• Analytical Science and Technology
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• v.23 no.6
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• pp.560-565
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• 2010

Perchlorate ion ($ClO_4^-$) has been widely used as oxidizing agent in military weapon system such as rocket and missile fuel propellant. So it has been challenging to remove the pollutant of perchlorate ion. nanoscale zero valence iron (nZVI) particles are widely employing reduction catalyst for decomposition of perchlorate ion. nZVI particles has increasingly been utilized in groundwater purification and waste water treatment. But it have strong tendency of aggregation, rapid sedimentation and limited mobility. In this study, we focused on reduction of perchlorate ion using nZVI particles immobilized in alginate polymer bead for stabilization. The stabilized nZVI particles displayed much greater surface area, and much faster reaction rates of reduction of perchlorate ion. In this study, an efficient way to immobilize nZVI particles in a support material, alginate bead, was developed by using $Ca^{2+}$ as the cross-linking cations. The efficiency and reusability of the immobilized Fe-alginate beads on the reduction of perchlorate was tested at various temperature conditions.

• Proceedings of the KWS Conference
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• 2005.06a
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• pp.387-392
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• 2005

For the production of further functional bio-degradable plastic(polybutylene succinate:PBS) with $TiO_{2}$ as photocatalyst, which shows the decomposition of detrimental organic compound and pollutant under ultraviolet irradiation, we attempted to prepare $TiO_{2}$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions. The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated through the photo degradation of gaseous acetaldehyde. The effects of primary particle size and spraying parameters on the formation behavior, photo catalytic performance and mechanical characteristics of the coatings have been investigated. The results indicated that with respect to both the HVOF sprayed $P_{200}$ and $P_{30}$ coatings, the high anatase ratio off 100% can be achieved regardless of fuel gas pressure. On the other hand, the HVOF sprayed $P_{7}$ coating exhibited largely decreased anatase ratio (from 100% to 49.1%) with increasing the fuel gas pressure, which may be attributed to the much higher susceptibility to heat of 7nm agglomerated powder. In terms of photocatalytic efficiency, HVOF sprayed $P_{200}$ and $P_{30}$ coatings seem to predominate as compared to that of plasma sprayed $P_{200}$ coatings owing to the higher anatase ratio. However, the HVOF sprayed $P_{7}$ coatings didn't show the photo catalytic activity, which may result from the extremely small reaction surface area to the photo-catalytic activity and low anatase ratio. Such functional PBS with new roles is expected to cosiderably contribute to the reduction of aggravated environmel problem.

• Environmental Engineering Research
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• v.11 no.4
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• pp.194-200
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• 2006

Recently, the population growth, industrial and agricultural development are rapidly undergoing in the Lower Rio Grande Valley (LRGV) in Texas. The Lower Rio Grande Valley (LRGV) composed of the 4 counties and three of them are interesting for Non-point and point source pollutant modeling: Starr, Cameron, and Hidalgo. Especially, the LRGV is an intensively irrigation region, and Texas A&M University Agriculture Program and the New Mexico State University College of Agriculture applied irrigation district program, projects in GIS and Hydrology based agricultural water management systems and assessment of prioritized protecting stream network, water quality and rehabilitation based on water saving potential in Rio Grande River. In the LRGV region, where point and non-point sources of pollution may be a big concern, because increasing fertilizers and pesticides use and population cause. This project objective seeks to determine the accumulation of non-point and point source and discuss the main impacts of agriculture and environmental concern with water quality related to pesticides, fertilizer, and nutrients within LRGV region. The GIS technique is widely used and developed for the assessment of non-point source pollution in LRGV region. This project shows the losses in $kg/km^2/yr$ of BOD (Biological Oxygen Demand), TN (total Nitrogen) and TP (total phosphorus) in the runoff from the surface of LRGV. Especially, farmers in Cameron County consume a lot of fertilizer and pesticide to improve crop yield net profit. Then, this region can be created as larger nonpoint source area for nutrients and the intensity of runoff by excess irrigation water. And many sediment and used irrigation water with including high nutrients can be discharged into Rio Grade River.

