• Title/Summary/Keyword: Surface treatment system

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Measurement of Secondary Electron Emission Coefficient and Bimolecular Valence Band Energy Structure of Erythrocyte with and Without Bioplasma Treatment

  • Lee, Jin-Young;Baik, Guyon;Choi, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.483-483
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    • 2012
  • Recently, nonthermal bioplasma has been attracted by researchers due to their potentials to modulate cellular functions resulting in changes of biomolecular electron band structures as well as cell morphologies. We have investigated the secondary electron emission characteristics from the surface of the erythrocyte, i.e., red blood cell (RBC) with and without the nonthermal bioplasma treatment in morphological and biomolecular aspects. The morphologies have been controlled by osmotic pressure and biomolecular structures were changed by well known reactive oxygen species. Ion-induced secondary electron emission coefficient have been measured by using gamma-focused ion beam (${\gamma}$-FIB) system, based on the quantum mechanical Auger neutralization theory. Our result suggests that the nonthermal bioplasma treatment on biological cells could result in change of the secondary electron emission coefficient characterizing the biomolecular valence band electron energy structures caused by the cell morphologies as well as its surface charge distributions.

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A Study on the Rare-earth Boronizing Treatment of STD 61 Steel (열간금형용강의 희토류붕화처리에 관한 연구)

  • Kim, C.C.;Youn, J.H.;Jang, Y.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.4
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    • pp.217-223
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    • 2000
  • The boronizing effects of STD 61 steel have been studied on the micro structure and hardness. The STD 61 Steel was soaked in molten salt, consisted of KCl, $BaCl_2$, NaF, $B_2O_3$, FeB, and Ce, at various temperatures and times. The boronizing conditions for the peak hardness were the temperature range of $900^{\circ}C$ to $950^{\circ}C$ for 5 hr and that of $1000^{\circ}C$ for 3 hr, respectively. Four boride layers such as FeB, $Fe_2B$, ${\alpha}$ and matrix layer surface were observed from the microscopic surface examination. The thickness of boride layer was increased by increasing the boronizing time and the temperature. The structure of boride layer was tooth shape.

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Surface Modification of Cellulose Acetate using $UV/O_3$ Irradiation

  • Lee, Hae-Sung;Jeong, Yong-Kyun;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.35-41
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    • 2006
  • Upon $UV/O_3$ irradiation cellulose acetate (CA) films showed modified surface properties such as increased hydrophilicity and surface roughness as well as increased dyeability to cationic dyes. UV treatment induced photoscission of acetyl groups in the main chain of CA resulting in decreased degree of substitution from 2.2 to 1.3. The slight decreases in reflectance and transmittance were caused by remarkably increased nano-scale surface roughness of the CA surface as much as 20-fold, which can destructively interfere with visible lights of wavelength lower thu 500nm. Water contact angle decreased from $54^{\circ}\;to\;14^{\circ}$ with increasing UV energy. Surface energy also increased slightly. The surface energy change was attributed to significant contribution of polar component rather than nonpolar component indicating surface photooxidation of CA film. The increased dyeability to cationic dyes in terms of both K/S and %E may be due to photochemically introduced anionic and dipolar dyeing sites on the film surfaces.

Optical Properties of PVA Polarizing Films Surface-modified by UV Irradiation (자외선 조사에 의해 표면 개질된 PVA 편광필름의 광학특성)

  • Koo, Gwang-Hoe;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.18 no.6 s.91
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    • pp.49-56
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    • 2006
  • Surface treatment using UV irradiation was carried out to improve optical properties of polarizing films. The effects of UV energy of the UV-treated PVA films were investigated by measuring reflectance, surface roughness, contact angles, ESCA, and ATR. Reflectance decreased at wavelength of 450 nm or less and surface roughness increased with increasing UV energy. Water contact angle increased in the irradiated PVA films and surface energy decreased with increase in w energy. An analysis showed that the OH groups were broken and some new groups were introduced such as C=C and C=O bonds together with increased $O_{1s}/C_{1s}$, resulting in the observed surface modification effect. Surface modified PVA polarizing films showed improvement in light transmittance of polarizing films at high wavelength region without deteriorating polarization efficiency, which was not affected by UV irradiation sequence during manufacturing processes such as coloring and drawing.

