• 제목/요약/키워드: Surface to Volume Ratio

검색결과 561건 처리시간 0.026초

Optimization of the Pt Nanoparticle Size and Calcination Temperature for Enhanced Sensing Performance of Pt-Decorated In2O3 Nanorods

  • Choi, Seung-Bok;Lee, Jae Kyung;Lee, Woo Seok;Ko, Tae Gyung;Lee, Chongmu
    • Journal of the Korean Physical Society
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    • 제73권10호
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    • pp.1444-1451
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    • 2018
  • The surface-to-volume ratio of one-dimensional (1D) semiconductor metal-oxide sensors is an important factor for achieving good gas sensing properties because it offers a wide response area. To exploit this effect, in this study, we determined the optimal calcination temperature to maximize the specific surface area and thereby the sensitivity of the sensor. The $In_2O_3$ nanorods were synthesized by using vapor-liquid-solid growth of $In_2O_3$ powders and were decorated with the Pt nanoparticles by using a sol-gel method. Subsequently, the Pt nanoparticle-decorated $In_2O_3$ nanorods were calcined at different temperatures to determine the optimal calcination temperature. The $NO_2$ gas sensing properties of five different samples (pristine uncalcined $In_2O_3$ nanorods, Pt-decorated uncalcined $In_2O_3$ nanorods, and Pt-decorated $In_2O_3$ nanorods calcined at 400, 600, and $800^{\circ}C$) were determined and compared. The Pt-decorated $In_2O_3$ nanorods calcined at $600^{\circ}C$ showed the highest surface-to-volume ratio and the strongest response to $NO_2$ gas. Moreover, these nanorods showed the shortest response/recovery times toward $NO_2$. These enhanced sensing properties are attributed to a combination of increased surface-to-volume ratio (achieved through the optimal calcination) and increased electrical/chemical sensitization (provided by the noble-metal decoration).

성장 중인 쥐에서 음식물의 경도가 하악 과두의 해면골에 미치는 영향 : 미세전산화 단층촬영을 이용한 연구 (THE EFFECTS OF DIETARY CONSISTENCY ON THE TRABECULAR BONE ARCHITECTURE IN GROWING MOUSE MANDIBULAR CONDYLE : A STUDY USING MICRO-CONFUTED TOMOGRAPHY)

  • 윤석희;이상대;김정욱;이상훈;한세현;김종철
    • 대한소아치과학회지
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    • 제31권2호
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    • pp.228-235
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    • 2004
  • 하악 과두의 발달과 증식은 측두하악관절 부위의 생역학적 환경의 변화에 따라 변경될 수 있다. 이 부위에 전달되는 생역학적 하중은 섭취하는 음식물의 경도를 다르게 함으로써 변화시킬 수 있다. 이번 연구의 목적은 성장 중인 쥐에서 부드러운 음식물의 섭취에 의해 저작력을 변화시키는 것이 하악 과두의 해면골의 형태를 변화시킬 수 있는지 미세전산화 단층촬영을 이용하여 분석하는 것이었다. 생후 21일 된 C57BL/6 쥐 36마리를 무작위로 두 그룹으로 나누었다. 8주 동안 대조군의 쥐들은 일반적인 딱딱한 덩어리의 사료를, 실험군의 쥐들은 덩어리의 사료를 잘게 갈은 후 물과 섞어 부드럽게 만들어 먹였다. 또한 실험군의 쥐들의 하악 절치를 일주일에 두 번씩 잘라서 짧게 만들었다. 8주 후 모든 쥐들을 희생하여 우측 하악 과두를 준비하였다. 미세전산화 단층촬영과 삼차원 영상 분석프로그램을 이용하여 하악 과두 해면골의 bone volume(BV), bone surface(BS), total volume(TV) bone volume fraction(BV/TV), surface to volume ratio(BS/BV), trabecular thickness(Tb. Th.), structure model index(SMI)와 degree of anisotropy(DA)를 측정하고 이들 값으로부터 trabecular number(Tb. N.)와 trabecular separation (Tb. Sp.)을 계산하였다 미세전산화 단층영상을 얻은 후 하악 과두의 조직 표본을 만들었다. 연구 결과는 다음과 같았다. 1. Bone volume fraction(BV/TV), trabecular thickness(Tb. Th.)와 trabecular number(Tb. N.)가 대조군에 비해 부드러운 음식을 먹인 실험군에서 유의하게 감소되었다(p<0.05). 2. Trabecular separation(Tb. Sp.)은 부드러운 음식을 먹인 실험군에서 유의하게 증가하였다(p<0.05). 3. Surface to volume ratio(BS/BV), structure model index(SMI), degree of anisotropy (DA)는 두 군 사이에 유의한 차이를 보이지 않았다(p>0.05). 4. 조직 절편을 관찰한 결과, 부드러운 사료를 먹인 실험군에서 하악 과두의 연골층의 증식 층과 전체 두께가 상당히 감소하였다.

