• The Journal of the Petrological Society of Korea
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• v.26 no.1
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• pp.13-43
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• 2017

In the Hapcheon area, hypersthene-bearing monzonite (mangerite) and syenite are recognized. The main minerals of syenite are alkali feldspar, plagioclase, amphibole, biotite, and quartz. Anhedral hornblende and biotite are interstitial between feldspar and quartz, indicating that the hydrous minerals were crystallized later on. Based on petrochemical studies of major elements, syenite is alkaline series, metaluminous, and I-type. The variation patterns in the trace and rare earth elements of mangerite and syenite show the features of subduction-related igneous rock such as depletion of HFSE, relative enrichment in LILE to LREE, and negative Nb-P-Ti anomalies. Based on the experimental data and petrographic characteristics of the syenite, Hapcheon syenitic magma is considered to be formed by partial melting in a dry system. SHRIMP U-Pb zircon data yield the Triassic age as $227.4{\pm}1.4Ma$ in mangerite, $215.3{\pm}1.2Ma$ in syenite, and $217.9{\pm}2.6Ma$ in coarse-grained syenite, respectively. The mangerite age is similar to those of post-collisional plutonic rocks in Hongseong (226~233 Ma), Yangpyeong (227~231 Ma), and Odaesan (231~234 Ma) areas in the Gyeonggi Massif. Syenites were intruded after about 10 Ma. The features seen in the mangereite and syenite rocks can be explained by models such as the continental collision and slab break-off and the lithosphere thinning and asthenosphere upwelling model.

• The Journal of the Petrological Society of Korea
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• v.15 no.1 s.43
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• pp.1-9
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• 2006

Sr isotopic compositions are determined from the syenite of Sancheong area, yielding age of $211{\pm}23(2\sigma)$ Ma and $^{87}Sr/^{86}Sr$ initial ratio of $0.70598{\pm}0.00060$. Such result confirms that Sancheong syenite was emplaced during the Mesozoic around the Triassic-Jurassic boundary. Rather low initial $^{87}Sr/^{86}Sr$ ratio suggests insignificant influence of old crustal materials. There are strong contrast in rock types of plutonic associations between Sancheong-Macheon area and adjacent Hamyang-Geochang area to the north, i.e. syenite-diorite-gabbro and granite-granodiorite respectively. $^{87}Sr/^{86}Sr$ initial ratios also show distinction between these areas. Such differences suggest regional contrast in tectonic environments between them.

• Economic and Environmental Geology
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• v.36 no.6
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• pp.407-413
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• 2003

The geology of the Apdong Nb-Ta deposit, is hosted by alkali metasomatites, consist of Upper Proterozoic sedimentary rocks, alkali syenites(Hoamsan intrusive) of Phyonggang Complex(late Paleozoic to early Mesozoic), Jurassic granite and Quaternary basalt. Alkali syenites are distinguished as alkali amphibole-pyroxene syenite, alkali amphibole-biotite syenite, biotite-nepheline syenite, biotite syenite, and quartz-alkali amphibole-pyroxene syenite. Alkali metasomatites are the products of intense post-magnatic metasomatism, and form the Nb-Ta ore bodies as the belt, irregular vein and lenticular types in the southern part of Hoamsan intrusive. The ore mineralization is characterized by the occurrence of pyrochlore, zircon, and small amounts of columbite, fergusonite. magnetite, fluorite, molybdenite, ilmenite, titanite, apatite, and monazite. Pyrochlore is one of the niobium/tantalum oxides and contains substantial amounts of rare earths and radioactive elements. The compositional varieties of pyrochlore can be defined: (1) enriched in tantalum, uranium and cerium, (2) substantially tantalum- and fluorine-poor, and (3) enriched in thorium or barium. The geochemical characteristics, ore textures and mineral occurrences indicate that alkali metasomatism of the mineralizing fluid was the dominant ore-forming process.

• The Journal of the Petrological Society of Korea
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• v.24 no.1
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• pp.25-54
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• 2015

