• 한국대기환경학회지
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• 제18권4호
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• pp.253-264
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• 2002

Surface ozone concentrations measured at 40 monitoring sites in three major cities (Seoul, Busan, and Daegu) of Korea during 1993~2000 were analyzed to understand the characteristics of temporal and spatial distributions. Trends were analyzed for annual mean, 95th percentiles of daily 8-hour maximum and days exceeding 8-h ozone standard of 60 ppb. Three indicators exhibited increasing trends (+0.75 ppb yr$^{-1}$ , +2.20 ppb yr$_{-1}$ , and +5.35 days yr$_{-1}$ on average) throughout the study period at all cities. Diurnal and seasonal variations were the largest in Seoul followed by Daegue and Busan, due to the high photochemical production and titration of ozone (Seoul), strong wind and constant supply of background ozone from the ocean (Busan). In the urban centers and industrial areas at all cities, scavenging of ozone by NO reduces the daily 8-hour maximum ozone by 10 ppb on average. High concentrations of ozone have frequently occurred in downwind eastern (Seoul and Daegu) or northern (Busan) sides of the territory. In particular, the coastal area of Busan had relatively high ozone level due to the local sea land breeze circulation. The results indicated that the temporal and spatial variations of ozone concentration were non -uniform and were closely related to the local environments; emission levels, climates, and geographic locations.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제50권4호
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• pp.169-175
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• 2001

Ozone has been widely applied to many industrial fields because of its strong oxidation power, Therefore, the studies have been carried out for the methods on an effective and high concentration ozone generation. The silent or surface discharge type ozone generators have been mainly used for high concentration ozone generation in many fields of applications. But these two types of ozone generators have shortcomings to be improved. In this study, the ozone generator which improved the shortcomings of above ozone generators was proposed and fabricated for the high concentration ozone generation. And the proposed ozone generator could generate the surface and barrier discharge simultaneously. For this purpose, a mesh type discharge electrode was proposed and studied as a function of the widths output maximum ozone concentration of 2.96[vol%] was obtained at 5.6[kV], 830[mA], for 0.3[mm] width and 0.8[mm] vacancy of the mesh electrode and gap spacing of 0.65[mm] respectively.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제50권7호
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• pp.334-339
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• 2001

A silent type ozone generator using water surface has been studied and improved its ozone generation characteristics by the controlling the height of Taylor cone by installing a mesh electrode, a dielectric bed of glass beads in the just under th surface of the water. The current-voltage characteristics and characteristics of ozone generation quantity of the test system were investigated and discharge current oscillograms of the each cases of the mesh electrode and the beds were observed and compared each other to analyze the discharge conditions. The Taylor cone height could be the cause of the discharge bridge to decrease the ozone generation on the discharge spacing. In this study, the hight of Taylor cone could be reduced greatly by installing the mesh and the glass beads bed just under the water surface. Therefore a higher ozone generation also could be obtained.

• 한국식품저장유통학회지
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• 제5권2호
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• pp.177-185
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• 1998

For the purpose of enhanceing soybean-sprouts quality, the optimum conditions for ozone treatment of soybean during soaking before cultivation at 18~2$0^{\circ}C$ were evaluated with ozone concentration, treatment time and treatment frequency by response surface methodology. Germination rates of cleaned soybean by ozone water in the conditions of solubilized-ozone concentrations of 0.15 to 0.35ppm, ozone-treatment frequency of 1.5 to 2.3 times and ozone-treatment time of 30 to 36min. increased 18.8 to 24.0% for the control products. And, length of hypocotyl in conditions of 0.12 to 0.33ppm, 1.7 to 2.7 times and 45 to 90min. were also increased by 69.36 to 79.40%. On the other hand, weight of roots with ozone treatment were decreased in the conditions of solubilized ozone concentrations of 0.1 to 0.2ppm and ozone-treatment time of 30 to 57min. But, ozone-treatment frequency did not affected root growth. Putrefaction rates of the control were 5 to 15%, but those of ozone-treated samples during cultivation did not show. The overall optimum conditions for above 16% germination rates, above 9% hypocotyl yields compared to the control samples and below 98% of the control root weight were solubilized-ozone concentrations of 0.25 to 0.30ppm, ozone-treatment time of 43 to 49min. and ozone-treatment frequency of one time.

• 한국환경과학회지
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• 제14권12호
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• pp.1103-1112
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• 2005

Ozone measurements made from 4 sites in Jeju Island have been analyzed, including those from two urban and two rural locales. The data were analyzed in terms of the seasonal and diurnal trends. It should be clear that the surface ozone levels in Jeju area would be relatively sensitive to the external ozone supply originated from the region of Northeast Asia. It seems to be that due to the reactions of ozone with $NO_{x}$ and CO, the average ozone level in Jeju City appears lower than that in Seogwipo City although Jeju City is the largest city in Jeju Island.