• Spatial Information Research
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• v.3 no.1
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• pp.1-18
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• 1995

Despite the widespread use of GIS over the past ten years, it has been limited application for regional modeling of pollutant loadings such as sediment, nitrogen, and phosphorus(non-point source pollution), The goals of this study were to: select important processes and parameters of watersheds that contribute to non-point source pollution degradation, develop a ranking model to use the environmental geologic data and verify the model by comparing results with existing water quality data(Chung-ju Lake) for specific watersheds, The GIS database consisted of topography, geology, soils, precipitation, rainfall erosivity, land use, and watershed boundaries. The index(NPSP) for assessing non-point source pollution was comprised in the following three seperate components: soil loss index(SLI) assesses the potential soil erosion and sedim-ent delivery from field to stream; run-off potential ratio(R.P.R) predicts the potential production of surface runoff; chloropgyll-a index ranks the potential manure(animal or human) production within a watershed. The GIS model was a valuable tool to assess the impact of environmental pollation in watersheds.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.254-257
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• 2017

As a part of the development of aircraft gas turbines, combustion performance tests have been conducted in the single combustor sector. The effects of change in the amount of air supplied to the main combustion zone to the performance of the combustor, such as a pollutant emission, a liner temperature distribution and an exit temperature patterns, were studied. Emissions of CO and NOx increased with the main air-ratio and exit temperature pattern was improved. When changing the pattern of the dilution holes, it was shown that the temperature patterns on the exit plane of the combustor and the surface of liner changed depending on the main flame structure and mixing with diluent air. These observations will be applied to combustor liner designs to improve combustor durability and emissions reduction performance.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.6
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• pp.417-421
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• 2018

$TiO_2$ has excellent photocatalytic properties and several studies have reported the increase in its specific surface area. The structure of $TiO_2$ nanofibers indicates promising improved photocatalytic properties and these nanofibers can thus potentially be applied in air pollution sensors and pollutant removal filters. In this study, a $TiO_2$ nanofiber was fabricated by the electrospinning method. The fabrication processing factors such as the applied voltage, the distance between nozzle and collector, and the inflow rate of solution were controlled. The precursor was titanium (IV) isopropoxide and as-spun $TiO_2$ nanofibers were heated at $450^{\circ}C$ for 2 h to obtain an anatase crystalline structure. The microstructure was analyzed using field emission scanning electron microscope (FE-SEM) and X-ray diffraction analysis (XRD). The anatase phase was observed in the $TiO_2$ nanofibers after heat treatment. The diameter of $TiO_2$ nanofibers increased with the flow rate, but decreased with decreasing applied voltage and nozzle to collector distance. The diameter of $TiO_2$ nanofibers was controlled in the range of 364 nm to 660 nm. These nanofibers are expected to be very useful in photocatalytic applications.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.1
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• pp.93-102
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• 2005

A prototype surface flow constructed wetland was built in the upstream area of Sihwa reclaimed tidal lands to improve the water quality of Lake Sihwa by treating severely polluted stream water. In this study, we monitored hydrology, macrophyte (Phragmites communis Trin,) growth, and water quality in the Banwol and Donghwa wetlands to evaluate their performance during the initial period after the completion of wetland construction, The average removal efficiency($\%$) in each wetland was relatively low compared with the performance data from the North America Wetland Treatment System Database (NADB), which mainly includes urban sewage-treatment wetlands. However, the average removal rates per unit area ($g/m^{2}/day$) were 0.72, 0.72 and 0.51 (BOD), 2,04, 2.46 and 0.70 (SS), 0.89, 0.43 and 1.09 (TN) and 0.02, 0.02 and 0.02 (TP) in the Banwol and Donghwa wetlands and NADB, respectively. The overall performance of the Banwol and Donghwa wetlands was within the expected range of the wetland system processes contributing the reduction of the pollutant load to Lake Sihwa during the initial period of wetland operation. Considering the low influent concentration, high hydraulic loading rate, and insufficient macrophyte growth since the wetland was constructed, better performance is expected if an improved operational scheme is adopted.

