewalls damaged by explosions. The fragments were assumed to be scattered, and fire occurred as a vehicle exploded in a large compartment of a roll-on/roll-off (RO-RO) vessel. The impact velocity of the fragments was calculated based on the TNT equivalent mass corresponding to the explosion pressure. Damage and thermal-structural response analyses of the firewall were performed using Ansys LS-DYNA code. The fire resistance reduction was analyzed in terms of the temperature difference between fire-exposed and unexposed surfaces, temperature increase rate, and reference temperature arrival time. The degree of damage and the fire resistance performance of the firewalls varied significantly depending on impact loads. When naval ships and RO-RO vessels that carry various explosive substances are designed, it is reasonable to predict that the fire resistance performance will be degraded according to the explosion characteristics of the cargo.

• Structural Engineering and Mechanics
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• 제84권2호
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• pp.167-180
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• 2022

A strategic structure when exposed to direct hit of conventional bomb/projectile are severely damaged because of large amounts of energy released by the impact and penetration of bomb. When massive concrete slabs suffer a direct hit, the energy released during impact and penetration process are able to easily break up large mass of concrete. When over stressed under such impact of bombs, the concrete structure fails showing brittle behavioural nature. This paper is intended to study and suggest the protective measures for structures used for strategic application by adopting a means to dissipate the large quantum of energy released. To quantitatively evaluate the force, displacement and energy in such scenario, a fine numerical model of the proposed layered structure of different combinations was built in ANSYS programme in which tri-nitrotoluene (TNT) explosive was detonated at penetration depth calculated for GP1000 Lbs bomb. The distinct blast mitigation effect of the proposed structure was demonstrated by adopting various layers/barriers created as protective measures for the strategic structure. The calculated result shows that the blast effect on the structure is potentially reduced due to provision of buster slab with sand cushioning provided as protective measure to the main structure. This concept of layered protective measures may be adopted for safeguarding strategic structures such as Domes, Tunnels and Underground Structures.

• Structural Engineering and Mechanics
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• 제91권1호
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• pp.103-121
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• 2024

The smoothed particle hydrodynamics (SPH) method is a numerical technique used in dynamic analysis to simulate the fluid-like behavior of materials under extreme conditions, such as those encountered in explosions or high velocity impacts. In SPH, fluid or solid materials are discretized into particles. These particles interact with each other based on certain smoothing kernels, allowing the simulation of fluid flows and predict the response of solid materials to shock waves, like deformation, cracking or failure. One of the main advantages of SPH is its ability to simulate these phenomena without a fixed grid, making it particularly suitable for analyzing complex geometries. In this study, the structural damage to a masonry arch bridge subjected to blast loading was investigated. A high-fidelity micro-model was created and the explosives were modeled using the SPH approach. The Johnson-Holmquist II damage model and the Mohr-Coulomb material model were considered to evaluate the masonry and backfill properties. Consistent with the principles of the JH-II model, the authors developed a VUMAT code. The explosive charges (50 kg, 168 kg, 425 kg and 1000 kg) were placed in close proximity to the deck and pier of a bridge. The results showed that the 50 kg charges, which could have been placed near the pier by a terrorist, had only a limited effect on the piers. Instead, this charge caused a vertical displacement of the deck due to the confinement effect. Conversely, a 1000 kg TNT charge placed 100 cm above the deck caused significant damage to the bridge.

• 한국지반환경공학회 논문집
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• 제16권4호
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• pp.13-22
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• 2015

나노여과공정에서 폭발 오염물질인 TNT(2, 4, 6-Trinitrotoluene), RDX(Hexahydro-1, 3, 5-trinitro-1, 3, 5-triazine) 및 HMX(1, 3, 5, 7-Tetranitro-1, 3, 5, 7-tetrazocane) 화약류의 잔류에 용존유기물의 오염과 무기물의 스케일링에 의한 케익층 형성 및 농도분극의 영향성을 분석하였다. 지표수 조건의 휴믹산 농도에 의한 나노여과공정에서는 용존유기물에 의한 나노여과막 오염이 발생되어도 플럭스의 큰 변화가 없는 것으로 나타났으며, 휴믹산과 무기 스케일링이 동시에 발생되었을 경우에는 나노여과공정에서 플럭스의 감소가 큰 것으로 나타났다. 휴믹산과 $Ca_3(PO_4)_2$을 혼합하였을 때 플럭스 투과량이 42% 감소하였고 휴믹산만 첨가하였을 경우에 플럭스 투과량은 8% 감소한 것으로 나타났다. 이는 NF 막의 $Ca_3(PO_4)_2$스켈턴트 결정과 용존유기물이 칼슘($Ca^{2+}$)이온의 상호작용에 의해 막 표면에 증강된 케익층을 형성하여 NF 막의 플럭스를 감소시키는 것을 알 수 있었다. 그리고 막의 크기배제에 의한 선택성을 기반으로 하여 폭발물의 나노여과막에 의한 잔류량을 조사할 경우 HMX(296.15, 83%) ${\gg}$ RDX(222.12, 49%) ≋ TNT(227.13, 32%)로 나타났다. 막 오염과 스케일링은 케익층의 형성으로 막 표면에서 증대된 농도 분극효과를 나타낼 수 있으나, 무기 스케일링 형성과 휴믹산에 의한 화약류의 잔류 영향성은 순수한 DI 및 NaCl 피드용액의 여과공정 결과와 크게 다르지 않는 것으로 나타났다. 이는 전량여과방식(Dead-end Flow)의 나노여과공정에서 화약류의 잔류 영향성은 임계크기에 의한 선택적 배제성이 케익층 형성 및 농도분극에 의한 잔류 영향성보다 크다는 것을 보여준다.