• 한국환경과학회지
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• 제10권6호
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• pp.417-422
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• 2001

The vertical structure of atmosphere was observed In investigate the variation of surface ozone concentration by vertical downward mixing of residual ozone in the atmospheric boundary layer at the Busan coastal area. Airsonde and pilot balloon measurements were made at Gamcheondong and the Kimhae airport for April 26~27, 1996. The vertical potential of potential temperature showed a residual layer between 510m and 1800m from 2100LST April 26 to 0900LST April 27. The downward mixing of ozone in the residual layer of the atmospheric boundary layer was confirmed from vertical profile of mixing ratio near 600m in the morning. The thickness of the sea breeze layer was 900m at 1500LST April 26. Thereafter, it become to be lowered with time A low level jet was measured near 900m at 0300LST on April 27 from a pibal measurement. Early morning sharp increase of surface ozone concentration at the Busan coastal area was caused by vertical downward mixing of ozone concentration rather than by photochemical reaction In the atmospheric boundary layer.

• 한국대기환경학회지
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• 제20권4호
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• pp.503-514
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• 2004

In Seoul metropolitan area, nocturnal variation of surface ozone concentrations observed at 27 monitoring sites from 1998 to 2002 showed that high ozone levels occurred frequently during the spring. Frequency distributions for nighttime ozone indicated that elevated concentrations in spring were influenced by advection of different air mass compared to other seasons. Surface wind analysis during the spring revealed that relatively strong southwesterly winds were associated with nocturnal ozone enhancement, which can be attributed to the regional transport of ozone. In order to identify the origin of nocturnal ozone enhancement in spring, 3-day backward trajectories were calculated by HYSPLIT 4 for the episode days and then classified. The results showed that NW, W, and SW flows, indicating influence of polluted air masses from the China continent, have 51% in a]1 the episode days, which suggest that the nocturnal ozone enhancement can occur under the effect of long-range transport of ozone-laden air mass on a regional scale. Case study of nocturnal ozone maxima associated with long-range transport was discussed in more detail in the light of meteorological conditions. Southwesterly synoptic flow along the outer edge of moving high-pressure system was found to be the important cause of nocturnal ozone maxima in Seoul. This flow could lead to be long-range transport of ozone that had effectively accumulated in the stagnating portion of the system located eastern coast of China. Low atmosphere soundings, backward trajectories, and elevated ozone and CO levels at the back-ground tiles gave evidence for regional effects on nocturnal ozone enhancement In Seoul.

• 전기학회논문지
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• 제59권5호
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• pp.932-938
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• 2010

This paper proposed the effective treatment method for organic substances using the barrier discharge plasma process and catalytic chemical reaction followed from ozone decomposition. The decomposition by the plasma process of organic substances such as trichloroethylene, methyl alcohol, acetone, and dichloromethane carried out, and ozone is generated effectively at the same time. By passing through catalysts, ozone easily decomposed and further decomposed organic substances. And, 2-dimensional distribution of ozone using the optical measurement method is performed to identify the catalytic surface chemical reaction. In addition, CO is easily oxidized into $CO_2$ by this chemical reaction, which might be induced oxygen atom radicals formed at the surface of catalyst from ozone decomposition.

• 한국군사과학기술학회지
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• 제11권2호
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• pp.101-108
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• 2008

This study attempted to develop the technology by gaseous ozone for decontaminating building affected by a model of biological weapon agent(Bacillus subtilis spores) instead of Bacillus anthracis spore. The use of ozone is attractive method from a practical point of view of decontamination procedure since it has strong oxidation power but no residue after application. We examined the disinfection efficiency of gaseous ozone to Bacillus subtilis spores which suspension was sprayed on different material surfaces and dried. Three different types of gaseous ozone was applied : dry ozone, dry ozone with humidified air, and water bubbled wet ozone. Dry ozone(1500ppm) failed to achieve any significant inactivation for 2hrs. However, six log reduction of B. subtilis spore was achieved within 30min by 1500ppm of water bubbled wet ozone. This result shows the noticeable inactivation efficiency by gaseous ozone compared with previous studies. Good performance by wet ozone was also found for military material surface.(i.e. : gas mask hood, protective garments, army peinted metal surface).

• 조명전기설비학회논문지
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• 제17권3호
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• pp.56-63
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• 2003

수표면을 전극으로 사용한 부성방전형 오존발생기를 제안하고 수표면의 바로 아래에 유전체구를 설치함으로써 오존발생특성을 향상시킬 수 있었다. 이때, 서로 다른 유전율을 갖는 유전체구를 사용하여 수표면에 형성되는 방전조건을 변화시키고자 하였다. 전류-전압특성과 오존발생특성을 조사하였고 방전현상을 관찰하기 위해 유리구슬 유전체를 사용한 경우의 방전모양을 사진 촬영하여 분석하였다. 수표면에 발생되는 수돌기의 크기는 교락현상(breakdown)의 원인이 될 수 있고 따라서 오존발생량을 감소시킨다. 본 연구에서는 수표면 바로 아래에 서로 다른 유전율을 갖는 유전체구를 투입함으로써 과도한 크기의 수돌기(Tayler cone)의 놀이를 제한할 수 있었다. 이에 따라, 유전체구를 사용하지 않은 경우보다 많은 양의 오존을 발생시킬 수 있었다. 수중에 투입되는 유전체의 유전율이 증가함에 따라 방전이 시작되는 전압을 앞당길 수 있었고 강유전체구를 사용한 경우 최대 110[ppmv]의 오존발생량을 얻을 수 있었다.