Effects of Plasma Treatment on Mechanical Properties of Jute Fibers and Their Composites with Polypropylene (황마섬유 및 황마-폴리프로필렌 복합체의 특성에 미치는 플라즈마 처리영향)

  • Huh, Yang Il;Bismark, Mensah;Kim, Sungjin;Lee, Hong Ki;Nah, Changwoon
    • Elastomers and Composites
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    • v.47 no.4
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    • pp.310-317
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    • 2012
  • A jute fiber surface was modified with argon gas in a cylinder type RF plasma generator to enhance the interfacial bond strength and to optimize the plasma treatment condition. The plasma power, gas pressure, and treat time were varied to figure out any effect of those parameters on the morphology and mechanical strength of jute fibers, and the interfacial bond strength for a model composite with polypropylene resin. As the severity of plasma treatment was increased, the surface of jute fibers became rougher. Gas pressure was less effective in roughening of the surface compared with those of treat time and plasma power. Approximately 25% drop in tensile strength of jute fibers was observed for the parameters of treat time and plasma power, while little deterioration was found for gas pressure, with increasing the severity. Based on the interfacial shear strength (IFSS), the optimum plasma treatment condition was determined to be treat time of 30 s, plasma power of 40 W, and gas pressure of 30 mTorr.

Change of the Moisture and Temperature in Planting Ground as Effected by Different Soil Thickness, Soil Mixture Ratios and Ground Cover Plants in the Green Roof System (옥상녹화에서 토심, 토양배합비 및 지피식물에 따른 식재지반 수분 및 온도변화)

  • Ju, Jin Hee;Yoon, Young Han
    • KIEAE Journal
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    • v.10 no.3
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    • pp.11-16
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    • 2010
  • This paper has attempted to investigate the change in soil moisture volume and temperature of architecture by planting ground(soil thickness and soil mixture ratio) and ground cover plants(Sedum sarmentosum, Zoysia japonica, Chrysanthemum zawadskii) for middle region green roof system. For this, a test was conducted on the roof of Konkuk University building from April 2009 to October 2009. In terms of treatment, five types(SL, $P_7P_1L_2$, $P_6P_2L_2$, $P_5P_3L_2$, $P_4P_4L_2$) depending on soil mixture ratio and two types(15cm, 25cm) by soil depth were created. Results of soil moisture volume by soil mixture ratio in the 15cm soil thickness showed that the difference was significance between simple soil and mixture soil treatment, however, the statistical significance was not recognized according to soil mixture ratio. In case of 25cm soil thickness, soil moisture volume by soil mixture ratio was more higher 7Vol.%~10Vol.% in the mixture soil than simple soil treatment. In terms of districts planted ground cover plants, soil volume moisture differed among plants in the order Zoysia japonica 17.74 Vol.%$34.86^{\circ}C$, district non-planted $27.49^{\circ}C$, Sedum sarmentosum $25.11^{\circ}C$, Chrysanthemum zawadskii $23.08^{\circ}C$, Zoysia japonica $24.45^{\circ}C$ respectively So, concrete surface showed more higher $5^{\circ}C{\sim}15^{\circ}C$ than other things among the all the time. Result of inner temperature of the architecture and soil, it was measured inner of architecture $25.69^{\circ}C$, inner district non-planted $24.29^{\circ}C$, Chrysanthemum zawadskii $23.90^{\circ}C$, Zoysia japonica $24.02^{\circ}C$, Sedum sarmentosum $25.13^{\circ}C$, respectively.

Evaluation of Diffusion on Cement Mortar and Durability of Concrete Specimen Using Inorganic Coating Material and Surface Treatment System (무기질 도료 및 표면처리 시스템을 적용한 시멘트 모르타르와 콘크리트의 내구성 평가)

  • Kim, In-Seob;Lee, Jong-Kyu;Chu, Yong-Sik;Kim, Tae-Hyun;Shim, Kwang-Bo
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.522-528
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    • 2003
  • Concrete has been considered as a semi-permanent structural material, because its excellent durability. However, such high durable structure is often attacked by some environmental condition such as chloride diffusion, carbonation and so on. In order to prevent the deterioration behaviors of concrete structures. We estimated durability of concrete when used surface treatment system and coatings by new type inorganic coating materials. Base on the results of chloride ion's diffusion test, the coated cement mortar had smaller transmitted quantity.

