• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.197-197
• /
• 2011

In this study, in contrast with cases in which Scanning Tunneling Microscopy (STM) tip-induced reactions were instigated by the tunneling electrons, the local electric field, or the mechanical force between a tip and a surface, we found that the tungsten oxide (WO3) covered tungsten (W) tip of a STM acted as a chemical catalyst for the S-H dissociative adsorption of phenylthiol and 1-octanethiol onto a Ge(100) surface. By varying the distance between the tip and the surface, the degree of the tip-catalyzed adsorption could be controlled. We have found that the thiol head-group is the critical functional group for this catalysis and the catalytic material is the WO3 layer of the tip. After removing the WO3 layer by field emission treatment, the catalytic activity of the tip has been lost. 3-mercapto isobutyric acid is a chiral bi-functional molecule which has two functional groups, carboxylic acid group and thiol group, at each end. 3-Mercapto Isobutyric Acid adsorbs at Ge(100) surface only through carboxylic acid group at room temperature and this adsorption was enhanced by the tunneling electrons between a STM tip and the surface. Using this enhancement, it is possible to make thiol group-terminated surface where we desire. On the other hand, surprisingly, the WO3 covered W tip of STM was found to act as a chemical catalyst to catalyze the adsorption of 3-mercapto isobutyric acid through thiol group at Ge(100) surface. Using this catalysis, it is possible to make carboxylic acid group-terminated surface where we want. This functional group-selective adsorption of bi-functional molecule using the catalysis may be used in positive lithographic methods to produce semiconductor substrate which is terminated by desired functional groups.

• Journal of International Academy of Physical Therapy Research
• /
• v.10 no.2
• /
• pp.1756-1762
• /
• 2019

Background: Functional ankle instability (FAI) indicating a decrease in muscle strength, proprioception, neuromuscular control, balance and postural control function. Objective: To investigate the effect of jumping exercise on the supporting surface on the ankle muscle thickness, proprioceptive sensation, and balance in adults with FAI. Design: Randomized Controlled Trial. Methods: Twenty young people with FAI were randomly assigned to the unstable supporting surface jump group (N=10) and the stable supporting surface jump group (N=10). The intervention was conducted three times a week for eight weeks, and for 30 minutes per session. Trampoline was used as an unstable support surface and the stable support surface was carried out on a regular floor. The thickness of the tibialis anterior muscle and medial gastrocnemius muscle was measured by ultrasonography, and the proprioception of dorsiflexion and plantarflexion was measured using an electrogoniometer. The dynamic balance was also measured with a balance meter. Results: The the muscle thickness of the medial gastrocnemius muscle was significantly higher in the stable supporting surface jump group than in the unstable supporting surface jump group (p<.05). Furthermore, the plantar flexion proprioception and dynamic balance were significantly improved in the unstable supporting surface jump group than in the stable supporting surface jump group in the intergroup comparison (p<.05). Conclusions: The conclusion has been reached in this study that the jumping exercise on the unstable supporting surface could be a more effective in improving FAI than the regular surface.

• The Journal of Korean Physical Therapy
• /
• v.28 no.4
• /
• pp.254-258
• /
• 2016

Purpose: This study was conducted to identify the effects of dual task training on balance and functional performance in high school soccer players with functional ankle instability. Methods: Twenty high school soccer players with functional ankle instability were randomly assigned to a single task training group and a dual task training group. One participant who did not participate regularly in the training was excluded. The single task training group (n=9) received balance training on an unstable surface. The dual task training group (n=10) received balance training on an unstable surface and had to catch thrown balls during the balance training. Both groups were trained for 4 weeks, 3 days a week. The balance and functional performance of both groups was measured before and after training. Balance was measured using an anterior-posterior and medio-lateral balance. Functional performance was measured based on a figure-of-8 hop test, up-down hop test, and a single hop test. All data were analyzed by repeated two-way ANOVA tests. Results: A time by group interaction effect was not observed in the medio-lateral balance test, figure-of-8 hop test, or single hop test (p>0.05). A time by group interaction effect was observed in the anterior-posterior balance and up-down hop test (p<0.05). Conclusion: These results suggest that dual task training improved balance and functional performance better than single task training for some items.

• The Journal of Korean Academy of Orthopedic Manual Physical Therapy
• /
• v.20 no.2
• /
• pp.1-7
• /
• 2014

Purpose: The purpose of this study was to compare the effects of the balance training on the stable and unstable supporting surfaces for the subjects with functional ankle instability. Methods: Twenty-nine subjects with functional ankle instability were randomly assigned to the stable group (n=14) and the unstable group (n=15). Balance training was conducted twenty minutes a day on the stable surface for the stable group and on the airostep for the unstable group three times a week for four weeks. Balance training program was consisted of ten steps by eye opened or closed and two or one leg standing. X-speed for transverse balance and Y-speed for longitudinal balance were measured with eye opened and closed in affected leg standing position. Results: There were significant improvements of balance ability in eye opened (p<.01) and eye closed standing (p<.01) in stable group. Unstable group also showed significant improvements of balance ability in eye opened (p<.01) and eye closed standing (p<.01). There were no statistical differences in the magnitude of improvement between the groups (p<.05). Conclusions: Based on such results, it can be said that balance training on the stable surface is effective as much as training on the unstable surface for the subjects with functional ankle instability.

