• Title/Summary/Keyword: Swelling pattern

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Effects of Cross-linked RS 4 starches on Pasting Profiles of Wheat Starch using RVA (밀전분의 RVA 호화특성에 가교결합 RS 4 저항전분의 첨가가 미치는 영향)

  • Shin, Mal-Shick;Mun, Sae-Hun;Woo, Kyung-Soo
    • Korean Journal of Food Science and Technology
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    • v.33 no.1
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    • pp.157-160
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    • 2001
  • RS yields and swelling powers of cross-linked RS 4 starches and effects of RS 4 starches on the pasting profiles of RS 4 added wheat starch were measured using RVA. RS yields by AOAC method were different among RS 4 starches and RS levels were higher in low swelling RS 4 starches than moderate swelling RS 4 starches. Swelling power was different with botanical source of starch and preparing procedure of RS 4 starches. The pasting curves of RS 4 added wheat starches showed increasing initial pasting temperature and lower viscosity but the patterns were similar to those of wheat starch. The pasting viscosity pattern of RS 4 added wheat starches was related with swelling power of RS 4 starch.

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Comparison of Some Physicochemical Properties of Ginger Root and Cross-linked Corn Starches (생강 전분과 옥수수 가교 전분의 이화학적 성질 비교)

  • Hur, June;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.16 no.2
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    • pp.201-205
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    • 1984
  • Some physicochemical properties of ginger root (Zingiber officinale) starch were compared with those of cross-linked corn starch. The ginger root starch that contained 23.5% amylose had a water-binding capacity of 99.1% and a B-type X-ray diffraction pattern. The optical transmittance of the ginger root starch suspension increased from $70^{\circ}C$ and showed a similar pattern to cross-linked corn starch. Solubility studies revealed that both ginger root and cross-linked corn starches had low swelling power and solubility in water up to $90^{\circ}C$, and reduced solubility in potassium hydroxide. Brabender amylograph data indicated that the ginger root starch (7%) had a relatively high initial pasting temperature $(81.5^{\circ}C)$ and was stable against heat and mechanical shear, which resembled to the cross-linked corn starch.

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Fixed Abrasive Pad with Self-conditioning in CMP Process (Self-conditioning 고정입자패드를 이용한 CMP)

  • Park, Boumyoung;Lee, Hyunseop;Park, Kihyun;Seo, Heondeok;Jeong, Haedo;Kim, Hoyoun;Kim, Hyoungjae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.4
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    • pp.321-326
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    • 2005
  • Chemical mechanical polishing(CMP) process is essential technology to be applied to manufacturing the dielectric layer and metal line in semiconductor devices. It has been known that overpolishing in CMP depends on pattern selectivity as a function of density and pitch, and use of fixed abrasive pad(FAP) is one method which can improve the pattern selectivity. Thus, dishing & erosion defects can be reduced. This paper introduces the manufacturing technique of FAP using hydrophilic polymers with swelling characteristic in water and explains the self-conditioning phenomenon. When applied to tungsten blanket wafers, the FAP resulted in appropriate performance in point of uniformity, material selectivity and roughness. Especially, reduced dishing and erosion was observed in CMP of tungsten pattern wafer with the proposed FAP.

Fabrication and Characterization of 3-D Porous Collagen Scaffold (3차원 다공성 콜라겐지지체의 제조 및 특성 분석)

  • Kim, Jin-Tae;Lim, Sumin;Kim, Byoung Soo;Lee, Deuk Yong;Choi, Jae Ha
    • Journal of Biomedical Engineering Research
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    • v.35 no.6
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    • pp.192-196
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    • 2014
  • Collagen scaffolds were synthesized by cross linking into a solution mixture of 1-ethyl-3-[3-dimethylaminopropyl] carbodiimide hydrochlorid(EDC) in ethanol, followed by pressing, cleaning and lyophilization process after the type I atelo-collagen solutions in D.I water(pH3). The experimental conditions are collagen concentration of 1.0 wt%, 3.0 wt%, 5.0 wt% and differential concentration of cross-linker. Then, parametric studies were performed by varying the parameters to investigate the morphology, the porosity, the swelling ratio and the thickness and genotoxicity of the scaffolds. The scaffolds thickness pattern was regular to concentration of the degree of cross-linker and collagen. It was observed that the swelling ratio, the degree of crosslink, and the pore size(thickness of scaffold) can be controlled by adjusting the collagen, crosslinker. Among the parameters investigated, the smallest thickness can be achieved by collagen, crosslinker concentrate condition. The collagen scaffold is induced no genotoxicity. The lowest swelling ratio, as an indication of the highest degree of crosslink, can be obtained by adding crosslink agent.