Syenite is not a common rock, unlike granitic rocks formed the major component of the continental crust. The aim of this study is to decipher the occurrences and detailed descriptive characteristics of the syenite distributed in Sancheong area, and to investigate the petrogenesis of the syenitic magma based on geochemical study. The dominant minerals in syenite are alkali feldspar (usually orthoclase and rarely microcline), plagioclase, amphibole, biotite, and quartz. Syenites are found in a wide variety of colors. The anhedral hornblende and biotite filling the boundary of feldspar and quartz indicate that the hydrous minerals were crystallized lately, and that water was insufficient at the beginning of crystallization in magma. According to the analysis of mineral composition, amphibole in syenite is mostly ferro-edenite, and the pressure is calculated as 3.3~4.9 kb with 11.9~17.3 km of emplacement depth. Biotite and pyroxene are plotted in the region of annite and hedenbergite, respectively. Based on petrochemical studies of major elements, syenite belongs to alkaline series, metaluminous, and I-type. On the other hand, the variation patterns of trace and rare earth elements of syenite differ from the patterns of diorite and granite. In the geochemical characteristics, syenite is different from gabbro-diorite spatially adjacent to syenite, as well as granite. These results suggest that each rock has been generated from the different sources of magma. Additionally, based on the experimental data, the syenitic magma can be formed (1) by the partial melting at a high pressure and dry system, (2) when the initial crystallization minerals to be residue with migration of the residual melts separated from the ascending cotectic magma (3) when fluorine compositions to be plentiful in the protolith and/or at depth of the magma. Based on the petrographic characteristics of the syenite, Sancheong syenitic magma may have been formed by partial melting in a dry system.

• Economic and Environmental Geology
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• v.11 no.2
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• pp.47-57
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• 1978

The study focused on the petrology and petrochemistry of the so called "Ganghwa syenitic rocks" which intruded into metasediment of basement in southeastern part of Ganghwa Island. The geologic sequence of the mapped area was shown in table 1, 10 model analyses and 7 chemical analyses on the rock samples taken from the Ganghwa syenitic rocks and Manisan granite have been used to discuss the nomenclature of the rocks and petrological relationship between rock types. The petrograpical and petrochemical features based on, the analyses are as follows: 1) Ganghwa syenitic rocks consist of Ganghwa alkali syenite and Ganghwa diorite porphyry which based on the classification of the subcommision on systematics of igneous of IGUS. Ganghwa diorite porphyry which occured as dike forms are intruded into Ganghwa alkali syenite. The rock forming minerals of Ganghwa alkali syenite are composed of perthite, plagioclase, quartz, hornblend and chlorite in major, and zircon, apatite, sericite and magnetite in minor. Ganghwa diorite porphyries consist of plagioclase, biotite, hornblend, orthoclase and chlorite, with, porphyritic texture. 2) In silica-oxides variation (Fig. 2) and AMF diagram (Fig_ 3), the Ganghwa alkali syenite is similar to the trend of Daly's average basalt-andesite-dacite-rhyolite than Skaergaard which shows the trend of the fractional crystallization of magma, and equivalent to the alkali rock series by Peacock. 3) The general trend of data points shift to plagioclase, and are superimposed on the alkali rich terminal part of the granodiorite province of SW Finland in normative Q-Kf-Pl(Fig. 4) and Or-Ab-An diagram respectively. The above-mentioned evidences suggested that the Ganghwa syenitic rocks are the differential products resulted by assimilation of intermediated magma and metasedment rock under relatively rapid cooling condition.

• Geosciences Journal
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• v.22 no.6
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• pp.921-938
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• 2018

The Motzfeldt intrusions in the Gardar Province, southern Greenland, split into syenitic plutonic and hypabyssal rocks, in which the latter include ring dykes and sheet intrusions. Sheet intrusions, considered as the source for rare earth elements (REE) and high field strength elements (HFSE), comprise sheets of peralkaline microsyenite (SPM), syenitic pegmatite (SP), and peralkaline microsyenite (PM). SP exhibits extremely high concentrations of REE and HFSE, which are positively correlated with increasing alkalinity from early towards late intrusion, caused by magmatic processes. In contrast, some of the SPM and PM are also significantly enriched in REE and HFSE, caused by post-magmatic fluids. The REE- and HFSE-rich phases in SP consist mainly of zircon and allanite with smaller amounts of pyrochlore in pseudomorph from the inferred eudialyte, whereas some of the PM and SPM consist of pyrochlore, REE-carbonate, and zircon in the matrix. The zircon grains in the Motzfeldt Sø Formation (MSF) syenite occur in interstitial spaces, exhibiting an association with magnetite and a bipyramidal form in texture. They are characterized by a highly fractured and embayed rim. Zircons from PM and SP are clearly enriched in Fe, Al, Ca, Na, Y, P, Hf, Y, P, Nb, Ta, and REE, and are depleted in Zr and Si in comparison with magmatic zircon. They also show a clear trend of higher LREE/HREE and $Eu/Eu^{\star}$ ratios, and lower $Ce/Ce^{\star}$ ratios, which define them as typical hydrothermal zircons. In contrast, zircons from the MSF syenite show a relatively lower LREE/HREE ratio and Eu and Ce anomalies of a similar magnitude compared with those from SP and PM. The occurrence and mineral composition of the zircon suggest that post-magmatic fluids have played an important role in the remobilization of REE and HFSE as well as the primary concentration of REE and HFSE, caused by magmatic processes.

