• 한국전기전자재료학회논문지
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• 제20권9호
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• pp.756-760
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• 2007

Flame retardant(FR) properties were investigated with tricredyl phosphate(TCP) and tris(pentafluorophenyl)phosphine(TFPP) as additives for lithium-ion batteries. Thermal stability was improved with additives in $Li/LiNi\frac{1}{3}Mn\frac{1}{3}Co\frac{1}{3}O_2$ cells comparing to non-additive electrolytes. Oxygen evolution reaction of the cathode material was delayed to up $55^{\circ}C$, from $275^{\circ}C\;to\;330^{\circ}C$. Electrolytes with the 1 wt.% additives provided good FR properties while the resonable battery performance is maintained.

• 한국항공우주학회지
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• 제32권4호
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• pp.12-17
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• 2004

고속 유동 속에 놓인 모델 표변의 압력분포를 정량적으로 측정하기 위해 PSP 기술이 사용되고 있다. 본 연구에서는 아음속 유동에 적용 가능한 PSP 기술을 개발하였다. 2가지의 백금계열 (PtOEP와 PtTFPP)의 발광분자와 2 가지의 폴리머 (Poly(TMSP)와 RTV-118)를 사 용하여 4가지의 PSP 조합을 만들어 그 성능을 확인하였다. 압력변화에 따른 PSP의 발광강 도를 측정하기 위해 $0{\sim}11kPa$까지 0.5, 1, 2kPa썩 압력을 증가시키면서 정적보정실험을 수행하였다. 4가지의 PSP 조성 중에 PtOEP 와 RTV-118의 조합이 가장 좋은 성능을 보였다. 충돌평판에 작용하는 압력장 분포를 측정하기 위하여 경사충돌분류에 본 연구에서 개발된 PSP 기술을 응용하였다.

• 대한기계학회논문집B
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• 제26권7호
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• pp.1031-1038
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• 2002

The pressure sensitive paint (PSP) has recently received a considerable attention in the fields of aerodynamics and fluid mechanics as a new revolutionary optical technique to measure pressure fields on a body surface. In this study, the feasibility and effectiveness of the PSP pressure field measurement technique have been investigated experimentally. Seven different PSP formulations including two porphyrins(PtOEP and PtTFPP) and four polymers(Polystyrene, cellulous acetate butyrate, GP-197 and Silicon-708) were tested to check the performance and characteristics of each combination. The static calibration of each PSP formulation was carried out in a constant-pressure chamber. The PSP technique was applied to an oblique impinging jet flow to measure variation of pressure field on the impinging plate at on oblique jet angle of ${\theta}=60^{\circ}$. Pressure field images were captured by an 12bit intensified CCD(ICCD, $1K{\times}1K$)camera. As a result, the dynamic response of PSP depends on the oxygen permeability of polymer and the photochemical interaction between luminophore and polymer as well as the reaction of luminophore itself. The reaction of luminophore was changed by employing different polymers. In conclusion, Among 7 PSP formulation tested, the combination of PtTFPP and cellulous acetate butyrate show the best performance. In addition, the detail pressure field of an oblique high-speed impinging jet was measured effectively using the PSP technique.

• 항공우주시스템공학회지
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• 제2권3호
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• pp.19-23
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• 2008

We have fabricated pressure sensitive paint films consisting of PtTFPP activators dispersed in fluorinated polymer matrix. This matrix material is unique in its composition and structure. We evaluated the oxygen quenching effects, and thus the pressure sensitivity, of the fabricated films in terms of various processing parameters. Based on the experimental results, we anticipate that a good but new pressure sensitive paint would be presented through further elaboration of the polymer compositions and optimization of the processing conditions.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.688-693
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• 2003

The PSP technique has been used to measure pressure distribution on a model surface quantitatively. The objective of this study is to develop PSP technique which can be applied to low-speed flows. Four different PSP formulations including two porphyrins (PtOEP and PtTFPP) and two polymers (Poly(TMSP) and RTV-118) were tested and the performance of each combination was checked. In the static calibration, the luminescent intensity of the PSP coatings was measured from 0kPa to 11kPa with 0.5, 1, 2kPa increments. Among 4 PSP formulations tested, the combination of PtOEP and RTV-118 shows the best performance. The PSP technique was applied to an oblique impinging jet to measure the pressure field distribution on the impinging plate.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2004년도 Proceedings of 2004 Korea-Japan Joint Seminar on Particle Image Velocimetry
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• pp.75-80
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• 2004

Aerospike nozzles have been expected to be used for an engine of a reusable space shuttle to respond to growing demand for rocket-launching and its cost reduction. In this study, the flow field structures in any cross sections around clustered linear aerospike nozzles are visualized and analyzed, using laser induced fluorescence (LIF) of nitrogen monoxide seeded in the carrier gas of nitrogen. Since flow field structures are affected mainly by pressure ratio, the clustered linear aerospike nozzle is set inside a vacuum chamber to carry out the experiments in the wide range of pressure ratios from 75 to 200. Flow fields are visualized in several cross-sections, demonstrating the complicated three-dimensional flow field structures. Pressure sensitive paint (PSP) of PtTFPP bound by poly- IBM -co-TFEM is also applied to measurement of the complicated pressure distribution on the spike surface, and to verification of contribution of a truncation plane to the thrust. Finally, to examine the effect of the sidewalls attached to the aerospike nozzle, the flow fields around the nozzle with the sidewalls are compared with those without sidewalls.