• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2316-2318
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• 2011

A novel technology has been developed for the synthesis of thioglycolic acid (TGA)-capped CdSe quantum dots (QDs) in aqueous medium. The reaction was carried out in air atmosphere with one-pot by using $SeO_2$ to replace Se or $Na_2Se$. The technological parameters including refluxing time, pH values and molar ratios of selenium to cadmium had significant influence on the luminescence properties of CdSe QDs. Furthermore, the obtained QDs were characterized by fluorescent spectroscopy, X-ray powder diffraction (XRD) and transmission electron microscopy (TEM), respectively. The results demonstrated that the CdSe QDs were of zinc-blended crystal structure in a sphere-like shape.

• Journal of the Korean Institute of Telematics and Electronics
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• v.26 no.9
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• pp.1436-1443
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• 1989

In this paper, we propose a maximum-likelihood estimation(MLE) method to obtain the location and the amplitude of the pulses in MPE( multi-pulse excitation)-LPC speech synthesis using multi-pulses as excitation source. This MLE method computes the value maximizing the likelihood function with respect to unknown parameters(amplitude and position of the pulses) for the observed data sequence. Thus in the case of overlapped pulses, the method is equivalent to Ozawa's crosscorrelation method, resulting in equal amount of computation and sound quality with the cross-correlation method. We show by computer simulation: the multi-pulses obtained by MLE method are(1) pseudo-periodic in pitch in the case of voicde sound, (2) the pulses are random for unvoiced sound, (3) the pulses change from random to periodic in the interval where the original speech signal changes from unvoiced to voiced. Short time power specta of original speech and syunthesized speech obtained by using multi-pulses as excitation source are quite similar to each other at the formants.

• The Journal of the Acoustical Society of Korea
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• v.15 no.3E
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• pp.37-44
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• 1996

A new method for efficient modeling of the Head-Related Transfer Functions(HRTF's) without loss of any directional information is proposed. In this paper, the HRTF's were empirically measured in a real room and modeled as the ARMA models with common AR coefficients and different MA coefficients. To assess the validity of the proposed ARMA model, psychophysical tests show that the proposed ARMA model, in comparison with the conventional MA model, requires a small number of parameters to represent empirical HRTF's and improves the back-to-front confusions in sound-field localization. Thus, significant simplifications in the implementations of sound-field synthesis systems could be obtained by using the proposed ARMA model.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.14 no.6
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• pp.699-712
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• 1989

This paper describes a method of Korean speech synhes is using format VOCODER. The parameters of speech synthes is are a follows, 1) format F1, F2, and F3 by spectrum moment method and F4, F5 using the length of vocal tract. 2) pitch frequencies obtained by optimu, Comb method using AMDF. 3) short time average energy and short time mean amplitude. 4) The decision method of bandwidth reportd by Fant. 5) voicde/unvoiced discrimination using zerocrossing. 6) excitation wave reported by Rosenberg. 7) gaussian white noise. Synthesis results are in fairly good agreement with original speech.

• Journal of Sensor Science and Technology
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• v.21 no.5
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• pp.385-388
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• 2012

This paper describes the synthesis and characterization of graphene by RTA process. Amorphous 3C-SiC were deposited using APCVD for carbon source and Ni layer were employed for transition layer. Various parameters of the ramping speed, the annealing time and the cooling speed are evaluated for the optimized combination allowed for the reproducible fabrication of graphene using 3C-SiC thin film. For analysis of crystalline Raman spectra was employed. Transferred graphene shows a high IG/ID ratio of 2.73. SEM and TEM images show the optical transparency and 6 carbon network, respectively. Au electrode deposited on the transferred graphene shows linear I-V curve and its resistance is 358 ${\Omega}$.

• Archives of Pharmacal Research
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• v.13 no.4
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• pp.355-358
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• 1990

In order to investigate the cellular mechanisms of hypoglycemic of brazilin, hepatocyte monolayer culture was introduced and, glycogen synthesis rate and insulin binding were measured as parameters. Glycogen synthesis and insulin sensitivity were remarkably augmented by the treatment of brazilin. Brazilin slightely increased insulin binding. Scatchard analysis revealed that this increase in insulin binding was not due to increase in the binding capacity but in binding affinity. These results suggest that the augmentation of hepatic glycogenesis and insulin sensitivity by brazilin may play an important role in the improvement of hyperglycemia.

• Journal of the Korean Ceramic Society
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• v.38 no.11
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• pp.959-961
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• 2001

Nanosized CeO$_2$Powders were prepared under high temperature and pressure conditions by precipitation from metal nitrates with aqueous potassium hydroxide. Spherical shape of CeO$_2$powder was obtained at 175$^{\circ}C$ for 6h. TEM and X-ray diffraction patterns showed that the synthesized particle was crystalline. The average size and size distribution of the synthesized particles were below 30 nm and narrow, respectively. In addition, the effects of synthesis parameters under hydrothermal process are discussed.

• Journal of the Korean Ceramic Society
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• v.43 no.9 s.292
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• pp.588-593
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• 2006

Spinel phase $LiMn_2O_4$ is of great interest as cathode materials for lithium-ion batteries. In this study, SHS (Self propagating High-temperature Synthesis) method to synthesize spinel $LiMn_2O_4$ directly from lithium nitrate, manganese oxide, manganese and sodium chloride were investigated. The influence of Li/Mn ratio, the heat-treated condition of product have been explored. The resultant $LiMn_2O_4$ synthesized under the optimum synthesis conditions shows perfect spinel structure, uniform particle size and excellent electrochemical performances.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.1290-1292
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• 2009

Modified-polyol protocol was utilized for synthesis of green-emitting ($^5D_4-^7F_j$ transitions of $Tb^{3+}$ ion) nanocrystalline $LaPO_4:Ce^{3+}$, $Tb^{3+}$ phosphors. Experimental parameters including chemical composition and annealing temperature were optimized to produce highly efficient, uniformly sized nanophosphors. Spin-deposited layer of $LaPO_4:Ce^{3+}$, $Tb^{3+}$ nanophosphors on glass substrate exhibited a transmittance of more than 80 %, indicating their efficacy for transparent display.

• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.2029-2033
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• 2007

Hydrotalcite, layered double hydroxides (LDH), with hexagonal morphology has been rapidly synthesized by microwave reaction within 1 hour by urea hydrolysis from homogeneous solution. Different synthesis parameters, Mg/Al molar ratio, microwave reaction temperature and microwave power were systematically investigated. Pure hydrotalcite phase was obtained for Mg/Al ratios of 2:1 and 3:1, and higher reaction temperature gave higher crystallinity. The hydrotalcite synthesized at 600W power shows the highest crystallinity and more homogeneous crystal size distribution. The hydrotalcite samples were characterized by powder X-ray diffraction (XRD), simultaneous thermogravimetric/differential thermal analysis (TG/DTA), Fourier Transform Infrared (FT-IR) and Scanning electron micrograph (SEM).