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Heat transfer characteristics of redan structure in large-scale test facility STELLA-2

  • Yoon, Jung;Lee, Jewhan;Kim, Hyungmo;Lee, Yong-Bum;Eoh, Jaehyuk
    • Nuclear Engineering and Technology
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    • 제53권4호
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    • pp.1109-1118
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    • 2021
  • The construction of STELLA-2 facility is on-going to demonstrate the safety system of PGSFR and to provide comprehensive understanding of transient behavior under DBEs. Considering that most events are single-phase natural circulation flow with slow transient, STELLA-2 was designed with reduced-height of 1/5 length scale. The ratio of volume to surface area in the vessel can relatively increase resulting in excessive heat transfer. Therefore, a steady-state thermal-hydraulic analysis was performed and the effect of design change to reduce the heat transfer through redan was investigated. The heat transfer through single wall redan in STELLA-2 was 3% of the core power, comparable to 1% of the core power in PGSFR. By applying the insulated redan, about 70% of decrease effect was observed. The effect on transient behavior was also evaluated. The conclusion of this study was directly applied to the STELLA-2 design and the modified version is under construction.

밀폐 공간내 Block에 의한 폭발특성 변화에 관한 연구 (A Study on the Variation of Explosion Characteristics by the Block in Closed Vessel)

  • 오규형;김종복;이성은;김홍;이영철;박승수
    • 한국가스학회지
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    • 제3권3호
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    • pp.23-28
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    • 1999
  • 밀폐공간 내에 블록을 조합하여 부피와 표면적이 다르게 내용물을 채우고 용기 부피에 대한 내용물의 부피와 내용물의 표면적을 변화시키면서 LPG 또는 NG와 공기 혼합가스의 폭발특성을 측정하여 밀폐공간 내부에 있는 내용물의 부피와 표면적의 변화가 폭발특성에 미치는 영향을 해석하고자 하였다. 폭발용기는 가로 세로 높이가 각각 $100cm{\times}60cm{\times}45cm$인 부피 270리터의 금속 용기이며, 용기 내 가연성 혼합가스는 전기 스파크로 착화시켰고, strain형 압력센서로 폭발압력을 측정하였다. 실험 결과 부피봉쇄율이 증가할수록 폭발압력이 감소하였으며, 내용물의 표면적의 증가에 따라서도 폭발압력이 낮아졌으며, 이러한 폭발압력의 감소 경향은 표면적의 증가에 대한 영향보다 부피의 증가에 의한 영향이 더욱 크게 나타났다.

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유기안료 배합이 도공층의 표면 및 광학적 특성에 미치는 영향 (Influence of Organic Pigment Blending on Surface and Optical Properties of Coated Paper)

  • 정경모;원종명;이용규
    • 펄프종이기술
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    • 제44권3호
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    • pp.1-8
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    • 2012
  • The effects of several factors including organic pigment blending and calending conditions on the surface and optical properties of coated paper were investigated. When clay and calcium carbonate are blended in the ratio of 7 to 3, highest smoothness and relative sediment volume were obtained. When organic pigments were added to the mixture of clay and calcium carbonate, the relative sediment volume did not changed significantly. However, when organic pigments were added to calcium carbonate, sheet gloss and smoothness were improved, and showed the better results than that obtained from the mixture of organic pigment and clay. When organic pigment is blended with clay, the particles of organic pigment are buried in the packing structure of coating layer. However, the particle shape of calcium carbonate is quite different from that of clay, and the aspect ratio of calcium carbonate is similar to that of organic pigment. Thus organic pigment particles are not buried and improved effectively the physical characteristics of coating layer. When the hollow sphere pigment was blended, opacity and sheet gloss were improved significantly. Even though the coating color applied was reduced, the similar level of opacity was maintained. Also, if particle size and void volume are increased, gloss is improved, because coating layer is easily transformed in calendering. Therefore, even though lower pressure was applied during calendering, the smoothness of surface of coating layer was improved, and the decrease of void volume in coating layer was reduced, and the quality of coated sheet can be improved.

미생물 입체선택성 가수분해 반응을 이용한 광학활성 Styrene Oxide 생산 (Production of Chiral Styrene Oxide by Microbial Enantioselective Hydrolysis Reaction)

  • 윤성준;이은열
    • KSBB Journal
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    • 제15권6호
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    • pp.630-634
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    • 2000
  • 에폭사이드 가수분해효소 활성이 우수한 Aspergillus niger 를 생촉매로 이용하여 업체선택적 가수분해 반응을 통해 라세믹 styrene oxide 기질로부터 광학활성 (S)-styrene oxide를 생산하는 실험을 수행하였다. (R)-styrene oxide 이성질체에 대한 초기 가수분해 속도에 영향을 주는 실험인자들인 pH, 반응온도, cosolvent 첨가량 등에 대해 중심합성계획법을 이용한 반응표면 분석을 통해 가수분해반응 속도를 향상시킬 수 있는 최적 반응조건을 결정하였다. pH 7.78, 반응온도 2 $28.32^{\circ}C$ 및 cosolvent 첨가량 2.4% (v/v)의 조건에서 약 10시간 정도의 반응을 통해 ee 값이 100%인 광학적으로 순수한 (S)-styrene oxide를 35% 정도(이론수율 = 50%)의 높은 수율로 얻을 수 있었다.

