• Title/Summary/Keyword: Swollen surface

Search Result 54, Processing Time 0.032 seconds

Study on Pulp Fibers and Paper Morphology by ESEM and LTSEM

  • Kim, Chul-Hwan;Yang, Jae-Kyung;Park, Chong-Yawl
    • Journal of the Korean Wood Science and Technology
    • /
    • v.29 no.3
    • /
    • pp.73-82
    • /
    • 2001
  • The ESEM could be used in investigating the fibrous networks developed during handsheet-forming processes with the exception of the stages relating to the actual dispersion of the fibers and the drying of formed sheets. Also the cross-sectional images of swollen fibers were generated with the ESEM but the information given by the images was rarely fresh compared to the CLSM images. The LTSEM was extremely useful in generating images of the microfibrillar structure of a wet fiber with great resolution. However, pretreatment required in the LTSEM chamber was somewhat tedious due to the time consumed in sublimation of ice and sputter coating. For observation of lamellar structure of a hydrated fiber, the LTSEM exhibited greatly detailed structure with high resolution. Finally ESEM and LTSEM should be used in a finite field such as observation of surface morphology in detail.

  • PDF

Mucous Cells and Their Structure on the Epidermis of Five Appendages in the Korean Flat- headed Goby, Luciogobius guttatus (Pisces; Perciformes) (한국산 미끈망둑 Luciogobius guffafus(농어목) 5개 부속지의 표피구조 및 점액세포)

  • Park, Jong-Young;Kim, Ik-Soo;Lee, Yong-Joo;Baek, Hyun-A
    • Korean Journal of Ichthyology
    • /
    • v.17 no.3
    • /
    • pp.167-172
    • /
    • 2005
  • The flat-headed goby, Luciogobius guttatus, inhabits tidepools and river mouths, and stays under stones on the dried bottom for the duration of the low tide. To know the relationship of its respiration and habit in this fish, the epidermis of five appendages was observed. The epidermis has three layers: the outermost layer, middle layer and stratum germinativum. The outermost layer is composed of polygonal cells or rather flattened cells, and mucous cells. The unicellular mucous cells showing acid mucopolysaccharides are 11.1 to $16.1{\mu}m$ in mean height and in one or two rows. The middle layer consists mainly of large epidermal cells that are swollen by adjacent epidermal cells and arranged in a web-shaped structure. The swollen cells are 12.3 to $15.2{\mu}m$ in mean height and arranged in one to 11 layers. Since the swollen cells occupy the entire height of the epidermis, the epidermis is thick. A large number of blood capillaries are present just below the stratum germinativum. Taste buds are distributed at intervals on the surface of the epidermis. Based on these epidermal strucures, it is likely that L. guttatus utilizes cutaneous respiration in a dual respiratory systems.

Analysis of Body Surface Developments for the Pattern of Armhole line (길의 진동둘레선 설계를 위한 체표전개도 분석에 관한 연구)

  • 이정란
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.21 no.6
    • /
    • pp.1031-1040
    • /
    • 1997
  • This study was done to analyze the body surface developments of armhole area. The major conclusions of this study are: 1. The body surface developments showed the characteristics of expansion and contraction of body at armhole area. By arm movements, front armhole lines on the body surface developments of upper arm were slow going, but back armhole lines were full and round. As a whole, armhole line of the back torso was swollen outside especially at backarmpit point area, it seemed like a line of raglan sleeve. 2. Regression Analysis was carried out to adapt armhole line on the upper arm and upper body to bodice and sleeve pattern, following the axillary circumference line and chest breadth line changed to the basic pattern form. As the result, armhole lines of 90$^{\circ}$ and 135-180$^{\circ}$ movements deviated from those of standard posture. U-type, clear armhole curve of standard posture turned to V-type, slanting line by arm movements.

  • PDF

Mechanistic examination of pre-exfoliating confinement of surface-functionalized nanobeads within layered silicates

  • Lee, Sang-Soo;Khvan, Svetlana;Kim, Jun-Kyung
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.190-190
    • /
    • 2006
  • The approach used in present work allows achieving highly exfoliated state of layered silicate s through confinement of the charged nanobeads within the gallery of swollen pristine clay. The latter is principally promoted by ion exchange that involves polar functional groups on the surface of nanobeads and sodium cation in the interlayer gallery of layered silicates. Surface functionality of the nanobeads plays crucial role in establishment of strong interactions with silicate surface, and eventually, dispersion of individual silicate nanoplatelets.