A Study of Homogeneous Sterilization of Micro-sized Food Powder by Rotatable Low-Temperature Plasma System (회전형 저온 플라즈마 시스템을 이용한 분말식품의 균일한 살균 연구)

  • Kim, Myung Chan;Park, Duck Mo;Han, Jin Soo;Woo, In Bong;Kim, Dong Hoo;Jang, Seong Eun;Yoon, Chan Suk;Kim, In
    • The Korean Journal of Food And Nutrition
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    • v.31 no.2
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    • pp.301-307
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    • 2018
  • In this study, a relatively effective process is used to sterilize Escherichia coli on the surface of micro-sized calcium citrate powder using nitrogen and argon as process gases in a low-temperature vacuum plasma treatment. The purpose of this study is to confirm and to introduce the effectiveness of homogeneous surface treatment for the sterilization of fine inorganic powder by the rotatable low-temperature RF plasma system designed by ourselves. The results of the test using 3M petrifilm showed that there were no remarkable spots in the case of the surface of plasma treated powder, whereas the untreated powder showed many blue spots, which indicating that the E. coli was alive. After 5 days, in the same samples, the blue spots were seen to be larger and darker than before, while the plasma-treated powder showed no changes. The results from FE-SEM analysis showed that the E. coli was damaged and/or destroyed by reactive species generated in the plasma space, resulting in the E. coli being sterilized. Furthermore, the sterilization effects according to the selected parameters ($N_2$ and Ar; flow rate 30 and 50 sccm) adapted in this study were mutually similar, regardless of such different process parameters, and this indicates that homogeneous treatment of powder surfaces could be more effective than conventional methods. Therefore, the plasma apparatus used in this study may be a practical method to use in a powerful sterilization process in powder-type food.

Comparison of Surface Characteristics According to 3D Printing Methods and Materials for the Fabrication of Microfluidic Systems (미세유체시스템 제작을 위한 3D 프린팅 방식 및 소재 별 표면특성 비교)

  • Bae, Seo Jun;Im, Do Jin
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.706-713
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    • 2019
  • In this study, basic research was conducted to provide guidelines for selecting printers and materials suitable for each application case by analyzing 3D printing method and surface characteristics of materials suitable for microfluidic system. We have studied the surface characteristics according to the materials for the two typical printing methods: The most commonly used method of Fused Deposition Modeling (FDM) printing and the relatively high resolution method of Stereolithography (SLA) printing. The FDM prints exhibited hydrophilic properties before post - treatment, regardless of the material, but showed hydrophobic properties after post - treatment with acetone vapor. It was confirmed by the observation of surface roughness using SEM that the change of the contact angle was due to the removal of the surface structure by post-treatment. SLA prints exhibited hydrophilic properties compared to FDM prints, but they were experimentally confirmed to be capable of surface modification using hydrophobic coatings. It was confirmed that it is impossible to make a transparent specimen in the FDM method. However, sufficient transparency is secured in the case of the SLA method. It is also confirmed that the electroporation chip of the digital electroporation system based on the droplet contact charging phenomenon was fabricated by the SLA method and the direct application to the microfluidic system by demonstrating the electroporation successfully.

Effect of Disperse Dyeing on UV-curable Flame-retardant Finish of PET Fabrics (분산염료 염색공정이 PET직물의 UV경화형 방염가공에 미치는 영향)

  • Jeong, Yong-Kyun;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.66-74
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    • 2008
  • Effect of disperse dyeing on flame retardant finishing of PET fabrics via UV curing using three UV curable phosphorous-containing methacrylates and ammonium polyphosphate(APP) was investigated. The dye fixation and flame retardancy of PET fabrics did not change significantly with excellent durability to five laundering cycles irrespective of the dyeing and finishing sequence. However, the flame retardancy of Pekoflam-treated fabrics was lower than that of the UV treated and decreased substantially when heat treatment was carried out before the dyeing. The dyeability of the flame-retardant PET fabrics was not affected in the case of UV curing of the methacrylates alone. However, UV finishing after the dyeing caused significant decrease in K/S and ${\Delta}E$ due to changed refraction and inherent color of surface coating of the UV curable monomers and APP. Whereas the heat treatment with Pekoflam decreased both color fastness to laundering and sublimation, surprisingly the UV finish of PET fabrics before and after the dyeing increased the color fastness probably resulting from the presence of photopolymerized surface layer on the fabrics.