Characterization of Cross Linked Hyaluronic Acid Microbeads by Divinyl Sulfone (Divinyl Sulfone으로 가교된 히알루론산 마이크로비드의 특성평가)

  • Kim, Jin-Tae;Lee, Deuk Yong;Jang, Ju-Woong;Kim, Tae-Hyung;Jang, Yong-Wun
    • Journal of Biomedical Engineering Research
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    • v.34 no.3
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    • pp.117-122
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    • 2013
  • Hyaluronic acid(HA) microbeads were synthesized by dropping the sodium hyaluronate(Streptococcus) solutions in NaOH into a solution mixture of divinyl sulfone(DVS) in 2-methyl-1-propanol, followed by stirring, cleaning and drying process at room temperature. The initial experimental conditions are crosslinking time(CLTi) of 5 h, crosslinking temperature(CLTe) of room temperature, injection air pressure(IAPr) of 5 psi, and DVS concentration( DVSc) of 0.2 vol%, respectively. Then, parametric studies were performed by varying the parameters to investigate the morphology, the porosity, the swelling ratio and the size of the beads. The microbead size pattern was not regular to function of the degree of crosslink. It was observed that the swelling ratio, the degree of crosslink, and the pore size can be controlled by adjusting the CLTi, CLTe and DVSc. Among the parameters investigated, the smallest bead size can be achieved by varying the CLTi parameter. The lowest swelling ratio, as an indication of the highest degree of crosslink, can be obtained by varying CLTe.

A novel hydrogel-dispersed composite membrane of poly(N-isopropylacrylamide) in gelatin matrix and its thermally actuated permeation of 4-acetamidophen

  • Chun, Suk-Won;Kim, Jong-Duk
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.04a
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    • pp.50-51
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    • 1995
  • The swelling behavior of hyddrogels has been interested in many applications of drug carriers. These gels show reversible swelling changes in response to pH, electric currcnt, and temperature. Among others, the temperature-responsive behavior of poly(N-isopropylacrylanxide) (p(NIPAAm)) was studied, because a lower critical solution temperature(LCST) is in the vicinity of 32$\circ$C, and remarkable temperature-response can be obtained. We propose a novel composite membrane, which is appropriate for transporting drug ingredients above the transition temperature. Our object was to design a high permeation system above the shrinking temperature of p(NIPAAm). The membrane was composed of a matrix polymer and thermosensitive p(NIPAAm) hydrogel. The flux pattern of 4-acctamidophen through membrane in response of temperature was opposite to that of p(NIPAAm) membrane.

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Physicochemical and Textural Properties of Chestnut Starches (밤전분의 물리화학적 특성과 텍스쳐 특성)

  • 김세권;전유진;김용태;이병조;강옥주
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.4
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    • pp.594-600
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    • 1995
  • To efficiently utilize not only fresh chestnut(FC) but also wormy chestnut(WC), four types of chestnut starches which were fresh chestnut starch(FCS), fresh chestnut crude starch(FCCS), wormy crude starch(WCS) and wormy chestnut crude starch(WCCS) were extracted. Amylose content of FCS(46.5%) and water binding capacity of FCCS(103.0%) were higher than those of othe three, respectively. Swelling powers of all sample starches increased rapidly from 6$0^{\circ}C$ to 8$0^{\circ}C$. Solubilities showed the same pattern as the swelling powers. In the textural properteis investigated with IUTM(instron universal testing machine), hardnesses and elasticties of chestnut starches were 50~58I.U. and 14~16I.U., respectively. The results of textural evaluations showed that it was possible to prepare chestnut mook with FCS, FCCS and WCS.