  • PDF

Textile Surface Modification by Environmentally Friendly Waterborne Fluorinated Acrylate Copolymer (환경친화형 수분산성 불소 아크릴레이트 공중합체에 의한 섬유 표면개질)

  • Yoo Su-Yong;Kim Jung-Du;Moon Myung-Jun;Suh Cha-Su;Ju Chang-Sik;Lee Min-Gyu
    • Journal of Environmental Science International
    • /
    • v.13 no.10
    • /
    • pp.947-953
    • /
    • 2004
  • Waterborne fluorinated acrylate copolymer (WFAC) for surface modification of textile was synthesized from perfluoroalkyl ethyl acrylate, octadecyl acrylate, glycidyl methacrylate, surfactant and 3,3 methyl-methoxy butanol. The structures of the synthesized WFAC were determinated by FT-IR and $^{19}F-NMR$ analysis. The thermal stability investigated with DSC and TGA was decreased with increasing the content of fluorinated acrylate in the copolymer. However, the particle sizes of WFAC were increased with increasing the content of fluorinated acrylate in the copolymer. The surface energies calculated by contact angles of WFAC were in the range of 29.80$\~$13.41 dyne/cm. On the observing SEM of the textile surface treated with WFAC, the textile was swollen and compacted with increasing the concentration of water repellency agent. WFAC synthesized in this study showed a good water repellency.

Core-Shell Polymerization with Hydrophilic Polymer Cores

  • Park, Jong-Myung
    • Macromolecular Research
    • /
    • v.9 no.1
    • /
    • pp.51-65
    • /
    • 2001
  • Two-stage emulsion polymerizations of hydrophobic monomers on hydrophilic seed polymer particles were carried out to make core-shell composite particles. It was found that the loci of polymerization in the second stage were the surface layer of the hydrophilic seed latex particles, and that it has resulted in the formation of either eccentric core-shell particles with the core exposed to the aqueous phase or aggregated nonspherical composite particles with the shell attached on the seed surface as many small separated particles. The driving force of these phenomena is related to the gain in free energy of the system in going from the hydrophobic polymer-water interface to hydrophilic polymer-water interface. Thermodynamic analysis of the present polymerization system, which was based on spreading coefficients, supported the likely occurrence of such nonspherical particles due to the combined effects of interfacial free energies and phase separation between the two polymer phases. A hypothetical pathway was proposed to prepare hydrophilic core-hydrophobic shell composite latex particles, which is based on the concept of opposing driving and resistance forces for the phase migration. It was found that the viscosity of the monomer-swollen polymer phase played important role in the formation of particle morphology.

  • PDF

Preparation of Porous Silica-Pillared Montmorillonite: Simultaneous Intercalation of Amine-Tetraethylorthosilicate into H-Montmorillonite and Intra-Gallery Amine-Catalyzed Hydrolysis of Tetraethylorthosilicate

  • Gwon, O Yun;Park, Gyeong Won;Jeong, Sun Yeong
    • Bulletin of the Korean Chemical Society
    • /
    • v.22 no.7
    • /
    • pp.678-684
    • /
    • 2001
  • Porous silica-pillared montmorillonites were prepared by simultaneous intercalation of dodecylamine-TEOS [tetraethylorthosilicate, Si(OC2H5)4] into the H-montmorillonite and intragallery amine-catalyzed hydrolysis of TEOS. Mixtures of the H-montmorillonite, dodecylamine and TEOS at molar ratios of 1 : 2 : 15-30 and 1 : 2-6 : 20 resulted to swollen and viscous gel once at room temperature, allowing intercalation compounds which dodecylamine and TEOS were simultaneously intercalated into interlayer of H-montmorillonite. The hydrolysis of the gallery TEOS was conducted in water solution for 40 min at room temperature, affording siloxane-pillared H-montmorillonite. Calcination of samples at 500 $^{\circ}C$ in air resulted in silica-pillared montmorillonite with large specific surface areas between 403 and 577 m2 /g, depending on the reaction stoichiometry. The reaction at H-montmorillonite : dodecylamine : TEOS reaction stoichiometries of 1 : 2 : 15 and 1 : 4 : 20 resulted in high specific surface areas and mesopores with a narrow pore size distribution. Result indicates that the intragallery-amine catalyze the hydrolysis of gallery-TEOS and simultaneously have a role of gallery-templated micellar assemblies.