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농업용 저수지 수질과 경험적 인자들과의 관계 (The Relationships Between Empirical Factors and Water Quality in Agricultural Reservoirs)

  • 김호섭;최은미;박주현;황하선;김범철;공동수;황순진
    • 한국물환경학회지
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    • 제24권3호
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    • pp.333-339
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    • 2008
  • This study was carried out to assay the relationships between empirical factors and water quality in 23 agricultural reservoirs. Based on the trophic state index (TSI) deviation analysis, phosphorus in type II and III was the primary limiting factor on algal growth. BOD, COD, TP and chl.a concentration in type III reservoirs showed higher concentration than those of other types, while SS and TN concentration was no noticeable difference among three types. Characteristics of type III reservoirs showed large reservoir surface and drainage area, large surface area to volume (SAV) ratio, small drainage area to reservoir area (DA/RA) ratio, relatively old age, large paddy field and upland field to drainage area ratio (Mean 17.4%) and high generation and discharge loads compared to other types of reservoirs. In type I and II reservoirs, trends of BOD, TN, TP concentration in water column, were similar to those of the discharge load of pollutants. Although type II reservoirs generally showed low phosphorus discharge loads compared to type I reservoirs, TP and chl.a concentration in water column was greater than that of type I. Characteristics of type II reservoirs showed relatively large SAV ratio and old age compared to type I reservoirs and was similar to those of type III including eutrophic reservoirs.

유동화물의 유효자유표면에 관한 연구 (A Study on the Effective Free Surface of Fluid Cargo)

  • 허일;왕지석
    • 한국항해학회지
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    • 제11권2호
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    • pp.73-88
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    • 1987
  • It is well known that the height of tank metacenter above the centroid of fluid in a tank is given by i/v where I is the inertia moment of free surface and v is the fluid volume. It is supposed in this formula that the inclination of ship is small and that the free surface of fluid do not touch the top and the bottom of tank. It the inclination of ship is large, the height of tank metacenter may be possibly greater than that given by i/v. The height of tank metacenter is smaller than i/v when the free surface of fluid touch the top or the bottom of tank. The reasonable method to calculate the height of tank metacenter is presented in this paper and prepared in FORTRAN program by FUNCTION EFFRES. The approximate formula was also developed and given by $g_m=(1+\frac{2}{1}tan^2\theta)[1-EXP\{-12(\frac{\alpha(1-\alpha)k}{tan\theta})^{1.25}\}]\frac{i}{v}$ where $g_m$ is the distance from the centroid of fluid to the tank metacenter, $\theta$ is inclined angle of ship, $\alpha$ is the ratio of filled volume to tank capacity and k is the ratio of the depth to the width of tank. The values calculated by the approximate formula given in this paper were compared with the exact values from the computer program and proved out to be sufficiently precise for practical use.

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소염 거리에 근접하는 소형 연소실 환경에서의 연소특성 (Combustion Characteristics in Small Combustion Chamber Size about Quenching Distance)

  • 이대훈;최권형;권세진
    • 한국연소학회지
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    • 제5권2호
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    • pp.63-68
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    • 2000
  • Combustion phenomenon in scale-downed combustor is investigated. As the combustor scale decreases surface to volume ratio increases and chamber size approaches quenching distance. As the combustor scales down surface to volume ratio increases resulting increased heat loss. And this heat loss can affect quenching and instability of the flame. To investigate this effect plastic mini combustor is made. Stoichiometricaly premixed Hydrogen / air gas is used as fuel. Initial chamber pressure and chamber size are varied and the effects are evaluated. Peak pressure decreased with the decrease in chamber height. As initial chamber pressure decreases peak pressure decreases and this change is more important than scale down effect till the chamber height of 1mm. With this result and further information following the experiments design parameter for micro engine can be established.

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마이크로 추진장치 (Micro Propulsion System)

  • 전재영;윤영빈;허환일
    • 한국추진공학회지
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    • 제5권3호
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    • pp.100-107
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    • 2001
  • Miro propulsion device is a literally very small propulsion system The reason why such a small propulsion system is required is that micro satellites are considered as substitutions for conventional satellites to reduce cost; the fabrication of micro satellites enables us to produce mass production Microrockets have relatively high values of thrust/weight ratio due to the cube law; weight is proportional to volume and thrust is proportional to area. Accordingly, downsizing makes the ratio of thrust/weight ratio high However, conventionally ignorable facts are not negligible any more in small scale systems. for chemical micro rockets, downsizing causes lots of heat loss as surface to volume ratio increases, which results in the destruction of radical ions. For thrusters using plasma, the generation of strong magnetic field for plasma is very difficult. Also, in the aspect of flow dynamics, the effects of drag and viscosity are important parameters in low Re flows. When these problems are solved, micro propulsion systems can be commercialized and result in spin-off effects in many fields.

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