• Economic and Environmental Geology
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• v.19 no.2
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• pp.123-131
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• 1986

This study is focused on petrochemistry and petrogenesis of alkali granite which exposed at northern area of the Uljin mine in NE Korea. The rock is corresponded to the range of alkali feldspar granite and alkali feldspar quartz syenite on IUGS classification and contains characteristic Fe-rich biotite (annite) and sodic alkali amphibole (arfvedsonite). The alkali granite is the hypersolvus one-feldspar granite which is characterized by the absence of plagiclase except as a component of perthite and its normatve An contents are less than 5wt%. The bulk compositions of the alkali granite show reverse trends compared to Daly's. Tuttle and Bowen (1958) experimentally support that properties of the hypersolvus granite indicate that they have crystallized at high temperatures from a magma.

• Economic and Environmental Geology
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• v.13 no.3
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• pp.185-192
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• 1980

The rocks exposed in the investigation area are andesite of Late Cretaceous age, and syenite and aplitic granite of Bulgugsa Series of Early Cretaceous Period, which is intruded in the older andesitic rock. The strike and dip of major joint is $N10^{\circ}$ to $60^{\circ}E$, and $70^{\circ}SE$ to vertical respectively. According to seismic exploration, lower velocity zone, deemed to be fractured and/or crushed zone, is appeared along the gully center of east flank of the area. Test drilling shows that andesite bedrock is mostly very hard, massive, and very fine to medium grained and has almost 100 percent RQD and core recovery. In comparision with andesitic bedrock, intruded syenite cores show that it is highly crush especially at the depth from 55m to 63m.

• The Journal of the Petrological Society of Korea
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• v.27 no.4
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• pp.223-233
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• 2018

In this study, SHRIMP zircon U-Pb dating was performed on deformed granitic rocks in the Sancheong area in the northeastern part of the Jirisan area, southwest of Yeongnam Massif. Until now, these have been known as Precambrian or age-unknown old igneous rocks, but the U-Pb concordant ages obtained from two samples are $237.8{\pm}4.0Ma$ and $230.2{\pm}3.4Ma$, respectively, showing their emplacements in Early to Middle Triassic. These results indicate that the deformed granite was emplaced at about 238~230 Ma. The study area shows the characteristics of ductile deformation with prominent development of foliation, augen structure, and lineation. It is observed that the deformed granites occur as xenoliths within the syenite, indicating that the time of deformation is earlier than the intrusion of the syenite of about 220 Ma. The emplacement and deformation periods of the deformed granite is similar to that of Permo-Triassic granite gneisses distributed in the Gimcheon and Andong areas of the Yeongnam Massif. Taken together, the eastern part of the Yeongnam Massif, extending from the central part to the southwestern part, granite intrusions occurred at about 260-230 Ma, followed by metamorphism-deformation of about 230-220 Ma.

• Economic and Environmental Geology
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• v.5 no.1
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• pp.1-20
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• 1972

A large anorthositic mass outcropped as mushroom-like body extending up to 46km which occurs in the Hadong kaoline district of southern Korea. The anorthositic mass is in contact with the metamorphic, plutonic and sedimentary rocks. The metamorphic rocks are of granitic gneiss and banded gneiss, etc; the plutonic rocks are of gabbroic and dioritic rocks, schistose granite, syenite, diorite and granite. The sedimentary rocks include siltstone and pebbly sandstone of Lower Gyeongsang System, Cretaceous in age. The anorthositic mass shows a gradational contact with the metamorphic and sedimentary rocks, and is cut by the plutonic rocks except gabbroic and dioritic rocks. The anorthositic mass is leucocratic in the central portion of the mass, and, in turn, grades to rock phases in which ma/ic minerals are irregularly scattered, then to the well-lineated rock and finally to the banded gneiss. Lineation of the anorthositic mass is accordant with that of the surrounding banded gneiss, and the lineation continues toward the gneiss. In some places, the rock phases in which mafics are scattered is gradational with adjacent sedimentary rocks. The anorthositic mass in contact with gabbroic and dioritic rocks shows spotted features. Various replacement features seen under the microscope and paragenetic sequence of the mineral components in the anorthositic rocks cannot be considered as the origin of magmatic crystallization. From the field and microscopic observations, it is concluded that the anorthositic mass was formed from replacement of the metamorphic rocks and plutonic rocks by the anorthositic magma.