Tegumental Ultrastruetures of Echinostoma hoytense observed by Scanning Electron Microscopy (Echinostoma hortense 표피의 주사전자현미경적 관찰)

  • 이순형;홍성종
    • Parasites, Hosts and Diseases
    • /
    • v.24 no.1
    • /
    • pp.63-70
    • /
    • 1986
  • The tegumental ultrastructures oi Echinostoma hortense adults were observed by scanning electron microscopy. The worms of 4 weeks of age were harvested from albino rats experimentally infected with the metacercariae obtained from the loach. The results were as follows: 1. The worms were leaf-like and their anterior end portion, including oral sucker and head crown, ventrally curved to face posteriorly. The tegument of whole body was wrinkled transversely and covered with cobblestone-like cytoplasmic processes. 2. The oral sucker had roundly swollen (type I ) sensory papillae on the ventral half of its lip and mini-ciliated knob-like (type I ) sensory papillae, arranged in 2∼3 rows, on the dorsal outer surface. 3. Aspinous ventral sucker had many of type I papillae arranged in a circular band on its outer surface. The tegument around the genital opening was of similar feature to the ventral sucker, but sensory papillae were hardly found around the former. 4. Scale-like spines with broad base and round tip were distributed densely on the tegument anterior to the ventral sucker but they became sparse in posterior half of the ventral surface, finally to disappear at posterior extremity. A few number of type I papillae were observed on the ventral surface. The results suggest that the tegument of 5. hortense is similar to that of other echinostomes etapecially 5. revolutum. But the number and arrangement of collar spines, and/or the type and distribution of sensory papillae seem characteristic features of E. hortense differed from other echinostomes.

  • PDF

Ultrastructure of the Epiphytic Sooty Mold Capnodium on Walnut Leaves

  • Kim, Ki Woo
    • 한국균학회소식:학술대회논문집
    • /
    • 2015.11a
    • /
    • pp.14-14
    • /
    • 2015
  • Cellular aspects of sooty mold on walnut leaves were investigated by using light and electron microscopy. A black coating developed on the adaxial leaf surface of a walnut tree. No infestations were found on the abaxial leaf surface with peltate glandular trichomes. Light microscopy showed that fungal complexes from the leaf surface were composed of brown conidia and hyphae. Conidia, with longitudinal and transverse septa, were variable in length ranging from 10 to $30{\mu}m$, and commonly found in clusters, forming microsclerotia. Neither epidermal penetration nor hyphal entrance to host tissues was observed. Based on their morphological characteristics, the fungal complexes were assumed to be Capnodium species. An electron-dense melanized layer was present on the cell wall of multi-celled conidia. Concentric bodies in the fungal cytoplasm had an electron-translucent core surrounded by an electron-dense margin with a fibrillar sheath. Chloroplasts without starch granules in the palisade mesophyll cells of sooty leaves had electron-dense stromata and swollen plastoglobuli. These results suggest that the epiphytic growth of fungal complexes can be attributed to the melanized layer and concentric bodies against a water-deficient environment on the leaf surface. Ultrastructural characteristics of the sooty leaves indicate typical features of dark-adapted and non-photosynthetic shade leaves.

  • PDF

Fabrication of Pre-Exfoliated Clay Masterbatch via Exfoliation-Adsorption of Polystyrene Nanobeads

  • Khvan, Svetlana;Kim, Jun-Kyung;Lee, Sang-Soo
    • Macromolecular Research
    • /
    • v.15 no.1
    • /
    • pp.51-58
    • /
    • 2007
  • The approach studied in the present work produced an exfoliated state of clay layers via confinement of the charged nano-sized polystyrene (PS) beads within the gallery of swollen pristine clay. It was demonstrated that adsorption of the polymer nanobeads dramatically promotes expansion of the clay gallery. A comparative study of incorporation was conducted by employing organo-modified clay along with two different colloid polymer systems: electrostatically stabilized PS nanobeads and cationic monomer-grafted PS nanobeads. The mechanism of adsorption of the monomer-grafted polymer beads onto clay via cationic exchange between the alkyl ammonium group of the polymer nanobeads and the interlayer sodium cation of the layered silicate was verified by using several techniques. As distinct from the polymer nanobeads formed using conventional miniemulsion polymerization method, competitive adsorption of stabilizing surfactant molecules was be prevented by grafting the surface functional groups into the polymer chain, thereby supporting the observed effective adsorption of the polymer beads. The presence of surface functional groups that support the establishment of strong polymer-clay interactions was suggested to improve the compatibility of the clay with the polymer matrix and eventually play a crucial role in the performance of the final nanocomposites.