• Environmental Engineering Research
• /
• v.24 no.1
• /
• pp.173-179
• /
• 2019

Prussian blue (PB) is known to be an effective material for radioactive cesium adsorption, but its nano-range size make it difficult to be applied for contaminated water remediation. In this study, a simple and versatile approach to immobilize PB in the supporting matrix via surface functionalization was investigated. The commercially available poly vinyl alcohol (PVA) sponge was functionalized by acrylic acid (AA) to change its major functional group from hydroxyl to carboxylic, which provides a stronger ionic bond with PB. The amount of AA added was optimized by evaluating the weight change rate and iron(III) ion adsorption test. The FTIR results revealed the surface functional group changing to a carboxyl group. The surface functionalization enhanced the attachment of PB, which minimized the leaching out of PB. The $Cs^+$ adsorption capacity significantly increased due to surface functionalization from 1.762 to 5.675 mg/g. These findings showed the excellent potential of the PB-PAA-PVA sponge as a cesium adsorbent as well as a versatile approach for various supporting materials containing the hydroxyl functional group.

• Corrosion Science and Technology
• /
• v.17 no.2
• /
• pp.74-80
• /
• 2018

The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

• Journal of Korean Society of Environmental Engineers
• /
• v.29 no.3
• /
• pp.357-364
• /
• 2007

This research is to set a direction on the recycle of Discarded Automotive tires reforming them into heavy metal adsorbents by developing a particular functional group inducing formation of Chelate complexes with heavy metal ion in the water, on the surface of the used tire conventionally turned into powdered form. For this purpose, through FT-IR, XRD, XRF, SEM, elution test we confirmed and analyzed the property of newly reformed scrapped tires, and functional group. Also, by Kinetics Study we produced an invariable value applying to absorption models. Conclusively the absorption preference of heavy metal is determined to be $Pb^{2+}>Cu^{2+}>Cd^{2+}$, and it reached absorption balance within first 30 minutes, also the absorption reaction time increased from 0.27 to $1.78\sim3.15(g/mg{\cdot}min)$, and showed more than 80% of removal efficiency. This result proved that the efficiency increased by 10 times compared with the conventional powdered Discarded Automotive tires, and the Discarded Automotive tire which implemented the Functional group can exhibit a great efficiency as heavy metal adsorbent.

• Physical Therapy Korea
• /
• v.15 no.4
• /
• pp.18-26
• /
• 2008

The present study was aimed at investigating the postural control ability of volleyball players with functional ankle instability. The subjects were 26 male volleyball players were divided into 2 groups (13 subjects with functional ankle instability and 13 subjects with ankle stability) who could evaluate Questionnaire. All the male participants were tested by a Balance Master System. This study were to measure of static balance ability, dynamic balance ability, motor function the difference between functional ankle instability group and control group. Ankle instability group and stable group in postural sway ($^{\circ}/sec$) on film surface with eye closed in modified clinical test sensory interaction on balance, and left unilateral stance with eye opened and closed were significantly different (p<.05). The ankle instability group and stable group in limit of stability were significantly different (p<.05). The ankle instability group and stable group in left/right rhythmic weight shirt were significantly different (p<.05). The ankle instability group and stable group in turn time (sec) & turn sway ($^{\circ}$) during step/quick turn and end sway ($^{\circ}/sec$) in tandem walk were significantly different (p<.05). This study showed that volleyball players with functional ankle in stability were effected postural control ability by static balance & dynamic balance ability. Further study is needed to measure various athletic with functional ankle instability for clinical application.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.6 no.4
• /
• pp.648-662
• /
• 1996

Electrode surface reaction on glassy carbon and synthesized graphite (PVDF mixed graphite) in sulfuric acid solution is investigated by impedance spectroscopy at cyclic polarization. The redox peak, which may be due to the change of chemical adsorped functional group on electrode surface or oxidation and reduction of oxygen, is represented on glassy carbon and graphite electrode in potentio-dynamic current curve. The oxidation and reduction of these surface functional group on glassy carbon and PVDF mixed graphite have a major affect on the impedance spectrum and Faraday impedance parameter at cyclic polarization.

• The Journal of Korean Physical Therapy
• /
• v.28 no.3
• /
• pp.189-194
• /
• 2016

Purpose: This study focuses on influence of ankle stabilization training on balance ability and lower limb muscle activation of soccer player with functional ankle instability. Methods: Subjects were grouped into ankle stabilization training group using biofeedback comprised of 15 subjects and general exercise group of 15. The training was conducted for 30 minutes, 3 times a week for 8 weeks in total. All 30 football players conducted plyometric training for 30 minutes before main training. To evaluate balance ability, biorescure was used to measure whole path length and surface area and surface electromyography (EMG) system was used to measure tibialis anterior, tibialis posterior, and soleus to evaluate lower limb muscle activation. Results: The experiment group showed significant difference to the comparison group in regard of whole path length and surface area which represents balancing capability and muscle activation of tibialis anterior, tibialis posterior, and soleus. Conclusion: Therefore, ankle stabilization training using biofeedback is more effective in enhancing balance ability and lower limb muscle activation than general exercise.