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A Case of Lichen Planus of the Sole (족척에 발생한 편평태선 증례보고 1례)

  • Kim, Chan-Jung;Han, Eun-Jeong;Chae, Byung-Yoon
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.14 no.2
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    • pp.39-43
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    • 2001
  • Lichen planus is a unique inflammatory cutaneous and mucous membrane reaction pattern of unknown etiology. Lichen planus of the soles generally occurs as an isolated phenomenon. The lesions differ from classic lesions of lichen planus in that the papules are larger and aggregate into semitransluecent plaques with a globular waxy surface. We report a 38-year-old female patient with lichen planus of right sole. The lesion shows erythematous eroded patch, swelling and severe pain. We thought that she might have envolved erysipelas. So, we gave her oriental medicine and antibiotics, so she was improved. But after long walking, lesion began to getting worse. There appeared oozing, ulcer, pus, pain and swelling in her lesion. We gave her oriental medicine and wet dressinf. But it didn't work.

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Mechanical behavior of composite gel periodic structures with the pattern transformation

  • Hu, Jianying;He, Yuhao;Lei, Jincheng;Liu, Zishun;Swaddiwudhipong, Somsak
    • Structural Engineering and Mechanics
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    • v.50 no.5
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    • pp.605-616
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    • 2014
  • When the periodic cellular structure is loaded or swelling beyond the critical value, the structure may undergo a pattern transformation owing to the local elastic instabilities, thus leading to structural collapse and the structure changing to a new configuration. Based on this deformation-triggered pattern, we have proposed the novel composite gel materials. This designed material is a type of architectural material possessing special mechanical properties. In this study, the mechanical behavior of the composite gel periodic structure with various gel inclusions is studied further through numerical simulations. When pattern transformation occurs, it results in a different elastic relationship compared with the material at untransformed state. Based on the obtained nominal stress versus nominal strain behavior, the Poisson's ratio and corresponding deformed structure patterns, we investigate the performance of designed composite materials and the effects of the uniformly distributed gel inclusions on composite materials. A better understanding of the characteristics of these composite gel materials is a key to develop its potential applications on new soft machines.

Influence of Crosslinking on Gelatinization Behavior and Morphological Change of Potato Starch (가교결합 감자 전분의 호화특성과 형태학적 변화)

  • Kim, Hyang-Sook;Lee, Young-Eun
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.580-586
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    • 1996
  • Gelatinization behavior and morphology of epichlorohydrin-crosslinked potato starches (XPs) were investigated. Native potato starch showed a very steep single stage swlling pattern, but crosslinked starches showed various patterns with the degree of crosslinking. Swelling power, solubility and light transmittance were reduced drastically as the degree of crosslinking increased. Brabender initial pasting temperature and peak temperature of crosslinked starches increased because the crosslinking reinforces the intermolecular net work of the starches. Although the swelling of the potato starch granule was inhibited by crosslinking as compared to that of the native one, Brabender peak viscosities (6.5% w/v, db) were on the order of 2,500 units for the native potato starch, 3,700 for the XP with 2.300 anhydroglucose units per crosslinking (AGU/CL) and 3,400 for the XP with 2,100 AGU/CL, due to the decreased breakdown of the swollen granule resulting from the resistance to heat and shear. The XP with 1,900 AGU/CL, however, did not show the peak viscosity and the viscosity was on the order of 500 units because of the excessive unhibition of the swelling. Unlike the native potato starch, 6.5%(m/v, db) pastes of the crosslinked potato starches could form gels, which could be predicted from the Brabender setback and consistency index. When the degree of crosslinking is low, random contraction and radial swelling of the granule was possible. As the degree of crosslinking increased, morphological change became similar to the single dimensional tangential swelling observed from the lenticular wheat starch. These morphological change during heating in excess water explained the gelatinization behaviors of crosslinked starches tested.

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