• Title/Summary/Keyword: Syntheses

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Syntheses of Silica Gel Bound Hemin, Biliverdin, and Bilirubin

  • Park, Yong-Tae;David A. Lightner
    • Bulletin of the Korean Chemical Society
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    • v.6 no.2
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    • pp.112-115
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    • 1985
  • 3-Aminopropylsilated silica gel bound hemin, biliverdin, and bilirubin were synthesized by reacting 3-aminopropyl silated silica gel with hemin, biliverdin and bilirubin respectively. The aspects of binding of bilirubin to amino group of 3-aminopropylsilated silica gel were studied using the above synthetic silica immobilized hemin, biliverdin and bilirubin, and oxodipyrromethene.

Efficient Synthesis of Benzoprostacyclins Using Free-Radical and Palladium-Catalyzed Tandem Alkene Insertion Strategies

  • Lee, Nam Ho;Richard C. Larock
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.857-866
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    • 2001
  • Efficient syntheses of PGI2 analogue 2a and its epimer 3 have been accomplished. Using aryl iodide 6 as the common intermediate, either radical or palladium-assisted tandem alkene insertion strategies have been employed for construction of the benzoprostacyclin framework.