• Transactions of Materials Processing
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• v.17 no.6
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• pp.412-419
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• 2008

Using lightweight materials in vehicle manufacturing in order to reduce energy consumption is one of the most effective approach to decrease pollutant emissions. As a lightweight material, magnesium is increasingly employed in automotive parts. However, because of its hexagonal closed-packed(HCP) crystal structure, in which only the basal plane can move, the magnesium alloy sheets show low ductility and formability at room temperature. Thus the press forming of magnesium alloy sheets has been performed at elevated temperature within range of $200^{\circ}C{\sim}250^{\circ}C$. Here we try the possibility of sheet metal forming at room temperature by adopting incremental forming technique with rotating tool, which is so called as rotational-incremental sheet forming(RISF). In this rotational-incremental sheet forming the spindle tool rotates on the surface of the sheet metal and moves incrementally with small pitch to fit the sheet metal on the desired shape. There are various variables defining the formability of sheet metals in the incremental forming such as speed of spindle, pitch size, lubricants, etc. In this study, we clarified the effects of spindle speed and pitch size upon formability of magnesium alloy sheets at room temperature. In case of 0.2, 0.3 and 0.4mm of pitch size with hemispherical rotating tool of 6.0mm radius, the maximum temperature at contact area between rotating tool and sheet metal were $119.2^{\circ}C,\;130.8^{\circ}C,\;and\;177.3^{\circ}C$. Also in case of 300, 500, and 700rpm of spindle speed, the maximum temperature at the contact area were $109.7^{\circ}C,\;130.8^{\circ}C\;and\;189.8^{\circ}C$.

• Journal of the Korean Institute of Gas
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• v.7 no.4 s.21
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• pp.7-13
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• 2003

This study was carried out to optimize premixed burner and heat exchanger of the condensing gas boiler which can save energy by utilizing latent heat of combustion gas and reduce pollutant in exhaust gas. The heat exchanger of the gas boiler was composed of three parts, which were an upper, lower, and coil heat exchanger. The upper heat exchanger was placed outside of the premixed burner and a lower heat exchanger was located under the upper heat exchanger. And, coil heat exchanger rounded the outer surface of an upper and lower heat exchanger. The boiler designed by this research reaches turn-down ratio 4:1 in the domain of equivalence ratio 0.75${\~}$0.8 and thermal efficiency of $97\%$. Emission of NOx and CO concentration was under 20ppm and 140ppm at equivalence ratio 0.8. When diameter of the burner is replaced from 60mm to 50mm, emission of CO was reduced about 50ppm remarkably.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.430-430
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• 2017

본 연구에서는 유역모델링 시 오염원 산정의 공간적 범위를 합리적으로 고려하기 위해서, 유역모델링을 위한 소유역 구분간의 공간해상도를 유역의 오염부하량 산정을 위한 공간단위 수준으로 설정하여 새만금호 유역수질모델링을 실시하였다. 모형 구축은 HSPF (Hydrological Simulation Program - Fortran)를 이용하였으며, 오염부하량 산정단위인 리 동의 행정경계, 수치표고모델(DEM), 농경지 배수로 등 구조물들을 고려하여 새만금 유역을 대상으로 804개의 소유역을 구분 적용하였다. 소유역 세분화에 따른 계산량을 고려하여 효과적인 모델 구동을 위해 만경유역 7개, 동진유역 7개, 연안유역 3개 (총 17개)의 서브모델로 모의시스템을 구성하여 상류에서 하류로 서브모델을 순차적으로 보 검정 및 모의하도록 구현하였다. 유량 보 검정은 14개소 수문측정자료(2009~2013)와 자동보정기법을 적용하여 수행하였다. 유량보 검정결과 NSE (Nash-Sutcliffe coefficient)가 0.66~0.97, PBIAS가 -31~16.5%, $R^2$는 0.75~0.98의 범위를 보여 모형의 적용성을 확인할 수 있었다. 한편, 수질 보 검정의 경우 29개소 수질측점을 대상으로 온도, DO, BOD, TN, TP의 항목에 대해 유량보정과 같은 기간에 대해 수동보정을 실시하였다. 수질결과는 일부 상류유역에서 갈수기시 모의값이 다소 불안정한 부분이 발견되나 대체로 각 측점의 수질에 대한 시간적 변동 패턴과 평균적 수질은 합리적으로 모의하는 것으로 나타났다. 공간세분화에 따른 모델링결과를 선행연구들과 비교한 결과, 유량부문에서 우수성을 보였으나 수질부문은 비슷한 수준으로 나타났다. 본 연구는 향후 유역 오염원, 수자원 운영 등에 관한 정밀 자료 확보 시 이를 고려하는 고도화된 수문 수질 모델링 개발 및 구축에 적용될 수 있는 시스템으로 활용성이 높을 것으로 판단된다.