• 한국시뮬레이션학회논문지
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• 제27권1호
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• pp.101-109
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• 2018

실험과 유한요소코드를 이용한 수치해석은 폭발 하중에 의한 구조거동을 이해하는 유용한 방법이다. 그러나 내부폭발에 의한 철근콘크리트 구조물 거동에 대한 유한요소해석 결과와 실험적 검증에 대한 자료는 극히 드물다. 이 논문에서는 내부폭발에 의한 철근콘크리트 구조물 거동을 수치해석과 실험적으로 연구하였다. 방 하나짜리 축소형 콘크리트 내력벽 건물 중심에서 TNT가 기폭되는 상황을 고려하였다. 내부 폭풍압 분포와 철근콘크리트 벽 거동 분석은 유한요소 해석 코드인 ANSYS AUTODYN을 사용하였다. 수치해석과 실험을 비교한 결과 방 내부 세 곳에서 측정한 폭풍압과 두 벽 중심의 변위, 네 벽의 파손형태가 유사하게 나타났다. 또한 내부폭발 시 구조부재 거동에 대한 수치해석의 타당성과 정당성을 구조적 피해평가 측면에서 논의한 결과, 해석과 실험에서 같은 파손으로 평가되었다.

• 한국안전학회지
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• 제31권4호
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• pp.55-63
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• 2016

A dust explosion is a phenomenon of strong blast wave propagation involving destruction which results from dust pyrolysis and rapid oxidation in a confined space. There has been some research done to find individual explosion characteristics and common physical laws for various dust types. However, there has been insufficient number of studies related to the heat of combustion of materials and the oxygen consumption energy about materials in respect of dust explosion characteristics. The present study focuses on the relationship between dust explosion characteristics of wood dust samples and oxygen consumption energy. Since it is difficult to estimate the weight of suspended dust participating in explosions in dust explosion and mixtures are in fuel-rich conditions concentrations with equivalent ratios exceeding 1, methods for estimating explosion overpressure by applying oxygen consumption energy based on unit volume air at standard atmospheric pressure and temperature are proposed. In this study an oxygen consumption energy model for dust explosion is developed, and by applying this model to TNT equivalent model, initial explosion efficiency was calculated by comparing the results of standardized dust explosion experiments.

• 한국안전학회지
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• 제32권5호
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• pp.62-68
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• 2017

It is necessary to analyze on the compressive strength among material properties of concrete for confirming damages of architectures due to large explosion. A non destructive test is known as the representative methods estimating compressive strength and ultrasonic pulse velocity, rebound hardness test are widely used because of their simplicity, convenience. But combined method supplementing two types is applied at now as they are affected by the characteristics of test specimen. In this research to check damages on the members of structure before and after explosion, the characteristics of compressive strength are compared and analyzed through a real explosion test prior to full scale structures. The test results showed that the larger the TNT powder and the shorter the distance, the greater the decrease in strength before and after the explosion and that the largest displacement and moment for the explosive load and the greatest decrease in the strength at the central part. Due to the surface condition and the thickness variation of the concrete specimens, the standard deviation value is the smallest in the combining method of fusion of the ultrasonic method and rebound hardness method. Thus, the combining method can be one of appropriate methods to evaluate the strength in the reinforced concrete structures damaged by the explosion.

• Korean Chemical Engineering Research
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• 제56권6호
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• pp.811-818
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• 2018

A fire and explosion accident caused by a liquefied petroleum gas (LPG) welding and cutting torch gas leak occurred 10 m underground at the site of reinforcement work for bridge columns, killing four people and seriously injuring ten. We conducted a comprehensive investigation into the accident to identify the fundamental causes of the explosion by analyzing the structure of the construction site and the properties of propane, which was the main component of LPG welding and cutting work used at the site. The range between the lower and upper explosion limits of leaking LPG for welding and cutting work was examined using Le Chatelier's formula; the behavior of LPG concentration change, which included dispersion and concentration change, was analyzed using the fire dynamic simulator (FDS). We concluded that the primary cause of the accident was combustible LPG that leaked from a welding and cutting torch and formed a explosion range between the lower and upper limits. When the LPG contacted the flame of the welding and cutting torch, LPG explosion occurred. The LPG explosion power calculation was verified by the blast effect computation program developed by the Department of Defense Explosive Safety Board (DDESB). According to the fire simulation results, we concluded that the welding and cutting torch LPG leak caused the gas explosion. This study is useful for safety management to prevent accidents caused by LPG welding and cutting work at construction sites.